1 H₂C-Br + N3 2 H₂C-Br + N3 2 CI EtOH CI DMSO + ОН CH3N3 + Br CH3N3+ Br acetone +HCN- acetone +CI OH CN + HCI

Chemistry
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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Each pair of reactions, 1 and 2, will both go by the same mechanism, Sn1 or S2, say which. Explain why your choice of mechanism. Also, say which of the two in each you expect to go faster, or the same, and explain why your choice goes faster.

### Chemical Reactions Involving Alkyl Halides

#### Substitution Reactions

1. **Reaction 1:**
   - **Reactants:** 
     - Alkyl bromide: \[ \text{H}_3\text{C}-\text{Br} + \text{N}_3^- \]
   - **Solvent:** 
     - Ethanol (\[ \text{EtOH} \])
   - **Products:** 
     - Azide compound: \[ \text{CH}_3\text{N}_3 + \text{Br}^- \]
   
2. **Reaction 2:**
   - **Reactants:** 
     - Alkyl bromide: \[ \text{H}_3\text{C}-\text{Br} + \text{N}_3^- \]
   - **Solvent:** 
     - Dimethyl sulfoxide (\[ \text{DMSO} \])
   - **Products:** 
     - Azide compound: \[ \text{CH}_3\text{N}_3 + \text{Br}^- \]

#### Nucleophilic Substitution Reactions

1. **Reaction 1:**
   - **Reactants:** 
     - Cyclopentyl chloride \[ \text{Cl} \] compound and hydroxide ion \[ \text{OH}^- \]
   - **Conditions:** 
     - Solvent: Acetone
   - **Products:** 
     - Cyclopentanol (with OH group)
     - Chloride ion \[ \text{Cl}^- \]

2. **Reaction 2:**
   - **Reactants:** 
     - Cyclopentyl chloride \[ \text{Cl} \] compound and hydrogen cyanide \[ \text{HCN} \]
   - **Conditions:** 
     - Solvent: Acetone
   - **Products:** 
     - Nitrile compound with CN group
     - Hydrochloric acid (HCl)

### Diagram Explanation

The diagram presents two sections with several chemical reactions showcasing examples of nucleophilic substitution reactions. The top section highlights two similar reactions where a bromide reacts with an azide ion in different solvents. The lower section illustrates substitution reactions involving cyclopentyl chlorides reacting with different nucleophiles leading to alcohol and nitrile products, replacing the chloride group.
Transcribed Image Text:### Chemical Reactions Involving Alkyl Halides #### Substitution Reactions 1. **Reaction 1:** - **Reactants:** - Alkyl bromide: \[ \text{H}_3\text{C}-\text{Br} + \text{N}_3^- \] - **Solvent:** - Ethanol (\[ \text{EtOH} \]) - **Products:** - Azide compound: \[ \text{CH}_3\text{N}_3 + \text{Br}^- \] 2. **Reaction 2:** - **Reactants:** - Alkyl bromide: \[ \text{H}_3\text{C}-\text{Br} + \text{N}_3^- \] - **Solvent:** - Dimethyl sulfoxide (\[ \text{DMSO} \]) - **Products:** - Azide compound: \[ \text{CH}_3\text{N}_3 + \text{Br}^- \] #### Nucleophilic Substitution Reactions 1. **Reaction 1:** - **Reactants:** - Cyclopentyl chloride \[ \text{Cl} \] compound and hydroxide ion \[ \text{OH}^- \] - **Conditions:** - Solvent: Acetone - **Products:** - Cyclopentanol (with OH group) - Chloride ion \[ \text{Cl}^- \] 2. **Reaction 2:** - **Reactants:** - Cyclopentyl chloride \[ \text{Cl} \] compound and hydrogen cyanide \[ \text{HCN} \] - **Conditions:** - Solvent: Acetone - **Products:** - Nitrile compound with CN group - Hydrochloric acid (HCl) ### Diagram Explanation The diagram presents two sections with several chemical reactions showcasing examples of nucleophilic substitution reactions. The top section highlights two similar reactions where a bromide reacts with an azide ion in different solvents. The lower section illustrates substitution reactions involving cyclopentyl chlorides reacting with different nucleophiles leading to alcohol and nitrile products, replacing the chloride group.
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