Project #3_ Kinetics of Gatorade W24
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Feb 20, 2024
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Project #3: Kinetics of Gatorade W24
https://docs.google.com/document/u/1/d/e/2PACX-1vRgJuqq1OmcvN3lL31UVXe-M3KHBPeimqX3qrtMQoryHUAi3wL8YgVcduTWdp4oEHX07RssjeQ6N0_t/pub
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PRE-LAB QUIZ Quiz #4
Session #1
A Canvas pre-lab quiz is due every week at 11:59 pm
the day before your lab section. The information
needed to answer these questions can be found in
your general chemistry lecture textbook, the Lab
Safety for Chemists online text (Section 4.1.1) and in
documents hyperlinked within this document.
INTRODUCTION
Kinetics
, the study of the speed or rate of a chemical
reaction, is one way to determine the reaction
mechanism (the breaking of reactant bonds, the
creation of reaction intermediates and the forming of
product bonds). Why study kinetics?
Understanding
the reaction mechanism of industrial scale synthesis
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Project #3: Kinetics of Gatorade W24
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allows for money saving optimizations. Determining
the kinetics of environmental processes
demonstrates how chemical hazards affect air and
water quality. Knowledge of the reaction mechanisms
of biochemical processes guide pharmaceutical
design.
In the Fundamental Skills
section of this experiment,
you and your team will look at the kinetics of crystal
violet hydroxylation. Crystal violet, which creates a
deep purple solution when dissolved in water, has
been used as a cytology stain, an antiseptic, an ink
component, and a colorant in a antifreeze and
detergent. Hydroxylating (add sodium hydroxide to) a
crystal violet results in a decolorization of the
solution, indicating a chemical reaction. Some
information about the mechanism of this reaction can
be found by monitoring the loss of color (the loss of
absorbance) as a function of time.
For a generic chemical reaction:
bB + cC → products
The typical equation for a rate law is:
Rate = k[B]
x
[C]
y
The reaction orders, x and y, are found
experimentally and indicate how the rate depends on
the reactant each is associated with. Reaction orders
are typically 0, 1, or 2. The rate constant, k, is a
constant for a particular reaction as long as the
temperature does not change.
If the reaction is monitored as a function of time when
one reactant (C for example) is in excess, the rate
law can be simplified to:
Rate = k
1
[B]
x
where k
1
= k[C]
y
This simplified “pseudo” rate law can be integrated to
create a rate law with a line equation form. Creating
the plots indicated in the last column of the table
enables one to determine the reaction order for B.
The function of [B] vs t which demonstrates a linear
relationship reveals the reaction order of B.
Table 1. Rate Laws
Order
Rate Law
Integrated
Rate Law
Plots
0
Rate =
k
1
[B]
0
= k
1
[B]
t
= -kt +
[B]
0
[B]
t
vs t
1
Rate =
k
1
[B]
1
=
k
1
[B]
ln[B]
t
= -kt +
ln[B]
0
ln[B]
t
vs t
2
Rate =
k
1
[B]
2
1/[B]
t
= kt +
1/[B]
0
1/[B]
t
vs t
The chemical reaction and rate law for the
hydroxylation of crystal violet are:
CV
+
+ -
OH → CVOH Rate = k[CV
+
]
x
[
-
OH]
y
If an excess of hydroxide ion is used, the [
-
OH]
y
term
can be assumed to be constant (any reduction in
concentration can be ignored because the
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concentration is so large). The new pseudo rate law
can be written as:
Rate = k
1
[CV
+
]
x
where k
1
= k[
-
OH]
y
.
How is [CV
+
] measured as a function of
time?
Because crystal violet is a colored species,
Beer’s Law (A = eCl) can be invoked, allowing for the
assumption that absorbance can be used in place of
[CV
+
] because the two quantities are directly
proportional to each other (i.e., A ≈ [CV
+
]).
In the Original Investigation
part of this project, you
will use what you learned in the Fundamental
Skills
section to determine the rate law of one or
more Gatorade dyes. Bleach (sodium hypochlorite,
NaOCl) will replace sodium hydroxide as the excess
reactant.
