1) a) When CO becomes coordinated to BH3, its stretching frequency increases, but when CO is coordinated to Ni(CO)3, its stretching frequency decreases. Explain. b) Does the stretching frequency of CO increase of decrease when (explain too) i) L of LM-CO becomes more electron withdrawing. ii) CO of L M-CO becomes coordinated to a Lewis acid, A, to become LÂM-CO-A 18

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Chapter1: Chemical Foundations
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1) a) When CO becomes coordinated to BH3, its
stretching frequency increases, but when CO is
coordinated to Ni(CO)3, its stretching frequency
decreases. Explain.
b) Does the stretching frequency of CO increase
of decrease when (explain too)
i) L of L M-CO becomes more electron
withdrawing.
ii) CO of L₁M-CO becomes coordinated to a
Lewis acid, A, to become LM-CO-A 18
Transcribed Image Text:1) a) When CO becomes coordinated to BH3, its stretching frequency increases, but when CO is coordinated to Ni(CO)3, its stretching frequency decreases. Explain. b) Does the stretching frequency of CO increase of decrease when (explain too) i) L of L M-CO becomes more electron withdrawing. ii) CO of L₁M-CO becomes coordinated to a Lewis acid, A, to become LM-CO-A 18
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