1- Write Walden's Cycle of Reactions Interconverting. 2- Mention the product of a nucleophilic substitution reaction of (S)-2- bromohexane with acetate ion, CH3CO2- Assume that inversion of configuration occurs, and show the chemistry of both the reactant and product. 3- Draw the mechanism of the SN2 Reaction. Show the correct directions of the arrows, and all reagents. 4- Draw the mechanism of the SÃ1 Reaction. Show the correct directions of the arrows, and all reagents. 5- Draw the mechanism of the E2 Reaction with an Alkyl Halide. Show the correct directions of the arrows, and all reagents. 6- Draw the mechanism of the E1 Reaction with an Alkyl Halide. Show the correct directions of the arrows, and all reagents. 7- Mention the product formed in an SN2 reaction between 1- bromobutane and Nal. 8- Rank the following compounds in order of their expected reactivity toward SN2 reaction: CH3Br, CH3OTOS, (CH3)2CHC1. 9- Explain Grignard Reagents in details with one example. 10- Mention how a halogen substituent can be replaced by a deuterium atom in the preparation of a deuterated compound. Br I CH3CHCH₂CH3 ? D | CH3CHCH₂CH3

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Chapter1: Chemical Foundations
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Question 1.
1- Write Walden's Cycle of Reactions Interconverting.
2- Mention the product of a nucleophilic substitution reaction of (S)-2-
bromohexane with acetate ion, CH3CO2-
Assume that inversion of configuration occurs, and show the chemistry
of both the reactant and product.
3- Draw the mechanism of the SN2 Reaction. Show the correct directions
of the arrows, and all reagents.
4- Draw the mechanism of the SN1 Reaction. Show the correct directions
of the arrows, and all reagents.
5- Draw the mechanism of the E2 Reaction with an Alkyl Halide. Show
the correct directions of the arrows, and all reagents.
6- Draw the mechanism of the E1 Reaction with an Alkyl Halide. Show
the correct directions of the arrows, and all reagents.
7- Mention the product formed in an SÃ2 reaction between 1-
bromobutane and Nal.
8- Rank the following compounds in order of their expected reactivity
toward SN2 reaction: CH3Br, CH3OT0s, (CH3)2CHCI.
9- Explain Grignard Reagents in details with one example.
10-
Mention how a halogen substituent can be replaced by a
deuterium atom in the preparation of a deuterated compound.
Br
D
|
CH3CHCH₂CH3
?
CH3CHCH₂CH3
Transcribed Image Text:1- Write Walden's Cycle of Reactions Interconverting. 2- Mention the product of a nucleophilic substitution reaction of (S)-2- bromohexane with acetate ion, CH3CO2- Assume that inversion of configuration occurs, and show the chemistry of both the reactant and product. 3- Draw the mechanism of the SN2 Reaction. Show the correct directions of the arrows, and all reagents. 4- Draw the mechanism of the SN1 Reaction. Show the correct directions of the arrows, and all reagents. 5- Draw the mechanism of the E2 Reaction with an Alkyl Halide. Show the correct directions of the arrows, and all reagents. 6- Draw the mechanism of the E1 Reaction with an Alkyl Halide. Show the correct directions of the arrows, and all reagents. 7- Mention the product formed in an SÃ2 reaction between 1- bromobutane and Nal. 8- Rank the following compounds in order of their expected reactivity toward SN2 reaction: CH3Br, CH3OT0s, (CH3)2CHCI. 9- Explain Grignard Reagents in details with one example. 10- Mention how a halogen substituent can be replaced by a deuterium atom in the preparation of a deuterated compound. Br D | CH3CHCH₂CH3 ? CH3CHCH₂CH3
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Introduction

Walden's cycle of reactions is a series of chemical reactions that involve the interconversion of an alkyl halide, an organometallic compound, and an alcohol. The cycle is named after German chemist Paul Walden, who first described the reactions in 1896.

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