Reaction of Dyes with Bleach
In Project #2 you were introduced to 3 dyes: Red 40,
Yellow 5, and Blue 1. In this project we will add
another dye found in Gatorade, Yellow 6. Including
the crystal violet, the dyes handled in this project can
be separated into two different categories: ●
azo dyes, which are named after their central
-N=N- linkage (Figure 1)
●
triarylmethane dyes which contain a center
carbon (“methane”) bound to three benzene
rings (“aryl”) (Figure 2)
Red 40 (allura red AC):
Na
2
[C
18
H
14
N
2
O
2
(SO
3
)
2
]
Yellow 5 (Tartrazine)
Na
3
[C
16
H
9
N
4
O
3
(SO
3
)
2
]
Yellow 6 (sunset yellow FCF):
Na
2
[C
16
H
10
N
2
O(SO
3
)
2
]
Figure 1.
Azo Dyes in Gatorade
In this project you will react bleach (sodium
hypochlorite, NaOCl) with the dyes. Bleach is
commonly defined as a substance that removes
stains or whitens fabric. Sodium hypochlorite
oxidizes a dye, chemically changing the dye into
chemical(s) that do not absorb visible radiation and
are, therefore, not colored. Azo dyes are usually
oxidized into two compounds, splitting in two at their
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azo linkage. Triarylmethane dyes react at their center
carbon in a way that either separates the 3 aryl
groups into 3 different chemicals (Blue 1) or bonds
directly to the center carbon (Crystal Violet). For both
types of dyes, the extensive bonding responsible
for HOMO-LUMO gaps in the visible region is
destroyed.
Blue 1 (brilliant blue FCF):
Na
2
[C
37
H
34
N
2
(SO
3
)
3
]
Crystal Violet
C
25
H
30
N
3
Cl
Figure 2. Triarylmethane Dyes
Concentration Units
For the Fundamental Skills section, molarity (moles /
liter) will be used to describe the concentration of
both the crystal violet and the sodium hydroxide
reagents. However, the concentration of bleach,
which is used in the Original Investigation, is typically
reported in volume percent (volume of solute /
volume of solution x 100). Serial Dilutions
During this project, you and your team may need to
perform multiple dilutions on one or both reagents
involved in the reaction you are investigating. Often,
an easy way to approach such a task is to do a serial
dilution, where each successive dilution reduces the
concentration by the same factor. Table 2 contains
two examples for such dilutions starting with a 4.5%
stock solution (your stock solution concentration may
differ). The accuracy of a graduated cylinder is
enough for this experiment, as the solution created
will be used to obtain an entire set of absorbance /
time data. A small concentration error will not change
the relationship between the two variables. However,
this is not a general rule for serial dilutions.
Table 2. Serial Dilution Examples with Percent
Volume
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5/13
Solution
Two-fold
Dilution
(concentration
reduced by ½
with each dilution)
Ten-fold Dilution
(concentration
reduced by with each dilution)
Stock
10 mL of 4.5%
volume stock
solution
10 mL of 4.5%
stock solution
Diluted
Solution
#1
Take 5.00 mL of
4.5% stock
solution, dilute it
to 10 mL by
adding solvent to
form a 2.25%
solution.
Take 1.00 mL of
4.5% stock
solution, dilute it
to 10 mL by
adding solvent to
form a 0.45%
solution.
Diluted
Solution
#2
Take 5.00 mL of
Diluted Solution
#1, dilute it to 10
mL by adding
solvent to form a
1.125% solution.
Take 1.00 mL of
Diluted Solution
#1, dilute it to 10
mL by adding
solvent to form a
0.045% solution.
Diluted
Solution
#3
Take 5.00 mL of
Diluted Solution
#2, dilute it to 10
mL by adding
solvent to form a
0.5625%
Take 1.00 mL of
Diluted Solution
#2, dilute it to 10
mL by adding
solvent to form a
0.0045% solution.
Further
Dilutions
Continue above
pattern.
Continue above
pattern.
Note: Stock bleach concentration may vary, adjust
calculations accordingly.
GUIDING
QUESTION(S)
1.
