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1. Molecularity of elementary reactions   Some elementary reactions for the reaction between CH4 and Cl2 are                Cl2   -------->       2 Cl                     2 Cl     --------->    Cl2                     2Cl + CH4 ---------->    Cl2 + CH4*                     Cl + CH4 --------->   HCl + CH3                     CH3 + Cl    ------------->    CH3Cl                     CH3 + CH3 -------------->   CH3-CH3                     CH3Cl + Cl --------------->   HCl + CH2Cl                       CH2Cl + Cl ---------------->   CH2Cl2 2. Write down the rate laws and describe them as uni- bi- or ter-molecular steps.

1. Molecularity of elementary reactions   Some elementary reactions for the reaction between CH4 and Cl2 are                Cl2   -------->       2 Cl                     2 Cl     --------->    Cl2                     2Cl + CH4 ---------->    Cl2 + CH4*                     Cl + CH4 --------->   HCl + CH3                     CH3 + Cl    ------------->    CH3Cl                     CH3 + CH3 -------------->   CH3-CH3                     CH3Cl + Cl --------------->   HCl + CH2Cl                       CH2Cl + Cl ---------------->   CH2Cl2 2. Write down the rate laws and describe them as uni- bi- or ter-molecular steps.

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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1. Molecularity of elementary reactions 

 Some elementary reactions for the reaction between CH4 and Cl2 are

               Cl2   -------->       2 Cl

                    2 Cl     --------->    Cl2

                    2Cl + CH4 ---------->    Cl2 + CH4*

                    Cl + CH4 --------->   HCl + CH3

                    CH3 + Cl    ------------->    CH3Cl

                    CH3 + CH3 -------------->   CH3-CH3

                    CH3Cl + Cl --------------->   HCl + CH2Cl

                      CH2Cl + Cl ---------------->   CH2Cl2

2. Write down the rate laws and describe them as uni- bi- or ter-molecular steps.

 

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