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11/29/23, 10 : 50 AM Chem21Labs - online lab submission. Page 1 of 7 https://www2.chem21labs.com/student2/ ? mode=assign&assignment=113 About Chem21Labs | Home | Contact Us | Reference Material | Logout Thanh Tam Student Area Thanh Tam is c This assignment is due at 11:45 PM on 11/28/2023. Any work submitted between that time and 11:45 PM on 11/29/2023 will result in an automatic 10 point de Also, any work submitted between 11:45 PM on 11/29/2023 and 11:45 PM on 11/30/2023 will result in an additional 10 points being deducted for the assignme PDF Lab Guide - Wor Online Lab Submission Complete. Check back several days after the due date to view points added by your instructor. Your Instructor prefers the use of the following links to instantly modify incorrectly entered lab data: 1. Lab Data and Calculation Reset - all lab data and all lab calculations are erased. Points lost on the erased calculations are not erased. 2. Change Incorrect Data - you select the data that needs to be changed - all calculations that depend on the changed data are erased. Points lost on the erased calculations are not erased. Attendance Points = 5 Experiment 12 Report Sheet BEHAVIOR OF GASES Total Points = Earned Total 7 150 More Information Introduction Note: All essay answers throughout the semester must be composed in the html text editor below. NG 10 The objective of experiment 12 was to demonstrate Boyle's Law by measuring the pressure of a gas while varying volume and to observe Amonton's Law by measuring the pressure of a gas while varying temperature. This was accomplished by using a syringe to create various amounts of pressure and the MeasureNet system recorded the pressure as we input the volume, and then the MeasureNet system recorded the temperature and volume as we cooled off the hot water around the submerged flask. The concepts related to the lecture were Boyle's Law, Charles' Law, Dalton's Law, Amonton's Law, and Ideal Gas. The lab techniques used were calibration for temperature, measuring pressure with a pressure sensor, varying pressure by changing the plunger of the syringe in a closed system, setting up the apparatus and testing for leaks, and finding the relationship between volume and temperature by cooling off a hot water bath. Edit Answer
11/29/23, 10 : 50 AM Chem21Labs - online lab submission. Page 2 of 7 https://www2.chem21labs.com/student2/ ? mode=assign&assignment=113 Experimental Procedure NG 3 The experimental procedure followed was found in the lab handout on Chem21labs.com, Experiment 12: Behavior of Gases, from pages 12-6 to 12-9. Edit Answer Results Part B: Pressure vs. Volume Measurements Atmospheric Pressure 763.7 Edit Pressure vs Volume Plot will not appear until atmospheric pressure is entered! 1/y vs. x ln(y) vs. x Draw Lines Mouse Coordinates: Enlarge Graph To record a point on the line or curve that lies between two data points, place the mouse at the desired position and read the mouse's x and y position displayed at the top of the graph. To draw lines on the graph . . . click the Draw Lines button position your mouse over the graph left-click / drag / drop To remove drawn lines from the graph . . . click the Remove Last Line button
11/29/23, 10 : 50 AM Chem21Labs - online lab submission. Page 3 of 7 https://www2.chem21labs.com/student2/ ? mode=assign&assignment=113 repeat until the desired lines are removed To see the x and y values at the intersection of two lines, place your mouse at the intersection and read it's position in the upper left corner of the graph. Part C: Pressure vs. Temperature Measurements Pressure vs Temperature Plot will not appear until atmospheric pressure is entered! 1/y vs. x ln(y) vs. x Draw Lines Mouse Coordinates: Enlarge Graph Upload the pressure-volume plots (2) and the pressure-temperature plot (1) below. Files must be jpeg, png or gif format--not pdf! Instructor Assigned Grade Based On Plot of V syringe vs. 1/P air More Information NG 20
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11/29/23, 10 : 50 AM Chem21Labs - online lab submission. Page 4 of 7 https://www2.chem21labs.com/student2/ ? mode=assign&assignment=113 Rotate Left | Rotate Right Edit Answer Instructor Assigned Grade Based On Plot of manipulated V air and P air values More Information NG 20 Rotate Left | Rotate Right Edit Answer
11/29/23, 10 : 50 AM Chem21Labs - online lab submission. Page 5 of 7 https://www2.chem21labs.com/student2/ ? mode=assign&assignment=113 Instructor Assigned Grade Based On Plot of P air vs. t More Information NG 30 Rotate Left | Rotate Right Edit Answer Questions 1. Explain how you used the graph of V syringe vs. 1/P air to determine the value of V tubing . NG 5 Vtubing was the opposite sign of the y-intercept (b) in the equation of y=mx+b when plotting the graph of Vsyringe vs. 1/Pair. Edit Answer 2. Which plot or plots generated by manipulating P air and V air demonstrate Boyle's Law? Explain your answer. NG 10 The plots generated by manipulating Pair and Vair that demonstrate Boyle's Law are plots of Pair vs. 1/Vair and Vair vs. 1/Pair. Boyle's Law states that pressure and volume are inversely proportional which means that Pair.Vair = constant or Vair = constant.(1/Pair) or Pair = constant.(1/Vair). When plotting out the graph, the equation of y=mx+b equals Vair = m.(1/Pair) will be y=constant. Therefore, there will be a straight line on the graph that demonstrates Boyle's Law and the 2 plots that generate the straight lines are the two plots mentioned above. Edit Answer 3. Express the slope of the line in this plot algebraically in terms of the quantities n , R , and T . Recall the Ideal Gas Law equation, PV = nRT, and that any straight line has the general formula y = mx + b . NG 6
