1) Sodium reacts violently with water according to the equation: 2 Na(s) + 2 H20(1) - 2 NaOH(aq) + H2(g) The resulting solution has a higher temperature after the reaction. What are the signs of AH® and AS for this reaction? A) AH® is negative and AS° is negative. C) AH® is positive and AS° is negative. B) AH® is negative and AS° is positive. D) AH° is positive and ASº is positive.
Thermochemistry
Thermochemistry can be considered as a branch of thermodynamics that deals with the connections between warmth, work, and various types of energy, formed because of different synthetic and actual cycles. Thermochemistry describes the energy changes that occur as a result of reactions or chemical changes in a substance.
Exergonic Reaction
The term exergonic is derived from the Greek word in which ‘ergon’ means work and exergonic means ‘work outside’. Exergonic reactions releases work energy. Exergonic reactions are different from exothermic reactions, the one that releases only heat energy during the course of the reaction. So, exothermic reaction is one type of exergonic reaction. Exergonic reaction releases work energy in different forms like heat, light or sound. For example, a glow stick releases light making that an exergonic reaction and not an exothermic reaction since no heat is released. Even endothermic reactions at very high temperature are exergonic.
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1) Sodium reacts violently with water according to the equation:
2 Na(s) + 2 H20(I) -2 NaOH(aq) + H2(g)
1)
The resulting solution has a higher temperature after the reaction. What are the signs of AH° and
AS° for this reaction?
A) AH° is negative and AS° is negative.
C) AH° is positive and AS° is negative.
B) AH° is negative and AS° is positive.
D) AH° is positive and AS° is positive.
2) Consider a reaction that has a negative AH and a positive AS. Which of the following statements is
TRUE?
2)
A) This reaction will be spontaneous at all temperatures.
B) This reaction will be nonspontaneous at all temperatures.
C) This reaction will be nonspontaneous only at high temperatures.
D) This reaction will be spontaneous only at high temperatures.
3) Consider the reaction:
3)
N2(8) + 3 F2(g) -2 NF3(g)
AH° = -249 kJ and AS° = -278 J/K at 25°C
Calculate AG° and state whether the equilibrium composition should favor reactants or
products at standard conditions.
4) Calculate the AG°rxn using the following information.
4)
2 HNO3(aq) + NO(g) -3 NO2(g) + H2O(1)
AH°F (kJ/mol)
-207
91.3
33.2
-285.8
S°J/mol K)
146
210.8
240.1
70.0
5) Calculate AGxn at 298 K under the conditions shown below for the following reaction.
5)
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