1. Draw the MAJOR organic product obtained in the following reactions. Be sure to include stereochemistry if it is important. H2, Pd + isomer H2, Pt На, Ni + isomer HBr, CHCI,, RT + isomer
1. Draw the MAJOR organic product obtained in the following reactions. Be sure to include stereochemistry if it is important. H2, Pd + isomer H2, Pt На, Ni + isomer HBr, CHCI,, RT + isomer
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:In the given image, two chemical reactions are represented:
1. **Reaction 1:**
- **Starting Material:** A cyclohexene ring with a single methyl group attached.
- **Reagents:** HCl, CH₂Cl₂ (dichloromethane), under room temperature (RT) conditions.
- **Outcome:** The reaction results in the addition of HCl across the double bond, forming a new product, which is accompanied by an isomer.
2. **Reaction 2:**
- **Starting Material:** A cyclohexene ring with two methyl groups and an ethyl group attached, with a cis-configuration indicated by the solid and dashed wedges.
- **Reagents:** HCl, CCl₄ (carbon tetrachloride), under room temperature (RT) conditions.
- **Outcome:** The reaction again involves the addition of HCl across the double bond, yielding a product, along with an isomer.
**Diagram Explanation:**
- The cyclohexene structures show the position of the methyl and ethyl groups, with solid and dashed lines indicating stereochemistry.
- Reaction arrows illustrate the transformation from the starting materials to the products, highlighting the conditions and reagents used.
- "+ isomer" indicates that in both reactions, an isomeric form of the product is also produced.

Transcribed Image Text:**Reaction Problem: Determination of Major Organic Products**
**Objective:**
Determine the major organic product formed in each of the following reactions. If stereochemistry plays a critical role, please include it in your answers.
1. **Reaction Conditions:**
- Starting material: Cyclohexadiene with an exocyclic methylene (CH2)
- Reagents:
- H₂, Pd/C (Palladium on Carbon)
- Note: Include the isomer if applicable.
2. **Reaction Conditions:**
- Starting material: Bicyclic compound
- Reagents:
- H₂, Pt (Platinum)
3. **Reaction Conditions:**
- Starting material: Substituted cyclohexane
- Reagents:
- H₂, Ni (Nickel)
- Note: Include the isomer if applicable.
4. **Reaction Conditions:**
- Starting material: Methylcyclohexene
- Reagents:
- HBr, CHCl₃, and R'I (alkyl iodide)
**Instructions:**
- Draw the major product for each reaction.
- The transformation should consider the reduction of double bonds due to hydrogenation.
- For reactions involving potential stereochemical outcomes, ensure to depict all possible configurations, clearly indicating if isomers are formed.
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