Practice Acid Base Equilibria

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Kennesaw Mountain High School *

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CALCULUS

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Chemistry

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Nov 24, 2024

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docx

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2

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Practice Acid-Base Equilibria 1. What is the pH of a 0.75 M solution of aqueous ammonia? K b = 1.8 x 10 -5 . 2. Classify the following as a strong or weak acid/base. Justify your answer. Then place them in order from lowest to highest pH. a. Chloric Acid b. Ammonium chloride c. Calcium hydroxide d. Ethylamine (CH 3 CH 2 NH 2 ) 3. Measurements show that the pH of a 0.10 M solution of acetic acid is 2.87. What is the K b for potassium acetate? 4. Hydrolysis of salts refers to the reactions of salt ions with water. Classify the following salts as an acid, base or neutral. Write the hydrolysis reaction to support your claim. a. Sodium nitrite b. Ammonium chloride 5. Which pair of chemical species is not a conjugate acid base pair? a. H 2 CO 3 and CO 3 2- b. OH - and H 2 O c. HPO 4 2- and PO 4 3- d. NH 3 and NH 4 + 6. Equal molar of each of the following salts is dissolved in one liter of water. Write them in order of increasing pH of the resulting solutions. a. KCl b. Na 2 CO 3 c. NH 4 Cl
7. What is the percent ionization of a 0.10 M solution of hydroazoic acid, HN 3 ? K a = 1.9 x 10 -5 . 8. Sulfurous acid is a diprotic acid. K a1 = 1.7 x 10 2- K a2 = 6.4 x 10 8- a. Write the net ionic equation for the aqueous ionization that corresponds to K a1 . b. Write the net ionic equation for the aqueous ionization that corresponds to the K a2 . c. Identify the conjugate acid base pairs in each of your two equations. d. Identify any amphoteric species, other than water, in your equations. e. Assume the amphoteric species you identified in part d is a base. Write the ionic equation for it aqueous ionization and calculate the corresponding K b . f. Is an aqueous solution of NaHSO 3 acidic or basic? Explain your reasoning. g. Calculate the pH of a 0.50 M solution of NaHSO 3 .
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