1. E/Z and Chirality.. (a) ) Assign the priorities (as either high and low, or 1 and 2) for the four groups of the alkene. Based on those assigned priorities, predict the configuration (E or Z). Include the corresponding priority directly adjacent to each of the four groups. H3C H3C ॐ HO CH3 _) Assign each of the following molecules as chiral or achiral. (b). (i) HO (ii) Н E OH H₂CCH₂ Н H3C H Br Br H CH3 2. E2 Mechanism and Products Draw an arrow pushing mechanism for the elimination reaction below and draw all products formed (including all organic and inorganic products). H CH2 O=S. HII. CH3 H 'H H3C CH3

Organic Chemistry: A Guided Inquiry
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ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter14: Elimination
Section: Chapter Questions
Problem 40CTQ
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1. E/Z and Chirality..
(a)
) Assign the priorities (as either high and low, or 1 and 2) for the four groups of the
alkene. Based on those assigned priorities, predict the configuration (E or Z). Include
the corresponding priority directly adjacent to each of the four groups.
H3C
H3C
ॐ
HO
CH3
_) Assign each of the following molecules as chiral or achiral.
(b).
(i)
HO
(ii)
Н
E OH
H₂CCH₂
Н
H3C
H
Br
Br
H
CH3
2. E2 Mechanism and Products
Draw an arrow pushing mechanism for the elimination reaction below and draw all
products formed (including all organic and inorganic products).
H
CH2
O=S.
HII.
CH3
H
'H
H3C CH3
Transcribed Image Text:1. E/Z and Chirality.. (a) ) Assign the priorities (as either high and low, or 1 and 2) for the four groups of the alkene. Based on those assigned priorities, predict the configuration (E or Z). Include the corresponding priority directly adjacent to each of the four groups. H3C H3C ॐ HO CH3 _) Assign each of the following molecules as chiral or achiral. (b). (i) HO (ii) Н E OH H₂CCH₂ Н H3C H Br Br H CH3 2. E2 Mechanism and Products Draw an arrow pushing mechanism for the elimination reaction below and draw all products formed (including all organic and inorganic products). H CH2 O=S. HII. CH3 H 'H H3C CH3
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