Fundamental Skills
: What are the optimal
conditions to observe the kinetics of the crystal
violet hydroxylation? What is the reaction order of
crystal violet? 2.
Original Investigation
: You will be performing
kinetics studies on the dyes in gatorade. What are
the optimal conditions to observe the kinetics of
the bleaching of your chosen dye? (Use the 1:10
dilution process for the bleach.) What is the
reaction order of that dye? a.
Once you have found the optimal
concentration for the bleach, test this
concentration on the gatorade.
Gatorade, dyes from gatorade, and bleach
will be
provided next week and all of the laboratory
equipment or glassware used in the Fundamental
Skills section will be available. Use the Original
Investigation framework provided in stemble to help
you and your team plan a course of action to answer
the question during next week’s lab period.
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6/13
Session
One
SAFETY MOMENT
(WEEK 7):
Context of Chemical Use
Your TA will assign each team one of the household
products and a chemical it contains. Look up the SDS
for the chemical and the information about the
cleaner’s ingredients. Answer the questions for your
assigned cleaning product in the Project #3
Fundamental Skills (FS#3) In-Lab Stemble
Assignment
. Select a team member to present (in
1-2 minutes) your answers to the class.
Acetic Acid
Ethanol
Ammonium
Hydroxide
Lactic Acid
Ethylene
Glycol
Oxalic Ac
a.
What GHS symbol(s) are associated with the
chemical? What hazards do these symbols
represent?
b.
What is the most common route of exposure and
what needs to be done to prevent exposure?
c.
What is the concentration of the chemical in the
product shown?
d.
Why do you think the product is safe to
consumers despite the warnings in the chemical’s
SDS? Are there any reactions with the chemical
listed that can cause hazards or demonstrate how
the human body’s other associations with the
chemical?
FUNDAMENTAL
SKILLS
Before
your lab section: ●
Fill in the Project #3 Fundamental Skills (FS#3)
In-Lab Stemble Assignment
before the lab
session
.
At the beginning
of the lab section, your TA will:
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●
Make sure you are dressed appropriately and
have personal protective equipment (lab coat,
goggles and gloves).
●
Discuss experimental determination of reaction
orders.
●
Make sure a team leader is nominated for the
project.
Safety:
Goggles, gloves, a lab coat, thick long pants
completely covering the ankles, and sturdy water
resistant closed toed shoes are required when
performing any experiment utilizing chemicals,
glassware, and/or lab equipment in a chemistry
laboratory. Use plastic wrap to protect touched
surfaces of your laptop and personal devices.
Bookbags need to be hung on hooks under the lab
tables or placed at the front of the room, away from
chemicals. There should be no clutter and tripping
hazards on the floor.
Sodium hydroxide, bleach, and crystal violet
are corrosive and can cause eye and skin
irritation and/or burns
.
●
Strong bases (
sodium hydroxide
) are more
hazardous than the weak acid or base buffers.
Bases typically saponify skin (turn it to soap) long
before feelings of discomfort. The higher the
concentration of acid or base, the more
hazardous the chemical.
●
Avoid contact with skin and eyes. Wash affected
area immediately if a chemical comes into contact
with bare skin. If a large quantity is splashed on
you, notify a labmate and/or TA while moving
toward the eye wash (by the lab door) or shower
(in the hallway). Contaminated clothing should be
removed as soon as possible.
●
Replace gloves if they become contaminated with
chemicals, do not continue to wear the gloves and
spread the contamination throughout the lab.
●
Notify the instructor if any chemical is spilled.
Acquiring absorption spectra
:
Calibrating the Spectrometer
Obtain two visible spectrometers and two LabQuest3
per table group from the front of the lab. Use the USB
cable to connect the visible spectrometer to the
LabQuest3. Calibrate the spectrometer by clicking
. The calibration dialog box will display the
message: “Waiting…seconds for lamp to warm up.”
For best results, allow the spectrometer to warm up
completely. Do not press “Skip Warmup”.
Create a blank.
The solvent and imperfections in the
cuvette can absorb light in the same region of the
visible spectrum as your sample. To eliminate these
interferences, the spectrometer must be “blanked”.
What should be used as the blank in this case?
