1. Draw all resonance structures for the following molecules. CF3 a. b. 2. Rank the following anions from most to least stable. d. a. 3. Explain what atomic and electronic effects stabilize the electrons in the most stable anion from question 2. 4. Draw the proper products for the following acid/base reaction, with diisopropylamide (1) acting as a base, and cyclohexanone (II) acting as an acid in the forward direction. I II 5. For the reaction in Problem 4, in which direction would the equilibrium favor based on thermodynamics (anion stability)? Toward the starting materials, (Keq <1, AG > 0) or toward the products (Keq > 1, AG < 0)? Explain your answer in terms of relative conjugate base stability.

1. Draw all resonance structures for the following molecules. CF3 a. b. 2. Rank the following anions from most to least stable. d. a. 3. Explain what atomic and electronic effects stabilize the electrons in the most stable anion from question 2. 4. Draw the proper products for the following acid/base reaction, with diisopropylamide (1) acting as a base, and cyclohexanone (II) acting as an acid in the forward direction. I II 5. For the reaction in Problem 4, in which direction would the equilibrium favor based on thermodynamics (anion stability)? Toward the starting materials, (Keq <1, AG > 0) or toward the products (Keq > 1, AG < 0)? Explain your answer in terms of relative conjugate base stability.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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