Chemistry11 Final Exam Review 2019 (2)

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Chemistry 11 Course Review Chemistry 11 – June Exam Review Unit 1— The Mole Concept 1. Make the following conversions, clearly showing your steps. Include proper units in all of your work and in your answer. a) 133.44 grams of PCl 5 = ? moles Answer ___________________________ b) 0.00256 moles of Li 2 Cr 2 O 7 = ? grams Answer ___________________________ c) 170.24 L of NO 2 at STP = ? moles Answer ___________________________ d) 570.625 g of PCl 3 gas = ? L (STP) Answer ___________________________ e) 1030.4 mL of C 2 H 6 gas at STP = ? g Answer ___________________________ f) 5.00 kg of nitrogen gas, N 2 = ? L (STP) Answer ___________________________ g) 0.5696 kg of CH 4(g) = ? mL Answer ___________________________ Chemistry 11—Course Review Page 1
Chemistry 11 Course Review 2. The density of liquid ethanol (C 2 H 5 OH) is 0.790 g/mL. Calculate the number of molecules in a 35.0 mL sample of liquid ethanol. (NOTE: You CAN’T use 22.4 L/mol since this is NOT a gas at STP!) Answer __________________________ 3. A 100.0 mL sample of liquid mercury contains 6.78 moles. Calculate the density of liquid mercury from this data. Answer __________________________ 4. Calculate the density of PCl 3(g) at STP. Answer __________________________ 5. The density of a gas at STP is 4.955 g/L. Calculate the molar mass of this gas. 6. 123.11 g of zinc nitrate, Zn(NO 3 ) 2 are dissolved in enough water to form 650.0 mL of solution. Calculate the [Zn(NO 3 ) 2 ]. Include proper units in your work and in your answers. Answer _______________________________ Chemistry 11—Course Review Page 2
Chemistry 11 Course Review 7. Calculate the mass of potassium sulphite (K 2 SO 3 ) needed to make 800.0 mL of a 0.200 M solution of K 2 SO 3 . Include proper units in your work and in your answers. Answer ______________________ 8. What volume of 2.50 M Li 2 CO 3 would need to be evaporated in order to obtain 47.232 g of solid Li 2 CO 3 ? Include proper units in your work and in your answers. Answer ______________________ 9. 150.0 mL of water are added to 400.0 mL of 0.45 M HNO 3 . Calculate the final [HNO 3 ]. Include proper units in your work and in your answers. Answer ______________________ 10. What volume of water needs to be added to 150.0 mL of 4.00 M H 2 SO 4 in order to bring the concentration down to 2.50 M? Include proper units in your work and in your answers. Answer ______________________ 11. Give directions on how to make 5.00 L of 0.020 M Ca(ClO) 2 using solid Ca(ClO) 2 and water. Include proper units in your work and in your answers. Directions: Unit 2— Chemical Reactions 1. Balance the following equations NH 3 + O 2 NO + H 2 O (NH 4 ) 2 C 2 O 4 + AlCl 3 Al 2 (C 2 O 4 ) 3 + NH 4 Cl C 14 H 30 + O 2 CO 2 + H 2 O Chemistry 11—Course Review Page 3
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Chemistry 11 Course Review Fe + HNO 3 Fe(NO 3 ) 3 + H 2 P 4 + Cl 2 PCl 3 H 3 PO 4 + Ca(OH) 2 Ca 3 (PO 4 ) 2 + H 2 O Ba(ClO 4 ) 2 Ba + Cl 2 + O 2 MgSO 4 . 5H 2 O MgSO 4 + H 2 O 2. Write a balanced chemical equation for each of the following, and classify each as synthesis, decomposition, single replacement, double replacement, neutralization or combustion. a) potassium sulphate is mixed with cobalt (III) nitrate b) liquid propanol (C 3 H 7 OH) is burned in air c) ammonium nitrate is decomposed into it’s elements d) a piece of zinc is placed in a test-tube containing a solution of silver nitrate e) bromine reacts with sodium iodide 3. State whether each of the following are exothermic or endothermic . HCl + 432 kJ H + Cl Answer ___________________________ C 12 H 22 O 11 + 12 O 2 12CO 2 + 11H 2 O H = -5638 kJ Answer ___________________ H 2 O (s) H 2 O (l) Answer ___________________________ Answer ___________________________ CD C + D H= 65.7 kJ Answer ___________________________ E + F + 437 kJ G + H Answer ___________________________ Chemistry 11—Course Review Page 4 A + B Energy (kJ) Reaction Proceeding AB