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●
Fill a cuvette with your solvent and wipe the
outside with Kimwipes to remove any
fingerprints or liquid. Why is this step
necessary?
●
Insert the cuvette into the spectrometer when
prompted so light passes through the clear
sides. Click Finish
Calibration
and then OK
.
Remove the cuvette when done.
Crystal Violet Absorbance Spectra
Create a Sample.
●
Pre-rinse a cuvette with 2.0 x 10
–5
M
aqueous crystal violet solution.
●
Fill the cuvette with 2.0 x 10
–5
M aqueous
crystal violet solution.
●
To obtain a spectrum, place the sample in the
spectrometer and click . Click once the data collection is complete.
●
Examine the absorbance spectrum and note
the wavelength of maximum absorbance,
λ
max
. What color of light is being absorbed
by the sample solution? How is that color
related to the color of the solution? Attach the
file to the Stemble assignment and provide
screenshots of the absorption spectra.
Crystal Violet Hydroxylation
The stockroom will provide a 0.10 M NaOH stock
solution. As a team determine how to do serial
dilutions to create at least 5 mL of 0.01 M, 0.001 M,
and 0.0001M solutions of NaOH. While taking turns
using the spectrometers, each team member is
responsible for one kinetics run with one of the above
concentrations (including the 0.10 M stock solution).
Determine which concentration provides the best
data.
To collect absorbance versus time data, go to the window, click on the mode and change it from full
spectrum to time based. Change the duration to 24
minutes and interval to 0.25 min/sample. Click OK
.
●
In the red box, check your λ
max
. If needed,
change the value of λ
max
to the value you
recorded in the “Create a Sample” steps by
clicking the red box and clicking “Change
Wavelength”. Input the correct λ
max
.
Why
is this wavelength used?
Pour 5.0-mL of the NaOH(aq) solution you prepared
and 5.0-mL of 2.0 x 10
–5
M crystal violet solution into
separate graduated cylinders. ●
Simultaneously pour the 5-mL portions of
crystal violet and sodium hydroxide into a
beaker and stir the reaction mixture
vigorously with a stirring rod.
●
Important Note:
Start with an empty cuvette.
Pre-rinse the cuvette once with ~1-mL amount
of the reaction mixture.
●
Fill the cuvette 3/4 full with reaction mixture.
Wipe the outside of the cuvette, place it in the
cuvette slot of the spectrometer so the light
passes through the clear sides of the
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cuvette. Click . Place the beaker with
the leftover reaction mixture solution in a
position where it can be observed periodically
during the next few steps.
●
Data collection will end after 24 minutes. If
you believe enough data has been collected
before 24 minutes has passed, click to
end data collection. (Note: If the initial data is
sporadic, remove those points when analyzing
your data). What has happened to the color
of the leftover solution in the beaker?
●
Place the solution in a 100 or 250 mL beaker
for neutralization at the end of the lab. Each
pair in the group should use the same beaker
to collect the waste solutions. You will
neutralize the waste with citric acid at the end.
●
Repeat the above steps for the other
concentration of NaOH.
Transferring Data from the LabQuest3:
●
Go to the File menu on the LabQuest3,
choose “Email”. Choose “Data File” (or
“Graph”, “Text File”, or “Screenshot”).
●
Enter your email address in the “To:” field. Hit
“Send”.
●
Check your email for the file. Refresh your
email, you should receive the email
immediately. If you do not receive anything
within 5 minutes, resend.
●
Repeat the process to receive the Graph, Text
File, and Screenshot of your data.
Neutralization
Combine all liquid waste into a 1L beaker and stir
gently.
●
Check the pH of the solution before moving
on. If the pH is ~7 (appropriate range = 6-8),
pour the waste down the drain. If the pH is not
7, adjust accordingly with sodium bicarbonate
or citric acid to pH 7.
●
To prevent foaming over, slowly pour the
sodium bicarbonate into the beaker and stir in
before adding more. Check the solution with a
small piece (< 1 inch) of pH paper.
●
If pH = ~7, the solution is neutral and can be
poured in the sink. ●
Use copious amounts of DI water (the small
sink faucet) to clean the glassware. This water
can go down the drain. If water beads up on
glassware or the glassware looks dirty, use 5-
10 mL of soap solution to clean the glassware
and then rinse again.
ORIGINAL
INVESTIGATION
Now it is time to answer the first Guiding Question
and create a plan to answer the second one:
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10/13
●
Fundamental Skills
: What are the optimal
conditions to observe the kinetics of the crystal
violet hydroxylation? What is the reaction order
of crystal violet? As a team, discuss these questions based on the
work you have done in the Fundamental
Skills section. ●
Original Investigation
: You will be performing
kinetics studies on the dyes in gatorade. What are
the best concentrations of bleach to observe the
kinetics of the bleaching of your assigned dye?
What is the reaction order of that dye? ○
Once you have found the optimal
concentration for the bleach, test this
concentration on the gatorade.
Planning questions can be found here
. Gatorade,
solutions of dyes found in gatorades, and a stock
bleach solution will be provided next week and all of
the laboratory equipment or glassware used in the
Fundamental Skills section will be available. Use the
Original Investigation framework provided in the
Project #3 Original Investigation (OI#3) In-Lab
Stemble assignment to help you and your team plan
a course of action to answer the question during next
week’s lab period. Session Two
PRE-LAB QUIZ Quiz #4
Session #2
A Canvas pre-lab quiz is due every week at 11:59 pm
the day before your lab section. The information
needed to answer these questions can be found in
your general chemistry lecture textbook, the Lab
Safety for Chemists online text (Sections 2.1.2), the
Odyssey program and in documents hyperlinked
within this document.
SAFETY MOMENT
(WEEK 8)
Fire Tetrahedron
The fire tetrahedron can help us to understand how to
mitigate fires when they happen. Fires need 4 things
to propagate: Fuel, Heat, an Oxidant (usually
oxygen), and the ability to propagate a chain reaction.
Taking
any one
of these four things away can put out
a flame.
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11/13
Before lighting any matches or lighter, check with
your TA and make sure no solvents or combustibles
are in the vicinity. As a team, pick up one candle, a
box of matches or lighter, an empty 100 mL beaker, a
crucible (ceramic bowl), and a squeeze bottle of
water. Do the next steps in the fume hood. You will
need to relight the candle between each step. All
matches should be placed in a beaker with water to
insure they are completely extinguished before
throwing away in the trash can. One team member is
responsible for putting out the candle out using one of
these methods:
1.
Oxygen: Put a beaker over the candle to
remove all oxygen. Real world application:
ABC fire extinguishers use monoammonium
phosphate to smother the fire.
2.
Chain reaction:
Blow the flame out to disrupt
the chemical chain reaction by disrupting the
fuel to oxygen ratio. Real world
application:
Halon fire suppression systems
directly inhibit the combustion chain reaction
through a free radical mechanism.
3.
Fuel Removal: Light a match and place it in
the crucible. The back (unlit) end of the match
should rest on the top edge of the crucible.
Observe what happens to the flame and
matchstick. Real world application:
When a
wildfire poses little safety risk or potential
damage to buildings, firefighters will establish
a barrier to contain the fire and allow it to burn
itself out.
4.
Heat Removal: Squirt the flame out with a
small squeeze bottle of water.
Real world
application: Water is used by firefighters to
control heat inside of a burning building. As
the water turns to steam, it absorbs heat from
the fire.
What is the term for the energy
required to turn water to steam?
Answer the following questions Project #3 Original
Investigation (OI#3) In-Lab Stemble Assignment
:
Which of these methods seemed to be the least
dangerous and most effective for extinguishing the
fire? What factors did you consider in making this
decision?
ORIGINAL
INVESTIGATION
As a team, proceed with the plans you outlined last
week for the Original Investigation
. Note:
Bleach is
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Project #3: Kinetics of Gatorade W24
https://docs.google.com/document/u/1/d/e/2PACX-1vRgJuqq1OmcvN3lL31UVXe-M3KHBPeimqX3qrtMQoryHUAi3wL8YgVcduTWdp4oEHX07RssjeQ6N0_t/…
12/13
NOT neutralized, it is washed down the sink with
copious amounts of water.
Once your data collection and analysis is complete,
create a “poster” on your lab bench with the
blackboard markers provided by your TA containing
the following sections:
●
Guiding Question:
Restate Guiding Question
#2. Do not feel that you have to write it word-
for-word as it appears on the previous page. ●
Claim:
Answer to Guiding Question #2.
●
Evidence:
For this experiment, no content
from Fundamental Skills
(i.e. your answer to
Guiding Question #1) needs to be included,
as it should have informed your approach to
the Original Investigation
. Decide as a team
how the information found in the Original
Investigation
should be incorporated as
concisely as possible.
●
Justification:
How does the evidence you
included support your claim? What
assumptions made or scientific theories/laws
were invoked during data analysis and
interpretation? ●
Comments:
The team leader should take
down important ideas gained from other
teams during the poster presentation.
ARGUMENTATION
(POSTER SESSION)
You and your team will then compare and contrast
your results with your peers during the poster
session. Nominate one team member will be your
“spokesperson” who will stay with the poster and
answer any questions from your labmates. (Each
project will have a different spokesperson.) The rest
of the team will be “travelers” who will go to other
posters and engage in discussion about data
collection and interpretation. The goal during this
session, this Argumentation
, is to challenge your
peers’ reasoning and reevaluate your own.
Spokespersons and travelers should discuss the
claim using the evidence to justify their own point of
view. What you discover during this process is pivotal
for creating a good Lab Report
. The three boldface questions
below apply to all
projects. A few sample questions specific to this
project are provided here to help the spokesperson
prepare and travelers initiate in-depth discussion
while at each poster.
●
What concept(s) were you investigating and
how are they related to the guiding
question(s)?
●
How did you go about your work and why?
●
What is your claim? How does your evidence
justify your claim?
At the end of the poster session, completely clean the
poster from the lab bench as directed by your TA then
your team should hold a short discussion to re-
evaluate your claim based on what they have learned
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2/6/24, 8:03 PM
Project #3: Kinetics of Gatorade W24
https://docs.google.com/document/u/1/d/e/2PACX-1vRgJuqq1OmcvN3lL31UVXe-M3KHBPeimqX3qrtMQoryHUAi3wL8YgVcduTWdp4oEHX07RssjeQ6N0_t/…
13/13
during the poster session. If time permits, you can
collect more data. Take a picture of the “poster” and attach it to the
appropriate field in the
Project #3 Original
Investigation (OI#3) In-Lab assignment
.
Once you
have finished all your work on the In-Lab
page,
review the assignment formatting document before
leaving lab.
LAB REPORT
The lab report is an individual, not team effort. The
content of the report is based on the evidence, claim,
and justification your team shared during the
argumentation section and the understanding you
gained by comparing those ideas against those of
other teams. (Be willing to adjust your justification
and/or claim in response to what you learn in the
argumentation poster session.)
Use the rubric and the boldfaced questions above to
structure your lab report. The first page should
answer the first two questions shown above, the
second page should answer the third question.
However, these are formal reports, not separate
responses to the three individual questions - make
sure your writing flows and creates a cohesive
message.
Lab Report: Review the assignment
formatting document before the next step. Complete
the Project #3 Lab Report (LR#3) Stemble
assignment
by 11:59 pm the day before your week 7
lab period.
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[] → Ca(CIO)₂(aq) + H₂O(1)
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Predict the reactants of this chemical reaction. That is, fill in the left side of the chemical equation. Be sure the equation you submit is balanced. (You can edit
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The nlx notation of 81Tl is:
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7₂22
6-27
ماره
Y
km
a fumax
b=um max
=1.4673
kom=
<=0,6815 mM min
The kinetic data in the following table were obtained for the
reaction of carbon dioxide and water to produce bicarbonate and
hydrogen ion catalyzed by carbonic anhydrase:
CO2 + H2O - HCO3 + H+
[H. De Voe and G. B. Distiakowsky, J. Am. Chem. Soc. 83, 274
(1961)].
km=a
Vmax=-
CO₂ Concentration, mmol/L
1.25
2.5
5.0
20.0
From these data, use a Lineweaver-Burk plot to determine K and
Vmax for the reaction.
