Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
Related questions
Question
Solve 1 please

Transcribed Image Text:English (Saudi Arabia)
measured a charge under the stripping curve of 3.71 x 103 coulombs.
1. According to the WHO, is the water safe to drink? Show all work.
Page 4 of 4
2. Could you experimentally determine if the water is safe to drink by setting
up a different electrochemical cell? This involves using a Pb wire and a
suitable reference electrode and measuring the equilibrium potential of
the Pb wire and the dissolved Pb²+ cations in the water sample? write a
few sentences fully explaining your thoughts.
MacBook Pro
Focus E
ER
E
I

Transcribed Image Text:English (Saudi Arabia)
20
F3
A.
Arizonium (Az) is a newly discovered element. Below is a Table (*note the units)
listing the chemical potentials at 298 K of the Az* cation, the Azo oxide and H₂O obtained
by first principles DFT calculations.
Dissolved substances
Az++
H+
Solid substances
Az
ΑΖΟ
Liquid substances
H₂O
μº chemical potential (calories/mole)
5,000
0
000
000
F4
0
-40,000
Construct the potential-pH diagram for Az for the concentration of Az²+ in the
electrolyte = 1M. Show all work and the equations used to construct the
diagram.
F5
-57,000
B.
Since 1993 the World Health Organization (WHO) has maintained that the
smallest maximum allowable level of lead in drinking water is 5µg/L. A colleague of yours
is collecting samples from the drinking water supply in a foreign country and is using an
electrochemical technique to determine the amount of Pb2+ cations in the water. He set
up an electrochemical cell of 1 L (liter) in volume and used the water sample containing
Pb²+ cations to electroplate Pb on to an inert gold cathode. The electroplating was
completed in 1 week. Then he stripped the metallic Pb from the gold surface and
measured a charge under the stripping curve of 3.71 x 103 coulombs.
MacBook Pro
N
F6
&
F7
*
DII
FB
F9
Focus E
E
I
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