1. In which direction does the equilibrium lie for each of the following reactions? Use the data in the Table to determine in which direction the equilibrium lie for each of the following reactions? a. CH3CO2H + CH3CH2O¯ b. CH3CONH2 +F CH3CO2 + CH3CH2OH CH3CONH + HF C. H2O + NH2 OH + NH3

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Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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1. In which direction does the equilibrium lie for each of the following reactions? Use the
data in the Table to determine in which direction the equilibrium lie for each of the
following reactions?
a. CH3CO2H + CH3CH2O
b. CH3CONH2 + F
CH3CO2 + CH3CH2OH
CH3CONH + HE
C. H20 + NH2
OH + NH3
Transcribed Image Text:1. In which direction does the equilibrium lie for each of the following reactions? Use the data in the Table to determine in which direction the equilibrium lie for each of the following reactions? a. CH3CO2H + CH3CH2O b. CH3CONH2 + F CH3CO2 + CH3CH2OH CH3CONH + HE C. H20 + NH2 OH + NH3
The pK, values for types of compounds frequently encountered in
organic chemistry.
Table 5.1
pka
Compound types
Mineral acids (H2SO4, HI, HBr, HCI); sulfonic acids (RSO3H)
H30*, H3PO4
Carboxylic acids (RCOO H), HF, aromatic thiols (ArSH), HN3
Weak inorganic acids (H2S, HCN, NHa*), amine salts (RNH3*), phenols (ArOH),
thiols (RSH), aromatic amides (ArCONH
H20, alcohols (ROH), amides (RCONH2)
-10
5
10
15
20
Ketones (RCH2COR')
25
Esters (RCH,COOR'), alkynes (RC=CH), nitriles (RCH2CN)
Anilines (ARNH2)
Ammonia (NH3), amines (RNH2), benzylic C-H (ArCH2X)
30
40
45
Arenes (ArH) and alkenes (RCH=CH2)
50
Alkanes (RH)
Transcribed Image Text:The pK, values for types of compounds frequently encountered in organic chemistry. Table 5.1 pka Compound types Mineral acids (H2SO4, HI, HBr, HCI); sulfonic acids (RSO3H) H30*, H3PO4 Carboxylic acids (RCOO H), HF, aromatic thiols (ArSH), HN3 Weak inorganic acids (H2S, HCN, NHa*), amine salts (RNH3*), phenols (ArOH), thiols (RSH), aromatic amides (ArCONH H20, alcohols (ROH), amides (RCONH2) -10 5 10 15 20 Ketones (RCH2COR') 25 Esters (RCH,COOR'), alkynes (RC=CH), nitriles (RCH2CN) Anilines (ARNH2) Ammonia (NH3), amines (RNH2), benzylic C-H (ArCH2X) 30 40 45 Arenes (ArH) and alkenes (RCH=CH2) 50 Alkanes (RH)
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