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. Why can't classical physics accurately predict the specific heat capacity of a material?

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The temperature inside a supernova explosion is said to be 2.00×1013 K . (a) What would the average velocity vrms of hydrogen atoms be?(b) What is unreasonable about this velocity? (c) Which premise or assumption is responsible?
The next four questions use this description. Our Sun has a peak emission wavelength of about 500 nm and a radius of about 700,000 km. Your dark-adapted eye has a pupil diameter of about 7 mm and can detect light intensity down to about 1.5 x 10-11 W/m2. Assume the emissivity of the Sun is equal to 1. First, given these numbers, what is the surface temperature of the Sun in Kelvin to 3 significant digits? What is the power output of the Sun in moles of watts? (in other words, take the number of watts and divide it by Avogadro's number) Assuming that all of the Sun's power is given off as 500 nm photons*, how many photons are given off by the Sun every second? Report your answer to the nearest power of 10 (e.g. if you got 7 x 1024, give your answer as 25).