1. At a given pressure and temperature, the phase with the highest chemical potential will be the most stable. 2. At equilibrium, the chemical potential of a substance is the same in and throughout every phase present in the system. 3. If a solute follows Henry's Law, its activity coefficient must be 0.
1. At a given pressure and temperature, the phase with the highest chemical potential will be the most stable. 2. At equilibrium, the chemical potential of a substance is the same in and throughout every phase present in the system. 3. If a solute follows Henry's Law, its activity coefficient must be 0.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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
Transcribed Image Text:1. At a given pressure and temperature, the phase with the highest chemical potential will be
the most stable.
2. At equilibrium, the chemical potential of a substance is the same in and throughout every
phase present in the system.
3. If a solute follows Henry's Law, its activity coefficient must be 0.
4. The equilibrium constant, K, can be calculated from the measured standard cell potential
RT
In K.
vF
of an electrochemical cell according to the relationship: E
5. Degeneracies do not need to be accounted for when calculating the Boltzmann ratio
Ni/N; (i.e., the relative population of two states i and j).
6. The molecular partition function indicates the number of thermally accessible states at a
given temperature.
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