1. An electron moving in a conjugated bond framework can be viewed as a particle in a box. An externally applied electric field of strength & interacts with the electron in a fashion described by the perturbation: V(r) = ee (x - 1) Where x is the position of the electron in the box, e is the electron charge, and Lis the length of the box. (a) Compute the first order correction to the energy (b) The first order correction to the wave-function (compute only the contribution to Y made by Y2)
1. An electron moving in a conjugated bond framework can be viewed as a particle in a box. An externally applied electric field of strength & interacts with the electron in a fashion described by the perturbation: V(r) = ee (x - 1) Where x is the position of the electron in the box, e is the electron charge, and Lis the length of the box. (a) Compute the first order correction to the energy (b) The first order correction to the wave-function (compute only the contribution to Y made by Y2)
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Transcribed Image Text:1. An electron moving in a conjugated bond framework can be viewed as a particle in a
box. An externally applied electric field of strength & interacts with the electron in a
fashion described by the perturbation:
V(r) = ee (x - 1)
Where x is the position of the electron in the box, e is the electron charge, and Lis
the length of the box.
(a) Compute the first order correction to the energy
(b) The first order correction to the wave-function (compute only the
contribution to Y made by Y2)
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