1. Consider this system at equilibrium: C,„H,„O,,(s) + 120,(g) → 12CO,(g)+ 11H,0(1) Which of the following stresses will shift the equilibrium to the right? I. Decreasing temperature II. Increasing volume III. Adding oxygen IV. Removing water V. Adding an inert gas VI. Adding a catalyst

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### Chemical Equilibrium and Reaction Kinetics

1. **Consider the system at equilibrium:**
   
   \[
   C_{12}H_{22}O_{11(s)} + 12O_{2(g)} \leftrightarrow 12CO_{2(g)} + 11H_2O_{(l)}
   \]
   
   **Which of the following stresses will shift the equilibrium to the right?**

   - I. Decreasing temperature
   - II. Increasing volume
   - III. Adding oxygen
   - IV. Removing water
   - V. Adding an inert gas
   - VI. Adding a catalyst

   **Options:**
   - a. I, III
   - b. II, IV, VI
   - c. III, IV, V
   - d. I, II, III, VI

2. **Kinetics of the Reaction:**
   
   **Reaction:**
   \[
   A + 2B \rightarrow 3C + \frac{1}{2} D
   \]
   
   If the rate of change of reactant B is 0.50 M/min, what is the rate of change of C?
   
   **Options:**
   - a. 0.25 M/min
   - b. 0.33 M/min
   - c. 0.50 M/min
   - d. 0.75 M/min

3. **Decomposition of Reactant A:**
   
   An experiment involving the decomposition of reactant A was performed using three different initial concentrations of A. The half-life was found to double as the concentration was halved. What is the order of reaction?

   **Options:**
   - a. 0\(^\text{th}\)
   - b. 1\(^\text{st}\)
   - c. 2\(^\text{nd}\)
   - d. -1\(^\text{st}\)

4. **Concentration-Time Plot:**
   
   The figure below shows the concentration-time plot for the consecutive reactions:
   
   \[
   A \xrightarrow{k_1} B \xrightarrow{k_2} C
   \]
   
   **Graph Description:**
   
   - **X-axis**: Time (seconds).
   - **Y-axis**: Concentration (arbitrary units).
Transcribed Image Text:### Chemical Equilibrium and Reaction Kinetics 1. **Consider the system at equilibrium:** \[ C_{12}H_{22}O_{11(s)} + 12O_{2(g)} \leftrightarrow 12CO_{2(g)} + 11H_2O_{(l)} \] **Which of the following stresses will shift the equilibrium to the right?** - I. Decreasing temperature - II. Increasing volume - III. Adding oxygen - IV. Removing water - V. Adding an inert gas - VI. Adding a catalyst **Options:** - a. I, III - b. II, IV, VI - c. III, IV, V - d. I, II, III, VI 2. **Kinetics of the Reaction:** **Reaction:** \[ A + 2B \rightarrow 3C + \frac{1}{2} D \] If the rate of change of reactant B is 0.50 M/min, what is the rate of change of C? **Options:** - a. 0.25 M/min - b. 0.33 M/min - c. 0.50 M/min - d. 0.75 M/min 3. **Decomposition of Reactant A:** An experiment involving the decomposition of reactant A was performed using three different initial concentrations of A. The half-life was found to double as the concentration was halved. What is the order of reaction? **Options:** - a. 0\(^\text{th}\) - b. 1\(^\text{st}\) - c. 2\(^\text{nd}\) - d. -1\(^\text{st}\) 4. **Concentration-Time Plot:** The figure below shows the concentration-time plot for the consecutive reactions: \[ A \xrightarrow{k_1} B \xrightarrow{k_2} C \] **Graph Description:** - **X-axis**: Time (seconds). - **Y-axis**: Concentration (arbitrary units).
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