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York University *
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Course
1010
Subject
Chemistry
Date
Nov 24, 2024
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1
Uploaded by ProfessorPencil6277
Question
4.
Use
molecular
orbital
theory
to
determine
whether
He22*
or
He*
is
more
stable.
Draw
the
molecular
orbital
diagram
for
each
and
explain
your
answer.
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Related Questions
4. Tetrachloroethene (CCI2=CCI2) does not have a dipole moment. Explain this fact on the basis of the
shape of CCI2=CCI2.
arrow_forward
Draw the molecular orbital diagram shown to determine which of the following is most stable.
B2, N2^2+, C2^2-, B2^2+, C2^2+
arrow_forward
I. Draw the molecular orbital diagram for the valence
electrons in the generic, diatomic ion X22+. Each neutral
atom of X contains 5 valence electrons. Use the
"reversed" energy ordering (for B2, C2, N2) where o2p is
higher in energy than n2p. The diagram has been started
for you below. Label all molecular orbitals.
Energy
2p
2p
2s
2s
X atom
Molecule
X atom
II. Calculate the bond order of X2*.
III. How would the bond length and bond strength of X22+
compare with neutral X2? Briefly explain why (in about 1
sentence).
arrow_forward
a) Identify atomic orbital #1 and #2. Indicate the number of radial and angular nodes for both
b) What type of molecular orbital (σ, π, or no interaction) will be formed when these orbitals approach each other along the x axis? Describe the orbital overlap if applicable. Assume that the atomic orbitals are at appropriate energy levels to mix.
arrow_forward
Using the following atomic orbital pictures and radial probability distribution plots:
a) Identify atomic orbital #1. Indicate the number of radial and angular nodes.
b) Identify atomic orbital #2. Indicate the number of radial and angular nodes.
c) What type of molecular orbital (o, T, or no interaction) will be formed when these orbitals
approach each other along the x axis? Describe the orbital overlap if applicable. Assume that the
atomic orbitals are at appropriate energy levels to mix
Atomic Orbital #1
PR
007
0.06
05
004
03
0.02
0.01
10
20
30
r (ao)
Atomic Orbital #2
R
012
0.06
04
02
10
15
20
25
r (ao)
JSmol
arrow_forward
I need the Hybridization, Overlapping orbitals, and Molecular geometry.
arrow_forward
Question in photo
arrow_forward
Shown below is the molecular orbital diagram for N2 (with the electrons omitted).
Which statement is not correct about N2*?
+++
+++
2p
2p
2s
2s
N2
N
arrow_forward
The research group has recently focused on identifying the chemical properties of fluorocarbons, such as CF4 and C2F4. These fluorocarbons display a very different reactivity compared to hydrocarbons.
Draw the molecular orbital theory diagrams for C-F and C-H bonds. Describe the difference between the C-F and C-H bond.
arrow_forward
9) HCCCO₂H, is an organic hydrocarbon.
a) Draw a geometrically accurate structure so that the formal charge of each
atom is zero identifying the bond angles (Draw it BIG!).
b) Identify the hybridization about each atom (not H) forming a bond
c) How many o or π bonds are there in this molecule
d) The combustion of the hydrocarbon produces carbon dioxide and water in
the gaseous state. Use average bond enthalpies to determine enthalpy of
reaction
arrow_forward
A Moving to another question will save this response.
Question 1
Which is the correct molecular orbital diagram for O 2 ion?
Oo 2s 1lo 2s t 1 T2p 1 1.t102p tI 2p t
o 2s 1ļo 2s 11 m2p 1102p 1 1 72p tt t
o 2s 1lo 2s 11 T|2p 1 1. t102p t 2p t1
o 2s 1ļo 2s 1 2p ↑ 1. t L. t I o2p ↑ 1 12p t
O o 2s 1io 2s t I 12p ↑ 1 02p ↑ 1 12p t 1.t
A Moving to another question will save this response.
arrow_forward
Nitric oxide (NO) is an important signaling molecule in biological systems. Two ions
based on NO are also known: the nitrosonium cation (NO*) and the nitroxyl anion (NO).
Construct the molecular orbital diagram for NO (Note: s-p mixing is significant in NO). To
the side, sketch the combinations of AOs that contribute to each MO.
b. Explain how your diagram illustrates the difference in electronegativity between N and O.
Predict the bond order and number of unpaired electrons in NO.
d. Predict the bond order and number of unpaired electrons in the ions NO* and NO". Which
of the three species would you predict to have the shortest bond? Explain why.
а.
С.
arrow_forward
Complete the table below, which lists information about some diatomic molecules or molecular ions.
In particular:
. Decide whether each molecule is stable or not.
. Decide whether each molecule would be diamagnetic or paramagnetic.
Calculate each molecule's bond order.
●
molecule
+
N
2
H₂
N₂
stable?
O yes
O no
O
yes
no
yes
no
diamagnetic or
paramagnetic?
diamagnetic
O paramagnetic
diamagnetic
paramagnetic
diamagnetic
paramagnetic
OLO
OO
bond order
0
0
0
00
X
arrow_forward
Find the hybrid orbital type for each atom, the carbon-carbon-oxygen bond angle, the molecular geometry of oxygen, and the number of sigma and pi bonds in the molecule.
arrow_forward
Help with this please.
