0.1 g of a sample of coal was used in a bomb calorimeter for the determination of calorific value. The ash formed was extracted with acid and the acid extract was heated with BaCl2 solution and a precipitate of BaSO4 was obtained. The precipitate was filtered, dried and weighed. The weight of precipitate was found to be 0.01 g. Calculate the percentage of sulfur in the coal sample.
Thermochemistry
Thermochemistry can be considered as a branch of thermodynamics that deals with the connections between warmth, work, and various types of energy, formed because of different synthetic and actual cycles. Thermochemistry describes the energy changes that occur as a result of reactions or chemical changes in a substance.
Exergonic Reaction
The term exergonic is derived from the Greek word in which ‘ergon’ means work and exergonic means ‘work outside’. Exergonic reactions releases work energy. Exergonic reactions are different from exothermic reactions, the one that releases only heat energy during the course of the reaction. So, exothermic reaction is one type of exergonic reaction. Exergonic reaction releases work energy in different forms like heat, light or sound. For example, a glow stick releases light making that an exergonic reaction and not an exothermic reaction since no heat is released. Even endothermic reactions at very high temperature are exergonic.
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