1. Draw the following potentialenergy diagrams and fill in the missing values. Potential energy of reactants = 350 kJ PE of reactants = 200 kJ %3D Activation energy = 100 kJ PE of activated complex = 400 kJ %3! Potential energy of products = 250 kJ Heat of Reaction = +150kJ ΔΗ- Ea = PE of activated complex = PE of products = Potential Energy Diagram Potential Energy Diagram 300- 20- 200- 10- 50 80 100 20 20 -8 -8 Putetl Engy
1. Draw the following potentialenergy diagrams and fill in the missing values. Potential energy of reactants = 350 kJ PE of reactants = 200 kJ %3D Activation energy = 100 kJ PE of activated complex = 400 kJ %3! Potential energy of products = 250 kJ Heat of Reaction = +150kJ ΔΗ- Ea = PE of activated complex = PE of products = Potential Energy Diagram Potential Energy Diagram 300- 20- 200- 10- 50 80 100 20 20 -8 -8 Putetl Engy
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:Potential Energy Diagrams, Catalysts, and Reaction Mechanisms
/5 C12-3-07 Draw potential energy diagrams for endothermic and exothermic reactions. Include: relative rates.
effect of a catalyst, and heat of reaction (enthalpy change)
1.
Draw the following potentialenergy diagrams and fill in the missing values.
Potential energy of reactants = 350 kJ
PE of reactants = 200 kJ
%3D
%3D
Activation energy = 100 kJ
PE of activated complex = 400 kJ
Potential energy of products = 250 kJ
Heat of Reaction = +15OKJ
ΔΗ -
Ea =
PE of activated complex =
PE of products =
Potential Energy Dlagram
Potential Energy Dlagram
500-
500
400-
300-
160
200
200
100-
100-
40
0-
0-
20
40
100
20
60
B0
100
2. What is the effect of a catalyst on the activation energy of a reaction?
3.
What is the effect of a catalyst on the heat of the reaction? Why?
![/5 C12-3-09 Explain the concept of a reaction mechanism. Include: rate-determining step
4.
What is a reaction mechanism?
5.
Why is a bimolecular step more reasonable than a termolecular step?
6.
Considerthe following mechanism:
Step 1: Clo laq) + H2O) → HCIO (aq) + OH (aq)
(Slow]
Step 2: l'(aq) + HCIO(ag) → HIO(aqg) + Cl (aq)
[Fast]
Step 3: OH (ag) + HIO(aq) → H2Om + 1O (aq)
[Fast]
а.
What is the overall equation?
b. Identify any intermediates
C.
What is the rate determining step? Why did you choose this step?
d. In which step is the catalyst placed? Why is it put in this step?
е.
Predict and explain the effect the following changes would have on the rate of the
reaction.
1 no we,
i.
Increasing the concentration of Clo-
ii.
Increasing the concentration of I-
for kit](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fb2cdfaf5-e7cf-4f56-a0bd-92fd085a41fa%2Fb6a5dfb6-e508-4725-9d63-e2e918978c0a%2Fx66auqr_processed.jpeg&w=3840&q=75)
Transcribed Image Text:/5 C12-3-09 Explain the concept of a reaction mechanism. Include: rate-determining step
4.
What is a reaction mechanism?
5.
Why is a bimolecular step more reasonable than a termolecular step?
6.
Considerthe following mechanism:
Step 1: Clo laq) + H2O) → HCIO (aq) + OH (aq)
(Slow]
Step 2: l'(aq) + HCIO(ag) → HIO(aqg) + Cl (aq)
[Fast]
Step 3: OH (ag) + HIO(aq) → H2Om + 1O (aq)
[Fast]
а.
What is the overall equation?
b. Identify any intermediates
C.
What is the rate determining step? Why did you choose this step?
d. In which step is the catalyst placed? Why is it put in this step?
е.
Predict and explain the effect the following changes would have on the rate of the
reaction.
1 no we,
i.
Increasing the concentration of Clo-
ii.
Increasing the concentration of I-
for kit
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