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01. Of the following statements, which are true for nucleophilic substitutions occurring by the SN1 mechanism? Write T or F only in the space provided after each statement. a. Primary alkyl halides react faster than secondary. b. The absolute configuration of the product is opposite to that of the reactant if an optically active substrate is used. c. The intermolecular reaction shows second order kinetics. d. The rate of the reaction depends on the nucleophilicity of the attacking nucleophile. e. The probable mechanism involves only one step. f. Carbocations are intermediates. g. The rate of the reaction does not depend on the nature of the leaving group. h. The rate is usually faster in polar, protic solvents. i. Branching at the B-carbon has little or no effect on the rate of the reaction. j. Hyperconjugation is mainly responsible for stabilizing the intermediate.

01. Of the following statements, which are true for nucleophilic substitutions occurring by the SN1 mechanism? Write T or F only in the space provided after each statement. a. Primary alkyl halides react faster than secondary. b. The absolute configuration of the product is opposite to that of the reactant if an optically active substrate is used. c. The intermolecular reaction shows second order kinetics. d. The rate of the reaction depends on the nucleophilicity of the attacking nucleophile. e. The probable mechanism involves only one step. f. Carbocations are intermediates. g. The rate of the reaction does not depend on the nature of the leaving group. h. The rate is usually faster in polar, protic solvents. i. Branching at the B-carbon has little or no effect on the rate of the reaction. j. Hyperconjugation is mainly responsible for stabilizing the intermediate.

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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01. Of the following statements, which are true for nucleophilic substitutions occurring by the SN1 mechanism? Write T or F only in the space provided after each statement. a. Primary alkyl halides react faster than secondary. b. The absolute configuration of the product is opposite to that of the reactant if an optically active substrate is used. c. The intermolecular reaction shows second order kinetics. d. The rate of the reaction depends on the nucleophilicity of the attacking nucleophile. e. The probable mechanism involves only one step. f. Carbocations are intermediates. g. The rate of the reaction does not depend on the nature of the leaving group. h. The rate is usually faster in polar, protic solvents. i. Branching at the B-carbon has little or no effect on the rate of the reaction. j. Hyperconjugation is mainly responsible for stabilizing the intermediate.
Transcribed Image Text:01. Of the following statements, which are true for nucleophilic substitutions occurring by the SN1 mechanism? Write T or F only in the space provided after each statement. a. Primary alkyl halides react faster than secondary. b. The absolute configuration of the product is opposite to that of the reactant if an optically active substrate is used. c. The intermolecular reaction shows second order kinetics. d. The rate of the reaction depends on the nucleophilicity of the attacking nucleophile. e. The probable mechanism involves only one step. f. Carbocations are intermediates. g. The rate of the reaction does not depend on the nature of the leaving group. h. The rate is usually faster in polar, protic solvents. i. Branching at the B-carbon has little or no effect on the rate of the reaction. j. Hyperconjugation is mainly responsible for stabilizing the intermediate.
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