1) a) When CO becomes coordinated to BH3, its stretching frequency increases, but when CO is coordinated to Ni(CO)3, its stretching frequency decreases. Explain. b) Does the stretching frequency of CO increase of decrease when (explain too) i) L of LM-CO becomes more electron withdrawing. ii) CO of L M-CO becomes coordinated to a Lewis acid, A, to become LÂM-CO-A 18
1) a) When CO becomes coordinated to BH3, its stretching frequency increases, but when CO is coordinated to Ni(CO)3, its stretching frequency decreases. Explain. b) Does the stretching frequency of CO increase of decrease when (explain too) i) L of LM-CO becomes more electron withdrawing. ii) CO of L M-CO becomes coordinated to a Lewis acid, A, to become LÂM-CO-A 18
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:1) a) When CO becomes coordinated to BH3, its
stretching frequency increases, but when CO is
coordinated to Ni(CO)3, its stretching frequency
decreases. Explain.
b) Does the stretching frequency of CO increase
of decrease when (explain too)
i) L of L M-CO becomes more electron
withdrawing.
ii) CO of L₁M-CO becomes coordinated to a
Lewis acid, A, to become LM-CO-A 18
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