1. In following pairs of nucleophilic substitution reaction, which one have higher reaction rate? Explain why. (а) HBr H20 + Br SN1 HO OH Br + HBr H20 + SN1 (b) CI CH3NH2 SN2 CI CH3NH2 SN2 (c) H2O Br NaSH SH NaBr SN2 H20 Br NaOH + NaBr SN2
1. In following pairs of nucleophilic substitution reaction, which one have higher reaction rate? Explain why. (а) HBr H20 + Br SN1 HO OH Br + HBr H20 + SN1 (b) CI CH3NH2 SN2 CI CH3NH2 SN2 (c) H2O Br NaSH SH NaBr SN2 H20 Br NaOH + NaBr SN2
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:Problems:
1.
LIn following pairs of nucleophilic substitution reaction, which one have
higher reaction rate? Explain why.
(а)
HOT
HBr
H20
+
Br
SN1
OH
Br
+
HBr
H20
+
SN1
1
(b)
'CI
CH3NH2
+
SN2
ONH, cº
CI
CH3NH2
SN2
(c)
H20
Br
NaSH
SH
NaBr
SN2
H20
+
NAOH
HO,
NaBr
Br
SN2
(d)
CH;OH
Br
NaSH
SH
+
NaBr
SN2
H
Me
`N´
Ме
Br
+
NaSH
SH
+
NaBr
SN2
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