Chemistry 11 Course Review 4. Given the equation: C 12 H 22 O 11 + 12O 2 12CO 2 + 11H 2 O + 5638 kJ a. How much heat is released during the formation of 880.0 g of CO 2 ? Answer _____________________________ b. How much heat is released during the formation of 5.6 moles of H 2 O? Answer _____________________________ c. If 179.2 L of O 2 (STP) are consumed, how much heat is released? Answer _____________________________ 5. Calculate the amount of heat (in Joules) required to warm 200.0 g of water from 8.0 o C to 45.0 o C. (Heat Capacity (C) for H 2 O is 4180 J/kg . o C) Answer _____________________________ 6. 13.376 kJ of heat are added to a 400.0 gram sample of water initially at 4.0 o C. Calculate the final temperature of the water sample. Be careful with units! (Heat Capacity (C) for H 2 O is 4180 J/kg . o C) Answer ____________________________ Chemistry 11—Course Review Page 5
Chemistry 11 Course Review Unit 3— Stoichiometry 1. Given the following balanced equation, answer the questions following it: 2NF 3(g) + 3H 2(g) N 2(g) + 6HF (g) a) If 5.5 moles of H 2 are reacted, how many moles of NF 3 will be consumed? Answer ____________ b) In order to produce 0.47 moles of HF, how many moles of NF 3 would be consumed? Answer ____________ c) If you needed to produce 180.6 g of N 2 , how many moles of H 2 would you need to start with? Answer ____________ d) If you completely react 17.04 g of NF 3 , what mass of HF will be produced? Answer ____________ 2. Given the following balanced equation, answer the questions following it: HBrO 3 + 5 HBr 3 H 2 O (l) + 3 Br 2(g) a) If 3.56 moles of HBr are reacted, how many litres of Br 2 will be formed at STP? Answer ______________________ Chemistry 11—Course Review Page 6
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Chemistry 11 Course Review HBrO 3 + 5 HBr 3 H 2 O (l) + 3 Br 2(g) b) In order to produce 3.311 x 10 24 molecules of Br 2 , what mass of HBr is needed? Answer ______________________ 3. Given the following balanced chemical equation, answer the question below it. MgCO 3 (s) + 2HCl (aq) CO 2 (g) + H 2 O (l) + MgCl 2(aq) a) What mass of MgCO 3 will react completely with 15.0 mL of 1.5 M HCl? Answer _______________________ b) Calculate the volume of 2.0 M HCl which would be needed to react completely with 37.935 grams of magnesium carbonate. Answer _______________________ 4. Given the following balanced equation, answer the questions below it. Ba(OH) 2(aq) + 2 HNO 3(aq) 2 H 2 O (l) + Ba(NO 3 ) 2 a) In an acid base reaction, 18.20 mL of 0.300 M Ba(OH) 2 is required to react completely with a 25.0 mL sample of a solution of HNO 3 . Find the [HNO 3 ]. Answer _______________________ Chemistry 11—Course Review Page 7
Chemistry 11 Course Review b) In an acid-base reaction, 11.06 mL of 0.200 M HNO 3 is required to react completely with a sample of 0.250 M Ba(OH) 2 . Find the volume of the Ba(OH) 2 sample. Answer _______________________ 5. Given the following balanced equation, answer the questions below it. 3 Cu (s) + 8HNO 3(l) 3 Cu(NO 3 ) 2(aq) + 2NO (g) + 4 H 2 O (l) a) If 317.5 grams of Cu are placed into 756.0 grams of HNO 3 , determine which reactant is in excess. Answer _______________________ b) If the reaction in (a) is carried out, what mass of NO will be formed? Answer _______________________ 6. Given the balanced equation: 2BN + 3F 2 2BF 3 + N 2 , When 161.2 grams of BN are added to an excess of F 2 , a reaction occurs in which 326.118 grams of BF 3 are formed. a) Calculate the theoretical yield of BF 3 in grams. Answer _______________________ b) Calculate the percentage yield of BF 3 . Answer _______________________ Chemistry 11—Course Review Page 8