Use the Molecular Orbital Theory to indicate the bond order, and paramagnetism or diamagnetism of O2, O2+, and O2-.
arrow_forward
I wanna help to answer this questions
Thanks a lot
arrow_forward
Molecule
C2H2
SFs-
NO3-
Lewis structure
include lone pairs &
formal charges on each
atom
Resonance
structures
don't have to include
lone pairs; write N/A if
there are none
Electron Geometry
Hybridization
on central atom
Overlapping
orbitals
O:
O:
include value of n in the
orbital name (e.g. 1s, not
s). Write N/A if that kind
T:
of bond is not present in
T:
the molecule
Molecular
Geometry
Bond angle(s)
include < as necessary
3D structure and
polarity
don't have to include
lone pairs; draw the
dipole arrow on the
molecule or write "non-
polar"
arrow_forward
5.Examine the model and real structures for XeF2.
A.What is unusual about the chemical identity of the central atom in this molecule?
B.Is this molecule polar or non-polar, explain how you arrived at your decision?
arrow_forward
2. Use the molecular orbital diagram shown to find the bond
magnetism, and stability of the following. Indicate which is
stable.
2+
C₂²+
2+
N₂²+
B₁₂
C, 2-
B₂2+
Bond Order para- or diamagnetic?
Atomic
orbitals
2p
2s
Molecular
orbitals
$
P2p
52p
P2P
524
B2, C₂, N₂
Atomic
orbitals
2p
order,
most
arrow_forward
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Related Questions
- 4. Tetrachloroethene (CCI2=CCI2) does not have a dipole moment. Explain this fact on the basis of the shape of CCI2=CCI2.arrow_forwardDraw the molecular orbital diagram shown to determine which of the following is most stable. B2, N2^2+, C2^2-, B2^2+, C2^2+arrow_forwardI. Draw the molecular orbital diagram for the valence electrons in the generic, diatomic ion X22+. Each neutral atom of X contains 5 valence electrons. Use the "reversed" energy ordering (for B2, C2, N2) where o2p is higher in energy than n2p. The diagram has been started for you below. Label all molecular orbitals. Energy 2p 2p 2s 2s X atom Molecule X atom II. Calculate the bond order of X2*. III. How would the bond length and bond strength of X22+ compare with neutral X2? Briefly explain why (in about 1 sentence).arrow_forward
- a) Identify atomic orbital #1 and #2. Indicate the number of radial and angular nodes for both b) What type of molecular orbital (σ, π, or no interaction) will be formed when these orbitals approach each other along the x axis? Describe the orbital overlap if applicable. Assume that the atomic orbitals are at appropriate energy levels to mix.arrow_forwardUsing the following atomic orbital pictures and radial probability distribution plots: a) Identify atomic orbital #1. Indicate the number of radial and angular nodes. b) Identify atomic orbital #2. Indicate the number of radial and angular nodes. c) What type of molecular orbital (o, T, or no interaction) will be formed when these orbitals approach each other along the x axis? Describe the orbital overlap if applicable. Assume that the atomic orbitals are at appropriate energy levels to mix Atomic Orbital #1 PR 007 0.06 05 004 03 0.02 0.01 10 20 30 r (ao) Atomic Orbital #2 R 012 0.06 04 02 10 15 20 25 r (ao) JSmolarrow_forwardI need the Hybridization, Overlapping orbitals, and Molecular geometry.arrow_forward
- Question in photoarrow_forwardShown below is the molecular orbital diagram for N2 (with the electrons omitted). Which statement is not correct about N2*? +++ +++ 2p 2p 2s 2s N2 Narrow_forwardThe research group has recently focused on identifying the chemical properties of fluorocarbons, such as CF4 and C2F4. These fluorocarbons display a very different reactivity compared to hydrocarbons. Draw the molecular orbital theory diagrams for C-F and C-H bonds. Describe the difference between the C-F and C-H bond.arrow_forward
- 9) HCCCO₂H, is an organic hydrocarbon. a) Draw a geometrically accurate structure so that the formal charge of each atom is zero identifying the bond angles (Draw it BIG!). b) Identify the hybridization about each atom (not H) forming a bond c) How many o or π bonds are there in this molecule d) The combustion of the hydrocarbon produces carbon dioxide and water in the gaseous state. Use average bond enthalpies to determine enthalpy of reactionarrow_forwardA Moving to another question will save this response. Question 1 Which is the correct molecular orbital diagram for O 2 ion? Oo 2s 1lo 2s t 1 T2p 1 1.t102p tI 2p t o 2s 1ļo 2s 11 m2p 1102p 1 1 72p tt t o 2s 1lo 2s 11 T|2p 1 1. t102p t 2p t1 o 2s 1ļo 2s 1 2p ↑ 1. t L. t I o2p ↑ 1 12p t O o 2s 1io 2s t I 12p ↑ 1 02p ↑ 1 12p t 1.t A Moving to another question will save this response.arrow_forwardNitric oxide (NO) is an important signaling molecule in biological systems. Two ions based on NO are also known: the nitrosonium cation (NO*) and the nitroxyl anion (NO). Construct the molecular orbital diagram for NO (Note: s-p mixing is significant in NO). To the side, sketch the combinations of AOs that contribute to each MO. b. Explain how your diagram illustrates the difference in electronegativity between N and O. Predict the bond order and number of unpaired electrons in NO. d. Predict the bond order and number of unpaired electrons in the ions NO* and NO". Which of the three species would you predict to have the shortest bond? Explain why. а. С.arrow_forward
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Chemistry by OpenStax (2015-05-04)
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