=96173
0.4
1/Velocity (sec/M)
36 x 10³
20 x 10³
12 x 103
6 x 10³
31 You do an enzyme kinetic experiment and calculate a Vmax of 1
If each assay used 0.1 mL of ar
μmol of product per minute.
enzyme solution that had a concentration of 02 mg/mL, what
the turnover number if the enzyme had a molecular weight
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O CHEMICAL REACTIONS
Natalie
Solving for a reactant in solution
Sodlum hydrogen carbonate (NaHCO,), also known as sodium bicarbonate or "baking soda", can be used to relieve acid Indigestion. Acid indigestlon Is the
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Suppose the fluid in the stomach of a woman suffering from indigestion can be considered to be 250. mL of a 0.043 M HCl solution. What mass of NaHCO,
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- eleganceextreme1 X (208) + X 7571&snapshotld=1324548&id =563649000&takeld=4bfba59b09f0e5b& aSearch this course References Use the References to access important values if needed for this question. A student ran the following reaction in the laboratory at 639 K: H2(g) + I>(g 2HI(g) A-Z When she introduced 0.311 moles of HI(g) into a 1.00 liter container, she found the equilibrium concentration of HI(g) to be 0.249 M. Calculate the equilibrium constant, K, she obtained for this reaction. Kc Submit Answer K from [Initial] and One [Equilibrium]: This is group attempt 1 of 5 Next Autosaved at 12:59 PM Back 1:05 PM 4x 11 9/24/2019 hp delete prt sc insert 12 f11 10 144arrow_forwardM Mathway | Chemistry Problem So X A ALEKS-Andrew Herrera ← → C ||| = www-awa.aleks.com/alekscgi/x/lsl.exe/1o_u-IgNslkr7j8P3jH-lvgXwPgmUhvITCeeBZbufuBYTi0Hz7m7D3ZcKsCEJuQCTg70iQiXu9bAsbFEhEkLFd_JMgnDGQSUWa 80°F Sunny O ELECTROCHEMISTRY Writing the half-reactions of a single-displacement reaction Study this chemical reaction: Ca(s)+ZnCl₂(aq) Then, write balanced half-reactions describing the oxidation and reduction that happen in this reaction. oxidation: reduction: Explanation - Check X + Zn(s)+CaCl₂(aq) ‒‒ ▬ ローロ 00 X Q Search S 4 LDL © 2023 McGraw Hill LLC. All Rights Reserved. Terms of Use | Priv CO 3 C 4 6arrow_forward(10) Good Morning Pakistan M Gmail T LI YouTube Maps GTranslate holodeck www-awu.aleks.com/alekscgi/x/Isl.exe/1o_u-IgNslkr7j8P3jH-lvdw7xgLCkqMfg8yaFKbD9GafJstkYLIJnusuqH-p1X_sK5Jf4E3cmXkMkyF9tYadmgkkpbMT2ejVO2limOXTcRDH8UEjl_2?10Bw7Q... Initial Knowledge Check mg I Don't Know News Type here to search +33a8d475-a67b-48e1-be0e-1154 x Submit College information A certain drug has a half-life in the body of 1.5 h. Suppose a patient takes one 50.0 mg pill at 7:00PM and another identical pill 90 min later. Calculate the amount of drug left in his body at 9:00PM. Be sure your answer has a unit symbol, if necessary, and round it to 3 significant digits. II x10 ALEKS - Rafia Riaz - Knowledge CX X H Success Confirmation of Question X + Question 20 © 2023 McGraw Hill LLC. All Rights Reserved. Terms of Use 35°F Cloudy Privacy Center Rafia V Ar Accessibility x Other bookmarks 8:16 PM 1/31/2023arrow_forward
