1) What type of crystal will each of the following substances form in its solid-state? Choices to consider are metallic, ionic, covalent, or molecular crystals. (a) C₂H6 (d) CO₂ (g) Al (b) Na₂O (e) N₂O5 (h) C(diamond). (c) SiO₂ (f) NaNO3 (I) SO₂

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1) What type of crystal will each of the following substances form in its solid-state?
Choices to consider are metallic, ionic, covalent, or molecular crystals.
(a) C₂H6
(d) CO₂
(g) Al
(h) C(diamond)
(b) Na₂O
(e) N₂O5
(c) SiO₂
(f) NaNO3
(I) SO₂
2) List the following substances in order of increasing boiling points: BaCl2, H₂, CO, HF,
Ne, CO₂
3)
Circle all the compounds in the following list which would be expected to form
intermolecular hydrogen bonds in the liquid state:
(a) CH3OCH, (dimethyl ether) (b) CH4
(c) HF
(f) CH3OH
(d) CH3CO₂H
(e) Br₂
4) Identify the most important types of intermolecular forces present in the solids of each of
the following substances.
a. Ar:
d.
CaCl₂:
g.
NaNO3:
b.
HCI:
e.
CH4:
h.
1₂:
C.
HF:
f.
CO:
i.
H₂O₂2:
5) Hydrogen peroxide (H₂O₂) is a syrupy liquid with relatively low vapor pressure and a
normal boiling point of 152.2°C. Rationalize the differences of these physical properties
from those of water
6) Why are heats of vaporization always larger than heats of fusion?
7) What are the four types of crystalline solids? Briefly explain each
8) Specify the predominant intermolecular force involved for each substance in the space
immediately following the substance. Then in the last column, indicate which member of
the pair you would expect to have the higher boiling point.
Transcribed Image Text:1) What type of crystal will each of the following substances form in its solid-state? Choices to consider are metallic, ionic, covalent, or molecular crystals. (a) C₂H6 (d) CO₂ (g) Al (h) C(diamond) (b) Na₂O (e) N₂O5 (c) SiO₂ (f) NaNO3 (I) SO₂ 2) List the following substances in order of increasing boiling points: BaCl2, H₂, CO, HF, Ne, CO₂ 3) Circle all the compounds in the following list which would be expected to form intermolecular hydrogen bonds in the liquid state: (a) CH3OCH, (dimethyl ether) (b) CH4 (c) HF (f) CH3OH (d) CH3CO₂H (e) Br₂ 4) Identify the most important types of intermolecular forces present in the solids of each of the following substances. a. Ar: d. CaCl₂: g. NaNO3: b. HCI: e. CH4: h. 1₂: C. HF: f. CO: i. H₂O₂2: 5) Hydrogen peroxide (H₂O₂) is a syrupy liquid with relatively low vapor pressure and a normal boiling point of 152.2°C. Rationalize the differences of these physical properties from those of water 6) Why are heats of vaporization always larger than heats of fusion? 7) What are the four types of crystalline solids? Briefly explain each 8) Specify the predominant intermolecular force involved for each substance in the space immediately following the substance. Then in the last column, indicate which member of the pair you would expect to have the higher boiling point.
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