1. Assign priorities to these set of Substituents (in assigning priority write numbers 1,2,3,4 below the structure of the molecules on the space given) a) -QHum -CH2CH3, -CH=CH2 , -OCH2CH3 1 4 3 2 b) -NH2 , -NO2 , -NHCH3 , -C=N c) -CH2CH3 -CH2SH , -CH(CH3)2 -C=CH

1. Assign priorities to these set of Substituents (in assigning priority write numbers 1,2,3,4 below the structure of the molecules on the space given) a) -QHum -CH2CH3, -CH=CH2 , -OCH2CH3 1 4 3 2 b) -NH2 , -NO2 , -NHCH3 , -C=N c) -CH2CH3 -CH2SH , -CH(CH3)2 -C=CH

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

Chapter6: Alkanes & Alkenes

Section: Chapter Questions

Problem 21E

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Concept explainers

Alkanes and Cycloalkanes

Alkanes are saturated organic compounds which are made up of C and H atoms. Alkanes have the general formula of CnH2n+2. Alkane contains sp3 hybridized carbon atoms with four sigmas (σ) bonds & every hydrogen atom is connected with one of the carbon atoms. The size of the alkane could be determined by the number of carbon atoms located in it.

Question

1. Assign priorities to these set of Substituents
(in assigning priority write numbers 1,2,3,4 below the structure of the
molecules on the space given)
a) -QH. -CH2CH3 ,
-CH=CH2
-OCH2CH3
1
4
2
b) -NH2 , -NO2
-NHCH3 ,
-C=N
c) -CH2CH3
-CH2SH , -CH(CH3)2 , -C=CH
|
d) -QCL -NHC ,-QBr
-NHBr

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Assign priorities to these set of Substituents (in assigning priority write numbers 1,2,3,4 below the structure of the molecules on the space given). Give explanation.
1. Assign priorities to these set of Substituents (in assigning priority write numbers 1,2,3,4 below the structure of the molecules on the space given) a) CH -CH3 -ČOCH3 -coČCH3 b) -CH(CH3)2.. -C(CH3)3 , -CH2CH(CH3)2 ,-CH2C(CH3)3| c) -OCI. -NHCI ,-OBr -NHBr
1. Assign priorities to these set of Substituents e) -ОН, -СН2CH3 , -CH=CH2 -OCH2CH3 (in assigning priority write numbers 1,2,3,4 below the struc- ture of the molecules on the space given) f) -NH2 , -NO2 -NHCH3 , -C=N а) -CH-CH2ОH, -Br, -H, -СH2CНЗ g) -CH2CH3 -CH2SH , -CH(CH3)2 -C=CH b)-COОН, -СООСНЗ, -СH2ОН, -ОН оо c) -CH2NHCH3, -CH2NH2, -NH2, -CN -COCH, h) -CCH3 -COČCH3 d)-Br, -CH2Br, -CI, -CH2CI i) -СH(CH3)2 , -С(CHз)з -CH2CH(CH3)2 ,-CH2C(CH3)3 j) -OCI , -NHCI -OBr -NHBR
1. Assign priorities to these set of Substituents а. -ОН, -СН2CH3 , -CH=CH2 -OCH2CH3 b. -NH2 -NO2 -NHCH3 , -C=N с. -СH2CH3 -CH2SH , -CH(CH3)2 -C=CH d. CH COCH3 -coČCH3 e. -CH(CH3)2 , -C(CH3)3 , -CH2CH(CH3)2 ,-CH2C(CH3)3 f. -OCI , -NHCI -OBr -NHB. End of document I
Assign priorities to these set of Substituents
D. Rank (increasing) the substituents in each of the following sets: (а) -Н, -ОН, -ОСH3, -СH, (Б) -Вr, -СНз, -СНBr, -а (c) -CH=CH2, -CH(CH3)2, -C(CH3)3, -CH 2CH3
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Which of the following represents the correct Cahn-Ingold-Prelog priority ranking of C5H11 substituents (used to determine R/S configuration) from lowest to highest? A) CH3(CH2)4- B) (CH3)3CCH2- C) C3H7CH(CH3)- D) (CH3)2CHCH2CH2- O a. A
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Explain the answrs
9. Rank the following groups in order of decreasing the priority. (a) —СНз, —СН2CН3, —СH2CH2СН3, — (CН2)3СH3 (b) —СООН, -CH2OH, —Н, —СНО (с) —С-СН, —CH(CH:)2, —СH2CН3, —СН3СH2