1 The following reaction schemes show possible mechanisms for the overall reaction: catalyst A + E Scheme 1 Scheme 2 Scheme 3 slow fast (i) A+B C fast (i) A+BO" C (i) A+BasC fast fast slow (ii) C, D + B (ii) C +D+B (ii) C →D+ B fast (iii) D+Ea,F slow (iii) D+EO",F fast (iii) D+E ,F fast slow fast |(iv) F- (iv) F (iv) F In Scheme 2, which species is the catalyst? b Which species cannot appear in the rate expression for Scheme 1? Which is the rate-determining step in Scheme 3?

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Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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1 The following reaction schemes show possible mechanisms for the
overall reaction:
catalyst
A + E
Scheme 1
Scheme 2
Scheme 3
slow
() A+B
fast
(i) A+B*C
fast
(i) A+B
, C
fast
(ii) Ca, D + B
fast
(ii) C-
+D + B
(ii) C
slow
+D+ B
fast
(iii) D+E
slow
(iii) D+EOW, F
fast
(iii) D+Ea +F
fast
fast
(iv) Fas,G
slow
(iv) F-
+G
(iv) F.
a In Scheme 2, which species is the catalyst?
b Which species cannot appear in the rate expression for
Scheme 1?
c Which is the rate-determining step in Scheme 3?
Transcribed Image Text:1 The following reaction schemes show possible mechanisms for the overall reaction: catalyst A + E Scheme 1 Scheme 2 Scheme 3 slow () A+B fast (i) A+B*C fast (i) A+B , C fast (ii) Ca, D + B fast (ii) C- +D + B (ii) C slow +D+ B fast (iii) D+E slow (iii) D+EOW, F fast (iii) D+Ea +F fast fast (iv) Fas,G slow (iv) F- +G (iv) F. a In Scheme 2, which species is the catalyst? b Which species cannot appear in the rate expression for Scheme 1? c Which is the rate-determining step in Scheme 3?
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