1. A sample of pure sodium oxalate, Na,C2O4 , weighing 0.2856 g is dissolved in water, sulfuric acid is added, and the solution titrated at 70°C, requiring 45.12 mL of a KMNO4 solution. The end poin is overrun and back-titration is carried out with 1.74 mL of a 0.1032 N solution of oxalic acid. Calculate the normality of the KMNO4 solution. Hint: A redox reaction is involed between oxalate and permanganate. Look at the changes in oxidation state by determining the balanced redox reaction: 5C,0,2 + 2 MnO4 + 10H* → 10CO2 + 2MN2+ + 8H20

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question
EXERCISE II - 3
1. A sample of pure sodium oxalate, Na,C204 , weighing 0.2856 g is dissolved in water, sulfuric acid
is added, and the solution titrated at 70°C, requiring 45.12 mL of a KMNO4 solution. The end point
is overrun and back-titration is carried out with 1.74 mL of a 0.1032 N solution of oxalic acid.
Calculate the normality of the KMNO4 solution.
Hint: A redox reaction is involed between oxalate and permanganate. Look at the changes in
oxidation state by determining the balanced redox reaction:
+ 10H*
5C,0, +
2 MnO4
10CO2
+ 2MN2+
+ 8H20
->
2. A sample of pure sodium chloride (MW = EW = 58.44 ) weighing 0.2286 g is dissolved in water
and exactly 50.00 mL of silver nitrate solution is added to precipitate AgClI. The excess Ag*
is titrated with 12.56 mL of a 0.0986 N solution of KSCN. Calculate the normality of the AgNO,
solution.
Transcribed Image Text:EXERCISE II - 3 1. A sample of pure sodium oxalate, Na,C204 , weighing 0.2856 g is dissolved in water, sulfuric acid is added, and the solution titrated at 70°C, requiring 45.12 mL of a KMNO4 solution. The end point is overrun and back-titration is carried out with 1.74 mL of a 0.1032 N solution of oxalic acid. Calculate the normality of the KMNO4 solution. Hint: A redox reaction is involed between oxalate and permanganate. Look at the changes in oxidation state by determining the balanced redox reaction: + 10H* 5C,0, + 2 MnO4 10CO2 + 2MN2+ + 8H20 -> 2. A sample of pure sodium chloride (MW = EW = 58.44 ) weighing 0.2286 g is dissolved in water and exactly 50.00 mL of silver nitrate solution is added to precipitate AgClI. The excess Ag* is titrated with 12.56 mL of a 0.0986 N solution of KSCN. Calculate the normality of the AgNO, solution.
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 2 steps with 2 images

Blurred answer
Knowledge Booster
Equilibrium Concepts in Analytical Chemistry
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY