test 2 white -key(1)(1)

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University of Alabama *

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105

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Chemistry

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Feb 20, 2024

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1 CH105-002 Exam #2 Name____________________________ CWID_____________________________ MULTIPLE CHOICE. Choose the one alternative that best completes the statement or answers the question. 1. What functional groups are in the open-chain forms of monosaccharides? A. Hydroxyl groups B. Aldehyde groups C. Ketone groups D. Hydroxyl and aldehyde or ketone groups E. Hydroxyl and ether groups 2. What is the classification of the following monosaccharide? A. aldotriose B. ketotriose C. aldotetrose D. ketotetrose E. ketopentose 3. Disaccharides have two monosaccharide units joined together by a glycosidic bond. What is the monosaccharide units for the following disaccharide? A. ß-D-galactose and α -D-glucose B. α -D-galactose and α -D-glucose C. ß -D-galactose and α -lactose D. maltose and lactose
2 4. Which pairs of Fisher projections represent enantiomers? 5. Which of the following is the Fischer projection of the following molecule? 6. What is the classification of the compound shown below? A. L B. D C. A sugar this small is not classified as L or D. A. B. C. D. A. B. C. D.
3 7. The sugar also is known as dextrose and blood sugar is A. sucrose. B. galactose. C. fructose. D. lactose. E. glucose. 8. What product forms when the compound below is treated with H 2 in the presence of a Pd catalyst? 9. Sucrose is a disaccharide. What is the glycosidic link in sucrose? A. α(1 6)-glycosidic bond B. α, β (1 2)-glycosidic bond C. α(1 4)-glycosidic bond D. β (1 4)-glycosidic bond 10. How many chiral centers in the following compound? A. B. C. D.
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4 A. 1 B. 2 C. 3 D. 4 11. What is the Haworth structure for β --L-glucose? 12. What hydrolysis products are formed when the following wax is treated with aqueous sulfuric acid? 13. What type of lipid is the following compound? A. B. C. D . A. CH 3 (CH 2 ) 18 CHO + CH 3 (CH 2 ) 18 CH 2 OH B . CH 3 (CH 2 ) 18 COOH + CH 3 (CH 2 ) 20 CH 2 OH C. CH 3 (CH 2 ) 20 COOH + CH 3 (CH 2 ) 16 CH 3 D. CH 3 (CH 2 ) 20 COOH + CH 3 (CH 2 ) 18 COOH E. CH 3 (CH 2 ) 18 CH 2 OH + CH 3 (CH 2 ) 16 COOH
5 A. sphingomyelin B. glycerophospholipid C. triacylglycerol D. wax 14. Compared to unsaturated fatty acids, saturated fatty acids have A. shorter carbon chains. B. lower melting points. C. weaker intermolecular attraction. D. higher melting points. E. longer carbon chains. 15. Choose the saturated fatty acid from the compounds below. A. B. C. D. 16. What is the condensed structural formula for the wax formed by the reaction of palmitic acid and cetyl alcohol? 17. Palmitic acid is a 16 carbon acid. In a balanced equation, the products of the saponification of glyceryl tripalmitate (tripalmitin) are A. B. C. D.
6 18. Which is a nonhydrolyzable lipid? 19. What is the main component of the cell membrane? A. triacylglycerols B. phospholipids C. steroids D. waxes 20. The transport of particles across a cell membrane from high concentration to low concentration is called 21. Fats and oils are structurally both triacylglycerols, but fats are solids at room temperature and oils are liquids at room temperature. Which statement best describes the reason for their difference in the physical state? A. B. C. D. A. a phospholipid B. a wax C. a triacylglycerol D. a cholesterol A. facilitated transport. B. diffusion. C. active transport. A. Fats are simple triacylglycerols and oils are mixed triacylglycerols. B. Oils are simple triacylglycerols and fats are mixed triacylglycerols. C. Oils contain longer fatty acid chains than fats do, and therefore have higher melting points than fats. D . Fats contain a higher percentage of saturated fatty acids than oils do, and therefore have higher melting points than oils.
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7 22. Which structure is the steroid skeleton? 23. Which compound has the highest boiling point? 24. Carboxylic acids are water-soluble due to their 25. What is the IUPAC name for the following ester? 26. What is the IUPAC name of the compound below? A. B. C. D. A. (CH 3 ) 2 CHCH 2 CHO B. (CH 3 ) 2 CHCH 2 CH 2 CH 2 OH C. CH 3 (CH 2 ) 6 CH 3 D. CH 3 CH 2 CH 2 CH 2 CH 2 COOH A. nonpolar nature B. ionic bonds C. ability to hydrogen bond D. high melting points A. propyl propanoate B. propyl ethanate C. ethyl propanoate D. propyl ethanoate A. 2-methyl-2-butyl-1-propanoic acid B. 2,2-dimethylhexanoic acid C. 2-methyl-2-propylpropanoic acid D. 2,2-dimethyl-1-hexoic acid E. 5,5-dimethylhexanoic acid
8 27. What are the products of the acid base reaction below? 28. What products are formed in the base hydrolysis of the ester shown below with NaOH? 29. What ester is formed when hexanoic acid is treated with methanol (CH 3 OH) in the presence of H 2 SO 4 ? 30. What is the hydrolysis reaction of an ester by a base called? 31. Which statement concerning carboxylic acids is incorrect? A. The functional group of a carboxylic acid is abbreviated as COOH or CO 2 H. B. Carboxylic acids are hydrogen ion donors. A. B. C. D. A. B. C. D. A. B. CH 3 CH 2 CH 2 CH 2 COOCH 3 C. D. A. an addition reaction B. an esterification C. a substitution reaction D. a saponification
9 C. The presence of a carboxylic acid increases the [H 3 O + ] in an aqueous solution relative to water. D. The reaction of a carboxylic acid with a strong base produces a water-insoluble carboxylate salt. 32. lactose, milk sugar, is a disaccharide found in milk and milk products. What kinds of monosaccharides are present in lactose? A. glucose + glucose B . glucose + galactose C. glucose + fructose D. galactose + galactose 33. Chirality occurs when stereoisomers have mirror images that are A. superimposable. B. the same. C. not superimposable. D. not visible to one another. E. identical.
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