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York University *
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Course
1010
Subject
Chemistry
Date
Nov 24, 2024
Type
png
Pages
1
Uploaded by ProfessorPencil6277
Question
4.
Use
molecular
orbital
theory
to
determine
whether
He22*
or
He*
is
more
stable.
Draw
the
molecular
orbital
diagram
for
each
and
explain
your
answer.
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Related Questions
4. Tetrachloroethene (CCI2=CCI2) does not have a dipole moment. Explain this fact on the basis of the
shape of CCI2=CCI2.
arrow_forward
Draw the molecular orbital diagram shown to determine which of the following is most stable.
B2, N2^2+, C2^2-, B2^2+, C2^2+
arrow_forward
I. Draw the molecular orbital diagram for the valence
electrons in the generic, diatomic ion X22+. Each neutral
atom of X contains 5 valence electrons. Use the
"reversed" energy ordering (for B2, C2, N2) where o2p is
higher in energy than n2p. The diagram has been started
for you below. Label all molecular orbitals.
Energy
2p
2p
2s
2s
X atom
Molecule
X atom
II. Calculate the bond order of X2*.
III. How would the bond length and bond strength of X22+
compare with neutral X2? Briefly explain why (in about 1
sentence).
arrow_forward
a) Identify atomic orbital #1 and #2. Indicate the number of radial and angular nodes for both
b) What type of molecular orbital (σ, π, or no interaction) will be formed when these orbitals approach each other along the x axis? Describe the orbital overlap if applicable. Assume that the atomic orbitals are at appropriate energy levels to mix.
arrow_forward
I need the Hybridization, Overlapping orbitals, and Molecular geometry.
arrow_forward
Question in photo
arrow_forward
Shown below is the molecular orbital diagram for N2 (with the electrons omitted).
Which statement is not correct about N2*?
+++
+++
2p
2p
2s
2s
N2
N
arrow_forward
The research group has recently focused on identifying the chemical properties of fluorocarbons, such as CF4 and C2F4. These fluorocarbons display a very different reactivity compared to hydrocarbons.
Draw the molecular orbital theory diagrams for C-F and C-H bonds. Describe the difference between the C-F and C-H bond.
arrow_forward
9) HCCCO₂H, is an organic hydrocarbon.
a) Draw a geometrically accurate structure so that the formal charge of each
atom is zero identifying the bond angles (Draw it BIG!).
b) Identify the hybridization about each atom (not H) forming a bond
c) How many o or π bonds are there in this molecule
d) The combustion of the hydrocarbon produces carbon dioxide and water in
the gaseous state. Use average bond enthalpies to determine enthalpy of
reaction
arrow_forward
B. Answer the next two questions about the Lewis structure
of XYZ shown below.
メー三
-YEz:
I. What is the hybridization of the central atom?
II. For all covalent bonds, specify the type of bond (o vs. T)
and the atomic orbitals that overlap to form the bond.
For example, in a molecule of H2, the only bond is o:
H(s)-H(s).
arrow_forward
Complete the table below, which lists information about some diatomic molecules or molecular ions.
In particular:
. Decide whether each molecule is stable or not.
. Decide whether each molecule would be diamagnetic or paramagnetic.
Calculate each molecule's bond order.
●
molecule
+
N
2
H₂
N₂
stable?
O yes
O no
O
yes
no
yes
no
diamagnetic or
paramagnetic?
diamagnetic
O paramagnetic
diamagnetic
paramagnetic
diamagnetic
paramagnetic
OLO
OO
bond order
0
0
0
00
X
arrow_forward
Find the hybrid orbital type for each atom, the carbon-carbon-oxygen bond angle, the molecular geometry of oxygen, and the number of sigma and pi bonds in the molecule.
arrow_forward
Help with this please.
Use the Molecular Orbital Theory to indicate the bond order, and paramagnetism or diamagnetism of O2, O2+, and O2-.
arrow_forward
I wanna help to answer this questions
Thanks a lot
arrow_forward
Molecule
C2H2
SFs-
NO3-
Lewis structure
include lone pairs &
formal charges on each
atom
Resonance
structures
don't have to include
lone pairs; write N/A if
there are none
Electron Geometry
Hybridization
on central atom
Overlapping
orbitals
O:
O:
include value of n in the
orbital name (e.g. 1s, not
s). Write N/A if that kind
T:
of bond is not present in
T:
the molecule
Molecular
Geometry
Bond angle(s)
include < as necessary
3D structure and
polarity
don't have to include
lone pairs; draw the
dipole arrow on the
molecule or write "non-
polar"
arrow_forward
5.Examine the model and real structures for XeF2.
A.What is unusual about the chemical identity of the central atom in this molecule?
B.Is this molecule polar or non-polar, explain how you arrived at your decision?
arrow_forward
Part 1) Select the correct description of the hybrid orbitals that are involved in the sigma
bond between C2 and C3 in the structure. choose from answers A through E.
Part 2) How many total sigma bonds exist in this structure? Choose from answers F through
1.
Part 3) How many total pi bonds exist in this structure? Choose from answers J through M.
Cl
H
C=C=C
2 3
H
Cl
arrow_forward
What are the angles a and b in the actual molecule of which this is a Lewis structure?
H-
H
a-0°
b = 1⁰
C
H
a
b
H
Note for advanced students: give the ideal angles, and don't worry about small differences from the ideal that might be caused by the fact that different electron
groups may have slightly different sizes.
X
S
arrow_forward
What is the atomic orbital and molecular orbital energy diagram for Li2+?
arrow_forward
Construct the molecular orbital diagram for SrCl. Would yo u expect the bond length of SrCl+ to be longer or shorter than that of SrCl? Explain and elaborate.
arrow_forward
Complete the table below, which lists information about some diatomic molecules or molecular ions.
In particular:
. Decide whether each molecule is stable or not.
●
Decide whether each molecule would be diamagnetic or paramagnetic.
. Calculate each molecule's bond order.
molecule
B
2
C₂
H₂
stable?
O
оо
yes
no
yes
no
yes
no
diamagnetic or
paramagnetic?
diamagnetic
paramagnetic
diamagnetic
paramagnetic
diamagnetic
O paramagnetic
bond order
0
0
0
00
arrow_forward
2) a) Consider the following molecule . Given what you have learned about hybridization theory, draw an image or images explaining the bonding situation in this molecule. I want you to draw out all of the orbitals, hybrid orbitals and how they overlap to form the bonds in the molecule. Indicate the % s or p character in the given atomic and hybrid orbitals. Which C-C bond or bonds are the longest? In a paragraph or so explain the image or images you just drew.
b) Lastly, consider the molecule below. Indicate the Molecular formula, the molar mass, label the hybridization of each atom except for hydrogen, indicate any chiral centers with a *, which bond or bonds are the shortest, identify by name of each functional group with an arrow pointing to the group.
arrow_forward
1.) Use the VSEPR model to determine the three-dimensional shapes ofcarbon tetraiodide, CI4, and phosphine, PH3.
Circle the correct answer! Choose only 1.
CI4:
Linear
trigonal planar
bent
tetrahedral
trigonal pyramidal
trigonal bipyramidal
seesaw
T-shaped
Octahedral
square pyramidal
square planar
Circle the correct answer! Choose only 1.
PH3:
Linear
trigonal planar
bent
tetrahedral
trigonal pyramidal
trigonal bipyramidal
seesaw
T-shaped
Octahedral
square pyramidal
square planar
2.) Identify the polarity of carbon dioxide (CO2) and water (H2O) based upon its geometry and the dipole moments of the individual bonds.
Circle the correct answer! Choose only 1.
carbon dioxide:
Polar
nonpolar
Circle the correct answer! Choose only 1.water:
polar
nonpolar
arrow_forward
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Related Questions
- 4. Tetrachloroethene (CCI2=CCI2) does not have a dipole moment. Explain this fact on the basis of the shape of CCI2=CCI2.arrow_forwardDraw the molecular orbital diagram shown to determine which of the following is most stable. B2, N2^2+, C2^2-, B2^2+, C2^2+arrow_forwardI. Draw the molecular orbital diagram for the valence electrons in the generic, diatomic ion X22+. Each neutral atom of X contains 5 valence electrons. Use the "reversed" energy ordering (for B2, C2, N2) where o2p is higher in energy than n2p. The diagram has been started for you below. Label all molecular orbitals. Energy 2p 2p 2s 2s X atom Molecule X atom II. Calculate the bond order of X2*. III. How would the bond length and bond strength of X22+ compare with neutral X2? Briefly explain why (in about 1 sentence).arrow_forward
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- Shown below is the molecular orbital diagram for N2 (with the electrons omitted). Which statement is not correct about N2*? +++ +++ 2p 2p 2s 2s N2 Narrow_forwardThe research group has recently focused on identifying the chemical properties of fluorocarbons, such as CF4 and C2F4. These fluorocarbons display a very different reactivity compared to hydrocarbons. Draw the molecular orbital theory diagrams for C-F and C-H bonds. Describe the difference between the C-F and C-H bond.arrow_forward9) HCCCO₂H, is an organic hydrocarbon. a) Draw a geometrically accurate structure so that the formal charge of each atom is zero identifying the bond angles (Draw it BIG!). b) Identify the hybridization about each atom (not H) forming a bond c) How many o or π bonds are there in this molecule d) The combustion of the hydrocarbon produces carbon dioxide and water in the gaseous state. Use average bond enthalpies to determine enthalpy of reactionarrow_forward
- B. Answer the next two questions about the Lewis structure of XYZ shown below. メー三 -YEz: I. What is the hybridization of the central atom? II. For all covalent bonds, specify the type of bond (o vs. T) and the atomic orbitals that overlap to form the bond. For example, in a molecule of H2, the only bond is o: H(s)-H(s).arrow_forwardComplete the table below, which lists information about some diatomic molecules or molecular ions. In particular: . Decide whether each molecule is stable or not. . Decide whether each molecule would be diamagnetic or paramagnetic. Calculate each molecule's bond order. ● molecule + N 2 H₂ N₂ stable? O yes O no O yes no yes no diamagnetic or paramagnetic? diamagnetic O paramagnetic diamagnetic paramagnetic diamagnetic paramagnetic OLO OO bond order 0 0 0 00 Xarrow_forwardFind the hybrid orbital type for each atom, the carbon-carbon-oxygen bond angle, the molecular geometry of oxygen, and the number of sigma and pi bonds in the molecule.arrow_forward
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