(1) A 1.475 g containing NH,CI (FM 53.492), K¿CO, (FM 138.21), and other impurities was dissolved to give 100.0 mL solution (Solution A). A 25.0 mL portion from this solution was acidified and treated with excess tetraphenylborate, Na'B(C,Hs);', to precipitate K and NH, ions completely: Deactant pec B(C,Hs), + K* (FM 358.33) NH,- EM 337.27) KB(C,Hg)4 B(C,H), NH,B(C,Hs), The resultant precipitate weighed 0.617 g. A fresh 50.0 mL portion of the original solution (Solution A) was made alkaline and heated to remove NH, as NH3: to tinct of ko NH, + OH It was then acidified and treated with tetraphenylborate to give 0.554 g precipitate. Find the weight percent NH,Cl and K;CO, in the original solid. NH,

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(1) A 1.475 g containing NH,CI (FM 53.492), K;CO; (FM 138.21), and other impurities was
dissolved to give 100.0 mL solution (Solution A). A 25.0 mL portion from this solution was
acidified and treated with excess tetraphenylborate, Na'B(C,Hs);, to precipitate (K) and
NH, ions completely:
Deactant
pect
B(C,H), + (K*
(FM 358.33)
B(C,H3), + \NH,*/→
FM 337.27)
KB(C,Hs)4
NH,B(C,Hs)4
The resultant precipitate weighed 0.617 g.
A fresh 50.0 mL portion of the original solution (Solution A) was made alkaline and heated
to remove NH,"as NH3:
to tindt of ko3
NH, + OH →
It was then acidified and treated with tetraphenylborate to give 0.554 g precipitate. Find the
weight percent NH,Cl and K;CO, in the original solid.
NH3
Transcribed Image Text:(1) A 1.475 g containing NH,CI (FM 53.492), K;CO; (FM 138.21), and other impurities was dissolved to give 100.0 mL solution (Solution A). A 25.0 mL portion from this solution was acidified and treated with excess tetraphenylborate, Na'B(C,Hs);, to precipitate (K) and NH, ions completely: Deactant pect B(C,H), + (K* (FM 358.33) B(C,H3), + \NH,*/→ FM 337.27) KB(C,Hs)4 NH,B(C,Hs)4 The resultant precipitate weighed 0.617 g. A fresh 50.0 mL portion of the original solution (Solution A) was made alkaline and heated to remove NH,"as NH3: to tindt of ko3 NH, + OH → It was then acidified and treated with tetraphenylborate to give 0.554 g precipitate. Find the weight percent NH,Cl and K;CO, in the original solid. NH3
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