11/29/23, 10 : 50 AM Chem21Labs - online lab submission. Page 6 of 7 https://www2.chem21labs.com/student2/ ? mode=assign&assignment=113 Because P.V=nRT -> P=nRT.(1/V) and in the equation of y=mx+b, the slope would be m. Therefore in the equation of P=nRT.(1/V), where P is the y-axis and (1/V) is the x-axis, the slope of the equation equals nRT or slope = n.R.T Edit Answer 4. Using your answer to the preceding question and your slope from the V syringe vs. 1/P air plot (mL-torr), and assuming that the temperature of the laboratory is 298 K, how many grams of air (average molecular weight 28.8 g/mol) were in your sample of air? Be careful with units! You must click the 1/y vs x button for the graphs above before submitting your answer. Try 1: 0.00346 Try 2: 3.0457E-3 Try 3: 4.0075E-3 2 4 Info (100) 5. Why must you be careful not to grasp the barrel of the syringe when making pressure measurements? NG 5 Since pressure is dependent on temperature, any measurement of the relationship between pressure and volume requires that temperature remain constant. Grasping the syringe barrel with your hand will heat up the gas inside the apparatus, increasing the pressure. Since pressure and volume are inversely proportional, grasping the barrel increases pressure, the volume would be exerted, and that would result in a decrease in the volume of the syringe, making the volume lower than expected. Edit Answer 6. How is the value of κ which you calculated related to T , the temperature in Kelvins? Using your value of κ , write the formula for conversion of the Celsius temperature t to the Kelvin temperature T . NG 6 The value of k equals the y-intercept divided by the slope, or in the equation of y=mx+b, k equals b divided by m. Therefore, the k value in my plot was 332.69 Celcius degree. Since the relation between the two scales of t ( o C) and T(K) is T(K) = t( o C) + k, my formula for the conversion of the Celcius temperature to the Kelvin temperature would be T(K) = t( o C) + 332.69 Edit Answer 7. Your formula may differ from the usually accepted formula T = t (°C) + 273.15. The error is most probably not your fault, but instead is due to the way in which the experiment was done and the value of κ calculated. Why might your experimental value differ from the accepted value? NG 4 The usually accepted formula T(K)=t(C) + 273.15 resulted from the experiment under standard pressure and temperature conditions, which is 1atm (or 760 torr) and 0 o C or 273K. However, in our experiment, the experiment was conducted under the pressure of 763.7 torr or 1.005 atm, which is not the standard pressure condition. Since the experiment was done and the data collected were not under standard conditions, the value of k calculated will also be different from the standard one, which is 273.15. Edit Answer 8. Use the Ideal Gas Equation to express the slope of your plot of P air vs . t algebraically in terms of n , R , and V . NG 6 PV=nRT -> P = T.(nR/V). In the equation y=mx+b, the slope would be m. Therefore, in the equation of P=T.(nR/V), where the P value will be the y-axis and the T value will be the x-axis, the slope equals nR/V, and nR/V = 2.5586. Edit Answer
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11/29/23, 10 : 50 AM Chem21Labs - online lab submission. Page 7 of 7 https://www2.chem21labs.com/student2/ ? mode=assign&assignment=113 9. Explain how your plot of P air vs . t provides a test of the validity of Amontons’ Law. NG 6 Amonton's Law states that pressure and temperature are directly proportional and when the pressure and temperature of a gas change, n and V stay constant. This is evident above since n/V multiplied by R(which is a constant value) is a constant of 2.5586. Edit Answer Conclusion NG 10 The objective of demonstrating Boyle's Law was achieved by pushing in and pulling out the plunger of the syringe to get different values of volume and observe the change of pressure under different volumes of air. A plot of Vsyringe vs. 1/Pair was made from the results and the Vtubing was found from the plot, Vtubing = -y intercept = 1.3483. Also, the set of points in the plot indeed falls along a straight line, which indicates that Boyle's Law of inverse proportion between volume and pressure was demonstrated. This experiment was a pretty successful one. The objective of observing Amonton's Law was achieved by setting up a closed system with a flask of air submerged in a warm water bath and recording the pressure inside the flask as the temperature decreases when the water is cooled down by adding ice. A plot of Pair vs. Temperature (in Celcius degree) was made from the result and the k value was found, k= y-intercept/slope = 332.69. Since the P/T value equals 2.5586, which is a constant value, this consistency has demonstrated Amonton's Law of direct proportion between pressure and temperature. Therefore, this experiment was also pretty successful. Edit Answer Total Points = Earned Total 7 150 View Printable Page Back to Main Menu - Thanh Tam is currently logged in. Due date passed. Any work on the assignment between now and 11/29/2023 11:45 PM will result in a loss of 100% of points earned in the late period or 10 points... whichever is smaller. Hide Side Panel Back to Main Menu