1. Dehydration: ● ● • 2. Oxidation: ALCOHOLS This is a reaction where an alcohol loses a water molecule to form an alkene. ● Types of Reaction(s) For example, when ethanol is treated with an acidic catalyst, such as sulfuric acid, it undergoes dehydration to form ethene (CH2=CH2) and water. In this reaction, an alcohol is converted to either a carbonyl compound or a carboxylic acid. .. For example, primary alcohols can be oxidized to aldehydes or carboxylic acids, while secondary alcohols can be oxidized to ketones. Tertiary alcohols are usually not affected by oxidations 3. Esterification: 0 The conversion of an alcohol and a carboxylic acid to an ester and water, in the presence of an acid catalyst. The reaction between methanol and acetic acid to form methyl acetate: CH3OH + CH3COOH CH3COOCH3 + H2O 4. Substitution: Substitution reactions in organic chemistry involve the replacement of one atom or group of atoms with another atom or group of atoms in a molecule. 1. Cleavage reactions: ● Ethers can be cleaved by strong acids, such as HBr or Hi, to form alkyl halides and alcohols. 2. Williamson ether synthesis: ETHERS This is a method for the synthesis of ethers by the reaction of a alkoxide ion with an alkyl hallde. 3. Acid-catalyzed dehydration: An ether is converted into an alkene by the elimination of a wa molecule under acidic conditions. 4. Oxidation: Ethers can be oxidized with strong oxidizing agents, such as peracids or chromium reagents, to form carbonyl compounds. However, ethers are generally less prone to oxidation compare to alcohols
1. Dehydration: ● ● • 2. Oxidation: ALCOHOLS This is a reaction where an alcohol loses a water molecule to form an alkene. ● Types of Reaction(s) For example, when ethanol is treated with an acidic catalyst, such as sulfuric acid, it undergoes dehydration to form ethene (CH2=CH2) and water. In this reaction, an alcohol is converted to either a carbonyl compound or a carboxylic acid. .. For example, primary alcohols can be oxidized to aldehydes or carboxylic acids, while secondary alcohols can be oxidized to ketones. Tertiary alcohols are usually not affected by oxidations 3. Esterification: 0 The conversion of an alcohol and a carboxylic acid to an ester and water, in the presence of an acid catalyst. The reaction between methanol and acetic acid to form methyl acetate: CH3OH + CH3COOH CH3COOCH3 + H2O 4. Substitution: Substitution reactions in organic chemistry involve the replacement of one atom or group of atoms with another atom or group of atoms in a molecule. 1. Cleavage reactions: ● Ethers can be cleaved by strong acids, such as HBr or Hi, to form alkyl halides and alcohols. 2. Williamson ether synthesis: ETHERS This is a method for the synthesis of ethers by the reaction of a alkoxide ion with an alkyl hallde. 3. Acid-catalyzed dehydration: An ether is converted into an alkene by the elimination of a wa molecule under acidic conditions. 4. Oxidation: Ethers can be oxidized with strong oxidizing agents, such as peracids or chromium reagents, to form carbonyl compounds. However, ethers are generally less prone to oxidation compare to alcohols
Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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