Chemistry 11 Course Review 7. When reacting NH 3 with O 2 according to the reaction: 4 NH 3 + 5 O 2 4 NO + 6 H 2 O Using 163.2 grams of NH 3 with an excess of O 2 produces a 67% yield of NO. a) Calculate the theoretical yield of NO in grams. Answer _______________________ b) Calculate the actual yield of NO in grams. Answer _______________________ Unit 4— Atoms, Periodic Table and Bonding 1. The Greek who developed the idea of atoms was _______________________________ 2. Consider the following ideas: Compounds are made up of molecules which are combinations of atoms All atoms of an element are the same Atoms of different elements are different Atoms are indivisible particles Who came up with these ideas? ______________________ He called the ideas, the ___________________________ Theory. 3. ___________________________ measured the charge/mass ratio of an electron and came up with the so- called “plum pudding” model of the atom. 4. ___________________________ devised the Scattering Experiment, which showed that all atoms had a small dense __________________________. 5. Bohr came up with an atomic model to explain the spectrum of ______________________. He said that the atom has certain _______________ levels which are allowed. These levels corresponded to ____________________ in which electrons move. If an electron absorbs a certain amount of energy, it will jump to a ___________________ level. It will release this energy (in the form of __________________) when it falls back to a ______________ level. What were two limitations of Bohr’s atomic model? Chemistry 11—Course Review Page 9
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Chemistry 11 Course Review 6. Give the number of protons, neutrons and electrons in the following: Isotope Protons Neutrons Electrons 194 Ir 3+ 202 Hg 2+ 125 Te 2- 263 Sg 2 H + 7. Give the nuclear notation of the following: Isotope Protons Neutrons Electrons 105 157 103 51 72 48 33 42 36 54 79 54 94 150 91 8. Element “X” is composed of the following naturally occurring isotopes: Isotope % Abundance 79 X 50.69 81 X 49.31 Calculate the average atomic mass of element “X” to 3 decimal places. Element “X” is actually the real element ________________________________. 9. Regions in space occupied by electrons are called ___________________________ 10. The principal quantum number is given the letter ____ and refers to the _______________ level. Chemistry 11—Course Review Page 10
Chemistry 11 Course Review 11. Write the ground state electron configurations (eg. 1s 2 2s 2 2p 6 ) for the following atoms or ions. You may use the core notation. a) P b) Mo c) Se d) Rb e) Cl - f) Al 3+ g) K + h) S 2- 12. In order to become stable, an atom of Sr will __________ ___ electrons and become the ion ________ an atom of As will __________ ___ electrons and become the ion ________ an atom of Al will __________ ___ electrons and become the ion ________ an atom of Se will __________ ___ electrons and become the ion ________ an atom of N will __________ ___ electrons and become the ion ________ an atom of I will __________ ___ electrons and become the ion ________ an atom of Cs will __________ ___ electrons and become the ion ________ an atom of Te will __________ ___ electrons and become the ion ________ 13. Circle the metalloid: Be Rb Os Ge Pb Al 14. Circle the most reactive element in the following: Na Mg Si Al Ar 15. Circle the most reactive element in the following: Na K Rb Cs Li 16. Circle the most reactive element in the following: Cl Br I At Ne 17. Circle the element with the largest atomic radius of these: Na Mg Si Al Ar 18. Circle the element with the largest atomic radius of these: N P As Sb Bi Chemistry 11—Course Review Page 11
