Thermochemistry
Thermochemistry can be considered as a branch of thermodynamics that deals with the connections between warmth, work, and various types of energy, formed because of different synthetic and actual cycles. Thermochemistry describes the energy changes that occur as a result of reactions or chemical changes in a substance.
Exergonic Reaction
The term exergonic is derived from the Greek word in which ‘ergon’ means work and exergonic means ‘work outside’. Exergonic reactions releases work energy. Exergonic reactions are different from exothermic reactions, the one that releases only heat energy during the course of the reaction. So, exothermic reaction is one type of exergonic reaction. Exergonic reaction releases work energy in different forms like heat, light or sound. For example, a glow stick releases light making that an exergonic reaction and not an exothermic reaction since no heat is released. Even endothermic reactions at very high temperature are exergonic.
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tive enthalpy changes are exothermic.
mole. The enthalpy value is negative, which indicates a cooling process.
The calculation shows the molar enthalpy change has units of joules per
lpy change, use the equation AH = CAT.
final value,
initial valu-
Calculate.
than the fi
AH = CAT
(24.2 J/K•mol)(-15 K) = -360 J/mol
Verify your results.
PRACTICE
The molar heat capacity of Al(s) is 24.2 J/K•mol. Calculate the molar
onthalpy change when Al(s) is cooled from 128.5°C to 22.6°C.
Lead has a molar heat capacity of 26.4 J/K•mol. What molar enthalpy
PRO
SO
S
change occurs when lead is cooled from 302°C to 275°C?
3 Calculate the molar enthalpy change when mercury is cooled 10 K.
The molar heat capacity of mercury is 27.8 J/K•mol.
Enthalpy Changes of Endothermic or Exothermic Processes
Notice the molar enthalpy change for Sample Problem B. This enthalpy change
is positive, which means that the heating of a sample requires energy. So, the
heating of a sample is an endothermic process. In contrast, the cooling of a sam-
ple releases energy or has a negative enthalpy change and is an exothermic
process, such as the process in Sample Problem C. In fact, you can use enthalpy
Changes to determine if a process is endothermic or exothermic. Processes that
ave positive enthalpy changes are endothermic and processes that have nega-"
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