1. A sample of pure sodium oxalate, Na,C2O4 , weighing 0.2856 g is dissolved in water, sulfuric acid is added, and the solution titrated at 70°C, requiring 45.12 mL of a KMNO4 solution. The end poin is overrun and back-titration is carried out with 1.74 mL of a 0.1032 N solution of oxalic acid. Calculate the normality of the KMNO4 solution. Hint: A redox reaction is involed between oxalate and permanganate. Look at the changes in oxidation state by determining the balanced redox reaction: 5C,0,2 + 2 MnO4 + 10H* → 10CO2 + 2MN2+ + 8H20

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EXERCISE II - 3
1. A sample of pure sodium oxalate, Na,C204 , weighing 0.2856 g is dissolved in water, sulfuric acid
is added, and the solution titrated at 70°C, requiring 45.12 mL of a KMNO4 solution. The end point
is overrun and back-titration is carried out with 1.74 mL of a 0.1032 N solution of oxalic acid.
Calculate the normality of the KMNO4 solution.
Hint: A redox reaction is involed between oxalate and permanganate. Look at the changes in
oxidation state by determining the balanced redox reaction:
+ 10H*
5C,0, +
2 MnO4
10CO2
+ 2MN2+
+ 8H20
->
2. A sample of pure sodium chloride (MW = EW = 58.44 ) weighing 0.2286 g is dissolved in water
and exactly 50.00 mL of silver nitrate solution is added to precipitate AgClI. The excess Ag*
is titrated with 12.56 mL of a 0.0986 N solution of KSCN. Calculate the normality of the AgNO,
solution.
Transcribed Image Text:EXERCISE II - 3 1. A sample of pure sodium oxalate, Na,C204 , weighing 0.2856 g is dissolved in water, sulfuric acid is added, and the solution titrated at 70°C, requiring 45.12 mL of a KMNO4 solution. The end point is overrun and back-titration is carried out with 1.74 mL of a 0.1032 N solution of oxalic acid. Calculate the normality of the KMNO4 solution. Hint: A redox reaction is involed between oxalate and permanganate. Look at the changes in oxidation state by determining the balanced redox reaction: + 10H* 5C,0, + 2 MnO4 10CO2 + 2MN2+ + 8H20 -> 2. A sample of pure sodium chloride (MW = EW = 58.44 ) weighing 0.2286 g is dissolved in water and exactly 50.00 mL of silver nitrate solution is added to precipitate AgClI. The excess Ag* is titrated with 12.56 mL of a 0.0986 N solution of KSCN. Calculate the normality of the AgNO, solution.
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