7_KHPReport2023

docx

School

Texas A&M University *

*We aren’t endorsed by this school

Course

317

Subject

Chemistry

Date

Apr 3, 2024

Type

docx

Pages

4

Uploaded by ProfessorBoar4096

Report
Lab Report 7 --Volumetric Determination of KHP Name: Ella Keheley Date : 3/7/24 Unknown #: 12 Partner’s Name : Gabriela McColl LabQuest #: _____ Probe #: _____ *no number on our probe/LabQuest Standardization of NaOH Solution n Trial # Mass of KHP used (g) Titration Volume (mL of NaOH) Molarity of NaOH Solution ( M) 1 0.5042 36.40 0.06783 2 0.4917 36.00 0.06688 3 0.4887 34.10 0.07018 Average = Standard Deviation = 0.06830 0.0017 Results -- Analysis of KHP Unknown Trial # Mass of Unknown (g) Titration Volume (mL of NaOH) Mass Percent (% KHP) 1 0.4974 14.20 39.82 2 0.5002 13.40 37.37 3 0.5004 13.95 38.88 4 – pH probe trial 0.5014 13.85 38.52 Average = Standard Deviation = 38.65 1.01 Calculations Standardization of NaOH solution for Trial #1 0.5042 g KHP× 1 mol KHP 204.22 gKHP × 1 mol NaOH 1 mol KHP × 1 0.03650 LNaOH = 0.06783 M NaOH Mass Percent KHP for Trial # 1 0.01420 LNaOH × 0.06830 molNaOH 1 L NaOH × 1 mol KHP 1 molNaOH × 204.22 g KHP 1 mol KHP = 0.1981 g KHP 0.1981 gKHP 0.4974 gunknown × 100 = 39.82% Graph Interpretation [state whose titrant solution and whose unknown solution was used with the pH sensor trial] : Unknown #12 with Ella Keheley’s titrant solution o Volume at Equivalence Point: __13.66 mL___ o Volume at Half-way to Equivalence Point: __6.83 mL___ o pH at this half-way point: _5.34____ o Show calculation used to convert this pH to the K a of the KHP. pH=pKa @ Half equivalence point pKa=5.34=-log(Ka) Ka=10^(-5.34)=4.57 × 10 6
Calculate % error of the K a value, after researching the “true” K a for KHP. Provide source used for the K a value. ¿ 4.57 × 10 6 3.9 × 10 6 ¿ 3.9 × 10 6 × 100 = 17.2% ¿ Source- ChemEurope Graphs 1) Insert Graph of the titration curve for your trial using the pH sensor, clearly stating which trial the graph illustrates. **Before making a screenshot or printing the graph, PLACE YOUR CURSOR on the graph so that the VOLUME AND pH of the equivalence point are CLEARLY indicated in the lower-left corner. The cursor will disappear, but the volume/pH values should be clearly visible. 2) Insert Graph of Second Derivative vs. Volume (you may place both plots on the same graph if you like). Graph of Trial 4 – Unknown #12 Photo Documentation Photo of a representative endpoint from your unknown analysis
Conclusions Briefly compare your precision in KHP values for your unknown, as reflected in the standard deviation. The precision of my values of KHP are decently accurate due to the standard deviation of ± 1.01 . Each titration had a similar volume of titrant used as the trial with the pH probe which also contributes to higher precision in the data. Raw Data Scan or photograph your data tables and insert below, making sure TA signatures are visible.
Your preview ends here
Eager to read complete document? Join bartleby learn and gain access to the full version
  • Access to all documents
  • Unlimited textbook solutions
  • 24/7 expert homework help