1. Benzene has a vapor pressure of 0.127 bar at 298 K and an enthalpy of vaporization of 30.7 kJ mol-'. The CP,m values of the vapor and liquid phases are 82.4 and 136 J K' mol-" respectively. Calculate the vapor pressure of benzene (1) at 340 K assuming: a) AvapH does not vary with T b) AvapH(T) = AvapH(T,) + ACp(T – T.) (assuming Cp is independent of T).

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Chapter17: Spontaneity, Entropy, And Free Energy
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Problem 128IP: Some nonelectrolyte solute (molar mass = 142 g/mol) was dissolved in 150. mL of a solvent (density =...
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1. Benzene has a vapor pressure of 0.127 bar at 298 K and an enthalpy of vaporization of
30.7 kJ mol-'. The Cp,m Values of the vapor and liquid phases are 82.4 and 136 J K-' mol-l
respectively. Calculate the vapor pressure of benzene (1) at 340 K assuming:
a) AvapH does not vary with T
b) AvapH(T) = AvapH(T,)+ AGp(T – T.)
(assuming Cp is independent of T).
Transcribed Image Text:1. Benzene has a vapor pressure of 0.127 bar at 298 K and an enthalpy of vaporization of 30.7 kJ mol-'. The Cp,m Values of the vapor and liquid phases are 82.4 and 136 J K-' mol-l respectively. Calculate the vapor pressure of benzene (1) at 340 K assuming: a) AvapH does not vary with T b) AvapH(T) = AvapH(T,)+ AGp(T – T.) (assuming Cp is independent of T).
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