1) Rationalize the region-selectivity of the following addition reactions ے والا

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Q1
1)
2)
3)
4)
D)
A)
8)
C)
Rationalize the region-selectivity of the following addition reactions
()
Boy
Give the expected products of the reaction of pent-1-ene with the following reagents,
paying attention to the expected regioselectivity (answer 2 of the 4)
(a) Bry in CC
(b) HB
(c) Brin Me
Jempio can be prepared through the hydration of (R)-limonene as shown below
Limonene
(a) Draw an arrow-pushing mechanism for this transformation
(b) Would you expect tegpin to be optically active? Justify your reasoning
5) Predict the major products for the following reactions.
Show the stereochemistry.
The following reaction is an example of iodolactonisation Using your knowledge of the
addition of halogens to alkenes, propose a mechanism for this transformation Based
upon your mechanism, which diastereoisomer of product (3 or 4) is expected?
4
CO₂H
Br₂ CCI
NHỌC,
Br₂. CH₂OH
H₂SO, HO
KMnO₂
KOH, Cold
H₂SO₂
H₂O
HBr
KMnO
KOH, Cold
Transcribed Image Text:1) 2) 3) 4) D) A) 8) C) Rationalize the region-selectivity of the following addition reactions () Boy Give the expected products of the reaction of pent-1-ene with the following reagents, paying attention to the expected regioselectivity (answer 2 of the 4) (a) Bry in CC (b) HB (c) Brin Me Jempio can be prepared through the hydration of (R)-limonene as shown below Limonene (a) Draw an arrow-pushing mechanism for this transformation (b) Would you expect tegpin to be optically active? Justify your reasoning 5) Predict the major products for the following reactions. Show the stereochemistry. The following reaction is an example of iodolactonisation Using your knowledge of the addition of halogens to alkenes, propose a mechanism for this transformation Based upon your mechanism, which diastereoisomer of product (3 or 4) is expected? 4 CO₂H Br₂ CCI NHỌC, Br₂. CH₂OH H₂SO, HO KMnO₂ KOH, Cold H₂SO₂ H₂O HBr KMnO KOH, Cold
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