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1) A Ni(II)L complex displays a reduction potential for the Ni(II/1) couple at -0.52 and a Ni(1/0) couple at -1.04 V, shown below. Ni(II)L + e- > Ni(1)L E°= -0.52 V Ni(1)L + e- > Ni(0)L E°= -1.04 V The following reductants and their formal potentials are given below. (Reductant) + e → (Reductant)" E°(V) Reductant E° (V) [CoCp2*]2 Fe(CO)2Cp] -1.91 -1.8 [FeCp*2] -0.59 NEt3 0.47 a) Which of the following reductants could you use to reduce the Ni(I)L complex by 1 e to give Ni(1)L. b) Which of the following reductants could you use to reduce the Ni(1)L complex by 1 e to give Ni(0)L.

1) A Ni(II)L complex displays a reduction potential for the Ni(II/1) couple at -0.52 and a Ni(1/0) couple at -1.04 V, shown below. Ni(II)L + e- > Ni(1)L E°= -0.52 V Ni(1)L + e- > Ni(0)L E°= -1.04 V The following reductants and their formal potentials are given below. (Reductant) + e → (Reductant)" E°(V) Reductant E° (V) [CoCp2*]2 Fe(CO)2Cp] -1.91 -1.8 [FeCp*2] -0.59 NEt3 0.47 a) Which of the following reductants could you use to reduce the Ni(I)L complex by 1 e to give Ni(1)L. b) Which of the following reductants could you use to reduce the Ni(1)L complex by 1 e to give Ni(0)L.

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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1) A Ni(II)L complex displays a reduction potential for the Ni(II/1) couple at -0.52 and a Ni(1/0) couple at -1.04 V, shown below. Ni(II)L + e- > Ni(1)L E°= -0.52 V Ni(1)L + e- > Ni(0)L E°= -1.04 V The following reductants and their formal potentials are given below. (Reductant) + e → (Reductant)" E°(V) Reductant E° (V) [CoCp2*]2 Fe(CO)2Cp] -1.91 -1.8 [FeCp*2] -0.59 NEt3 0.47 a) Which of the following reductants could you use to reduce the Ni(I)L complex by 1 e to give Ni(1)L. b) Which of the following reductants could you use to reduce the Ni(1)L complex by 1 e to give Ni(0)L.
Transcribed Image Text:1) A Ni(II)L complex displays a reduction potential for the Ni(II/1) couple at -0.52 and a Ni(1/0) couple at -1.04 V, shown below. Ni(II)L + e- > Ni(1)L E°= -0.52 V Ni(1)L + e- > Ni(0)L E°= -1.04 V The following reductants and their formal potentials are given below. (Reductant) + e → (Reductant)" E°(V) Reductant E° (V) [CoCp2*]2 Fe(CO)2Cp] -1.91 -1.8 [FeCp*2] -0.59 NEt3 0.47 a) Which of the following reductants could you use to reduce the Ni(I)L complex by 1 e to give Ni(1)L. b) Which of the following reductants could you use to reduce the Ni(1)L complex by 1 e to give Ni(0)L.
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