Chemistry 11 Course Review 19. Circle the element with the largest ionization energy of these: K Ca Ga As Kr 20. Circle the element with the largest ionization energy of these: C Si Ge Sn Pb 21. What is meant by ionization energy? 22. Circle the element with the largest density of these: C Si Ge Sn Pb 23. Circle the element with the largest density of these: Na K Rb Cs Li 24. Circle the element with the highest electronegativity of these: Mg Sr Ba Ra 25. Circle the element with the highest electronegativity of these: Mg Si S Cl 26. Circle the element with the highest electronegativity of these: F Cl Br I 27. What is meant by electronegativity? 28. Circle the most metallic element of these: Be Mg Ca Sr Ba 29. Circle the most metallic element of these: B Al Ga In Tl 30. Circle the most metallic element of these: Ga Ge Se Br Kr 31. Write a balanced equation for the reaction of potassium with water. 32. Write a balanced equation for the reaction of aluminum with bromine. 33. In an ionic bond, electrons are a. shared equally by two atoms b. shared unequally by two atoms c. transferred from a metal to a non-metal d. transferred from a non-metal to a metal e. closer to one end of a molecule, forming a temporary dipole 34. In a covalent bond, electrons are a. shared equally by two atoms b. shared unequally by two atoms c. transferred from a metal to a non-metal d. transferred from a non-metal to a metal e. closer to one end of a molecule, forming a temporary dipole 35. In a polar covalent bond, electrons are a. shared equally by two atoms b. shared unequally by two atoms c. transferred from a metal to a non-metal d. transferred from a non-metal to a metal e. closer to one end of a molecule, forming a temporary dipole Chemistry 11—Course Review Page 12
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Chemistry 11 Course Review 36. In London forces, electrons are a. shared equally by two atoms b. shared unequally by two atoms c. transferred from a metal to a non-metal d. transferred from a non-metal to a metal e. closer to one end of a molecule, forming a temporary dipole 37. Complete the following table for shapes, polarities and intermolecular forces. Formula Electron Count General Formula AX s E t Molecule Shape Bond Angle(s) Polarity (Y/N) Intermolecular Forces H 2 O C F 4 P Cl 3 Br 2 As F 5 Te F 4 B H 3 Kr F 2 Si H 3 Cl C S 2 HI N H 3 Chemistry 11—Course Review Page 13
Chemistry 11 Course Review 38. Compare BeH 2 to H 2 O a) Lewis Dot Structures b) Molecular Geometry (Shapes) c) Bond Angle d) Dipole Moment (Overall Molecular Polarity) e) Intermolecular Forces f) Boiling or Freezing Point 39. Atomic vs. Ionic Radii a) Metal Atom vs. Metal Ion (Ca vs. Ca 2+ ) b) Non-metal Atom vs. Non-metal Ion (Cl vs. Cl -1 ) 40. Using nuclear forces and atomic structure, explain the trend in a) Ionization energy across any period b) Electronegativity down any family Chemistry 11—Course Review Page 14
Chemistry 11 Course Review Unit 4— Solution Chemistry Dissociation Equations 41. Write dissociation equations for the salts listed below when they are dissolved in water: NiCl 3( s ) Ba(NO 3 ) 2( s ) Li 2 CrO 4( s ) Al 2 (SO 3 ) 3( s ) Rb 2 Cr 2 O 7( s ) Co(NO 2 ) 2( s ) Dilution Calculations M 1 V 1 = M 2 V 2 42. A student dilutes 90.0 mL of 1.25 M lithium sulphate solution by adding 150.0 mL of water to it. Calculate the molarity of the Li 2 SO 4 and also the Li +1 ( aq ) . 43. During a lab activity a student heats a beaker containing 140.0 mL of 0.340 M CuCl 2 until the volume of the solution is reduced by 25.0 mL. Calculate the molarity of the resulting solution. 44. When equal volumes of the following 0.20 M solutions are combined, determine if a reaction results in the formation of a precipitate. If a precipitate forms write a balanced chemical equation, a complete ionic equation and a net ionic equation. a) KCl + AgNO 3 b) SnCl 2 + Na 3 PO 4 c) FeBr 3 + LiOH 45. Identify the spectator ions in each of the equations in question 44. Chemistry 11—Course Review Page 15
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