1. Arrange these alcohols in order of increasing boiling point: 1-butanol (CH₂CH₂CH₂CH₂OH), 1-heptanol (CH CH CH CH CH CH CH OH), and 1-propanol (CH₂CH₂CH₂OH). 2. Which has the higher boiling point- butane (CH₂CH₂CH₂CH) or 1-propanol (CH CH₂CH₂OH)? 3. Arrange these alcohols in order of increasing solubility in water: 1-butanol (CH₂CH₂CH₂CH₂OH), methanol (CH₂OH), and 1-octanol (CH₂CH₂CH₂CH₂CH₂CH₂CH₂CH₂OH).

Introduction to General, Organic and Biochemistry
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Chapter14: Alcohols, Ethers, And Thiols
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Problem 14.48P: 14-48 Explain why methanethiol, CH3SH, has a lower boiling point (6°C) than methanol, CH3OH (65°C),...
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Answer the following exercises without consulting tables in the
text.
1. Arrange these alcohols in order of increasing boiling point:
(CH₂CH₂CH₂CH₂OH), 1-heptanol
1-butanol
(CH CH₂CH₂CH₂CH₂CH₂CH₂OH), and 1-propanol
(CH₂CH₂CH₂OH).
2. Which has the higher boiling point-
butane (CH CH₂CH₂CH) or 1-propanol (CH₂CH₂CH₂OH)?
3. Arrange these alcohols in order of increasing solubility in
water: 1-butanol (CH₂CH₂CH₂CH₂OH), methanol (CH₂OH),
and 1-octanol (CH₂CH₂CH₂CH₂CH₂CH₂CH₂CH₂OH).
4. Arrange these compounds in order of increasing solubility
in water: 1-butanol (CH₂CH₂CH₂CH₂OH), ethanol
(CH₂CH₂OH), and pentane (CH₂CH₂CH₂CH₂CH₂).
5. Which compound has the higher boiling point-
CH CH₂CH₂OCH CH or CH₂CH₂CH₂COOH? Explain.
6. Which compound has the higher boiling point-
CH CH CH CH CH OH or CH₂CH₂CH₂COOH? Explain.
7. Which compound is more soluble in water-CH₂COOH or
CH₂CH₂CH₂CH? Explain.
8. Which compound is more soluble in water-CH₂CH₂COOH
or CH₂CH₂CH₂CH₂CH₂COOH? Explain.
Transcribed Image Text:Answer the following exercises without consulting tables in the text. 1. Arrange these alcohols in order of increasing boiling point: (CH₂CH₂CH₂CH₂OH), 1-heptanol 1-butanol (CH CH₂CH₂CH₂CH₂CH₂CH₂OH), and 1-propanol (CH₂CH₂CH₂OH). 2. Which has the higher boiling point- butane (CH CH₂CH₂CH) or 1-propanol (CH₂CH₂CH₂OH)? 3. Arrange these alcohols in order of increasing solubility in water: 1-butanol (CH₂CH₂CH₂CH₂OH), methanol (CH₂OH), and 1-octanol (CH₂CH₂CH₂CH₂CH₂CH₂CH₂CH₂OH). 4. Arrange these compounds in order of increasing solubility in water: 1-butanol (CH₂CH₂CH₂CH₂OH), ethanol (CH₂CH₂OH), and pentane (CH₂CH₂CH₂CH₂CH₂). 5. Which compound has the higher boiling point- CH CH₂CH₂OCH CH or CH₂CH₂CH₂COOH? Explain. 6. Which compound has the higher boiling point- CH CH CH CH CH OH or CH₂CH₂CH₂COOH? Explain. 7. Which compound is more soluble in water-CH₂COOH or CH₂CH₂CH₂CH? Explain. 8. Which compound is more soluble in water-CH₂CH₂COOH or CH₂CH₂CH₂CH₂CH₂COOH? Explain.
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