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Material Science

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Dec 6, 2023

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2. Chapter 1 1. Why does a razor blade get dull (blunt)? Explain. Each of the crystals that make up a razor blade includes billions of atoms that are arranged in a precise, three-dimensional pattern. The crystal's strength comes from the bonds that hold the atoms together and keep them from moving. When a razor blade cuts through hair, it collides with it and causes the crystals to reorganize into a different shape, which causes the blade to become dull. This causes the bond to break down, which ultimately causes the razor edge to develop small dents. 2. Why is re-sharpening a razor blade a challenge? Re-sharpening a razor blade is a challenge because heat softens metal crystals. Heat can affect the hardness and temper of the blade material. When re-sharpening a razor blade, high heat may affect the blade's structure and result in unwanted modifications to its qualities. Heat may be produced during re-sharpening a blade because of friction between the blade and the sharpening instrument. The blade's hardness and temper may be impacted by localized temperature rises brought on by this heat. Too much heat might cause the blade to soften, lose its hardness, or even undergo unfavorable changes in its microstructure.
3. Explain the significance of dislocations. Include connections to malleability and melting points. Dislocations are atomic disruptions that shouldn't be there and are considered flaws in the metal crystals since they deviate from the normally ideal crystalline arrangement of the atoms. However, they are crucial because metals can alter shape thanks to dislocations. The ease with which the dislocations move is also influenced by a metal's melting point, which measures how firmly the metal atoms are held together. As a result, a metal with a low melting point is brittle, whereas one with a high melting point is stronger. Metals become softer as a result of heating because it allows dislocations to move about and reorganize themselves. 4. How was copper discovered? How was it originally made? Copper was first discovered by early humans who were experimenting with various rocks and minerals in prehistoric times. Malachite was placed into a hot fire surrounded by red-hot embers in order to detect copper. The somewhat greenish rock changed into a bright metal object. Other rocks were attempted, but not all of them were successful. Early metalsmiths refined the method of producing copper through trial and error. 5. What is an alloy? Compare properties of alloys with pure metals. Explain the differences.
Alloy is the process of combining different metals to produce a new element with enhanced qualities compared to pure metals. Because the alloy atoms differ in size and chemistry from the host metal's atoms, they cause a variety of mechanical and electrical disturbances inside the host crystal that all add up to one very important thing: they make it harder for dislocations to move. This is why alloys tend to be stronger than pure metals. Additionally, if dislocations find it difficult to shift, the metal is stronger since the metal crystals have a tougher time changing shape. Thus, the magic of alloy design is to stop dislocations from moving. 6. What is steel? Steel is an alloy of iron, carbon, and other elements. Our ancestors were unaware that steel was an alloy and that carbon, in the form of charcoal, could penetrate the iron crystals as well as be used to heat and reshape iron. Steel's carbon content can be regulated during the manufacturing process, giving rise to several types and grades of steel with unique properties. It is an extensively used material in many different sectors and applications because of its excellent strength, toughness, and adaptability. 7. What is the source of carbon in steel? Charcoal is the source of the carbon in steel. Since it was a popular fuel source and produced a lot of heat, charcoal was employed in the furnaces because of its high carbon content. However, there was little control over how much charcoal was used and how it interacted with the iron or steel that was being produced. The carbon content of charcoal produced from various kinds of wood or under various circumstances may vary. This could lead to variable carbon levels in the steel produced, together with the lack of exact control over the input of charcoal.
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8. Why doesn’t carbon create an alloy with copper, tin or bronze during smelting? What is unique about iron? During the smelting process, carbon does not combine with copper, tin, or bronze because it behaves differently in those metals than it does in iron. The carbon atoms in metals like copper, tin, and bronze don't get along well with the other metal atoms. Instead of integrating into the metal structure, it would want to remain separate. It creates different stages or compounds all on its own. Contrarily, when carbon and iron meet, a special reaction takes place. Iron can accommodate carbon, which integrates into the iron's structure. Carbon differs from other metals in that it may dissolve into the iron lattice. According to the amount of carbon present, it continuously mixes with iron to produce various types of steel. 9. Explain how ancient samurai swords were made. These samurai swords were handmade from a unique sort of steel called tamahagane and were created from the Pacific's volcanic black sand, which is primarily made of magnetite, the iron ore that served as the compasses' initial needle. The enormous clay tatara is used to create this steel. By starting a fire inside the vessel, the molded clay is fired to solidify it into ceramic. After being fired, it is painstakingly layered with black charcoal and sand, which are burned in the ceramic furnace. A group of four or five people must be on hand at all times during the process, which lasts about a week. They must ensure that the fire's temperature is kept high enough by manually forcing air into the Tatara using bellows. At the conclusion, the Tatara is split apart, and the steel from the tamahagane is excavated from the ash and remaining sand and charcoal. These lumps of
discolored steel differ in carbon content from extremely low to very high, making them very variable in appearance. They could ensure that the low-carbon steel was used to create the sword's center by segregating the various types of steel. 10. What is the Bessemer process? The Bessemer process was the first low-cost industrial method for producing large amounts of steel. In order for the oxygen in the air to interact with the carbon in the iron and extract it as carbon dioxide gas, it required blowing air through the molten iron. It required chemistry knowledge, which gave steelmaking a scientific foundation. Furthermore, a great deal of heat was produced by the exceedingly violent reaction between the oxygen and the carbon. The steel's temperature was boosted by this heat, keeping it hot and liquid. 11. How was stainless steel discovered? How does it work? Harry Brearley was given the responsibility of researching metal alloys in order to improve cannon barrels. He performed experiments with the addition of various elements to steel, and cast samples, and evaluated the hardness of those materials while working in a metallurgical lab in Sheffield, England. Even though the composition of steel was known to be iron and carbon, the impacts of other elements were not yet well understood. Brearley performed experiments using trial and error by melting steel and adding various substances to determine their effects. Brearley made little progress at first, discarding samples that didn't fit his standards for hardness. After a month of work, he finally made a breakthrough
when he discovered a shining specimen amidst the collection of rusting samples. He didn't ignore it; he understood its importance. It turned out to be the first stainless steel object ever made. By accident, Brearley had balanced the alloy's carbon and chromium content to produce a distinctive crystal structure. Chromium wasn't added to the steel to make it harder; instead, it had a more intriguing impact. Iron on steel's surface typically reacts with oxygen and water to produce iron(III) oxide, also known as rust. Rusting issues are brought on when this rust peels off, exposing the underlying steel to more corrosion. But when chromium was present, something unusual happened. Before the iron atoms could react with oxygen, chromium did, forming chromium oxide, a clear and resilient mineral. Contrary to rust, chromium oxide attaches effectively to steel, creating a chemically protective layer that is completely undetectable. This layer also has a remarkable capacity for self-healing. The stainless steel can rebuild itself, keeping its protective qualities even if it is scraped and the barrier is broken.
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