1. 1. A tricritical point is a point in a phase diagram where a line of second-order critical points meets a line of first-order critical points. We can model this by consider a Landau-Ginsburg free energy density of the form fLG = am? + bm' + cm® where we must have c > 0 for stability but a and b can be negative as well as positive. (a) Show that a second-order transition occurs at a=0 when b>0. (b) Taking a>0 and b<0, sketch fLG at a point on the first-order line. Find the first-order line by solving fic(m) = 0 and fLG(m) = 0 simultaneously. (c) Where is the tricritical point in the (a, b) plane? Sketch the phase diagram in %3D %3D that plane, showing the 1st- and 2nd-order lines as well as the tricritcal point.

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1. 1. A tricritical point is a point in a phase diagram where a line of second-order
critical points meets a line of first-order critical points. We can model this by
consider a Landau-Ginsburg free energy density of the form
fLG = am? + bm“ + cm®
where we must have c > 0 for stability but a and b can be negative as well
as positive.
(a) Show that a second-order transition occurs at a=0 when b>0.
(b) Taking a>0 and b<0, sketch fiG at a point on the first-order line. Find the
first-order line by solving fiG(m) = 0 and fLc(m) = 0 simultaneously.
(c) Where is the tricritical point in the (a, b) plane? Sketch the phase diagram in
that plane, showing the 1st- and 2nd-order lines as well as the tricritcal point.
Transcribed Image Text:1. 1. A tricritical point is a point in a phase diagram where a line of second-order critical points meets a line of first-order critical points. We can model this by consider a Landau-Ginsburg free energy density of the form fLG = am? + bm“ + cm® where we must have c > 0 for stability but a and b can be negative as well as positive. (a) Show that a second-order transition occurs at a=0 when b>0. (b) Taking a>0 and b<0, sketch fiG at a point on the first-order line. Find the first-order line by solving fiG(m) = 0 and fLc(m) = 0 simultaneously. (c) Where is the tricritical point in the (a, b) plane? Sketch the phase diagram in that plane, showing the 1st- and 2nd-order lines as well as the tricritcal point.
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