- Lecture X zm CHM12 x Assign X ChatGP X Cedxb Home xb Answer X M Inbox ( X M Inbox ( X Google x | ← → Cmoodle.uog.edu.gy/mod/quiz/attempt.php?attempt=143670&cmid=59476 M Gmail YouTube My courses 15 Google Calendar Periodic table - Cre... AccessPharmacy -... Cart Maison Fran... Exploring the Impa... 25:00 - Time to foc... UG_MOODLE 2023 2024 Home Dashboard My courses Search Question 11 Not yet answered Marked out of 1.00 Flag question OH HO CH₂ Phenylephrine (PE, see the structure below) is a nasal decongestant and is the active ingredient in Sudafed, which contains phenylephrine hydrochloride (PEHCI). This conjugate acid of phenylephrine (PEH+) has a pKa = 5.5. At a physiological pH of 7.4. What is the ratio of concentrations, [PE]/[PEH+]? O a. 79 O b. 0.14 ○ c. 21 O d. 6.7 ○ ○ e. 0.01 Clear my choice ZM ? = ☑ - 0 В >> All Bookmarks Quiz navigation 2 3 5 6 15 BC 10 12 13 14 Finish attempt... 10:49 AM 4/26/2024arrow_forwardIs it correctarrow_forwardCalc molar massarrow_forward
- M Mathway | Chemistry Problem So x A ALEKS-Andrew Herrera ← → C = www-awa.aleks.com/alekscgi/x/Isl.exe/1o_u-IgNslkr7j8P3jH-lvgXwPgmUhvITCeeBZbufuBYTI0Hz7m7D3ZcKsCEJuQCTg70iQiXu9bAsbFEhEkLFd_JMgnDGQSUWa... ☆ OTHERMOCHEMISTRY Calculating specific heat capacity -1 J.g.K A chemist carefully measures the amount of heat needed to raise the temperature of a 517.0 mg sample of a pure substance from -4.5 °C to 13.7 °C. The experiment shows that 2.21 J of heat are needed. What can the chemist report for the specific heat capacity of the substance? Round your answer to 3 significant digits. Explanation Russell 2000 -1.06% -1 Check x X + EN ‒‒ X Q Search S - 1/5 BLO R 50 Andr E © 2023 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Accessibility Co 10:15 AM 7/14/2023arrow_forwardwww-awu.aleks.com/alekscgi/x/Isl.exe/1o_u-IgNslkr7j8P3jH-IvWyv8WYLP6W0cqJcWJdIACROQwyw24GWHInMM72ts1NTBcSzwZOGGhrmlP4yCeje RhX9HIzqlzRTj2iaDBXTCRIHYWNO MEASUREMENT AND MATTER Using mass density to find mass or volume 6°F Mostly cloudy A chemistry student needs 90.0 mL of diethylamine for an experiment. By consulting the CRC Handbook of Chemistry and Physics, the student discovers that -3 the density of diethylamine is 0.706 g cm . Calculate the mass of diethylamine the student should weigh out. Round your answer to 3 significant digits. 0 g JQ Explanation Check X 5 Q Search 3/5 L 2023 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Access Oarrow_forwardM Mathway | Chemistry Problem So x A ALEKS-Andrew Herrera ← → C = www-awa.aleks.com/alekscgi/x/Isl.exe/10_u-IgNslkr7j8P3jH-lvgXwPgmUhvITCeeBZbufuBYTI0Hz7m7D3ZcKsCEJuQCTg70iQiXu9bAsbFEhEkLFd_JMgnDGQSUWa... ☆ USD/CAD +0.79% OCHEMICAL REACTIONS Identifying oxidized and reduced reactants in a single-... 2Fe(s) + 3 CuCl(aq) → 2FeCl, (aq) + 3Cu(s) X + For each reaction, write the chemical formulae of the oxidized reactants in the space provided. Write the chemical formulae of the reduced reactants in the space provided. Explanation 2 AgNO3(aq) + Mg(s) + 2Ag(s) + Mg(NO₂)₂ (aq) FeSO₂ (aq) + Zn(s) Fe(s) + ZnSO₂ (aq) Check Q Search reactants 0 oxidized: reactants reduced: reactants oxidized: reactants reduced: reactants oxidized: reactants reduced: LD A FO F10 X 00 O▬▬▬▬ 0/5 S FIL 4 Prisc Andrew V Delete FEE © 2023 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Accessibility G KO POD 10:19 AM 7/14/2023 all Ar ☐arrow_forward
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