1) Presented below are three proposed synthetic schemes to make the target compound of 1- deutero-1-butynę. Of these three proposed schemes, only one will produce the target compound in a high yield. a) Identify the two flawed synthetic schemes. b) For each flawed synthetic scheme, Identify all of the errors. For each error, explain why this error would cause a drastic decrease in the yield of the target compound.
1) Presented below are three proposed synthetic schemes to make the target compound of 1- deutero-1-butynę. Of these three proposed schemes, only one will produce the target compound in a high yield. a) Identify the two flawed synthetic schemes. b) For each flawed synthetic scheme, Identify all of the errors. For each error, explain why this error would cause a drastic decrease in the yield of the target compound.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:1) Presented below are three proposed synthetic schemes to make the target compound of 1-
deutero-1-butyne. Of these three proposed schemes, only one will produce the target
compound in a high yield.
a) Identify the two flawed synthetic schemes.
b) For each flawed synthetic scheme,
Identify all of the errors.
For each error, explain why this error would cause a drastic decrease in the yield of
the target compound.
1) NaH/CH3OH.
2) CH3CH2B
D NaH /CH3OH, CHe CH2C=CD
2) D20
HCECH
CH3CH2C =CH
) NaH / Ether
2) CH3CH2 Br
1) NaH/Ether
2) D20
HC=CH
CH3CH2C=CH
→ CH3 CH2C=CD
HC=CHDNAH/Ether
2) DzO
DNAH/ Ether, CHSCH_C=CD
2) CH3CH2B
→ HC=CD
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