ORGANIC CHEM. VOL.1+2-W/WILEYPLUS
12th Edition
ISBN: 9781119304241
Author: Solomons
Publisher: WILEY C
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Chapter SRP, Problem 8P
Interpretation Introduction
Interpretation:
The structure of the product(s) formed in the Diels-Alder reaction of cyclopentadiene with ethene at the given temperature is to be written.
Concept Introduction:
In a Diels-Alder reaction, dienophile is reacted with a conjugated diene. Such reactions are called pericyclic reactions. In this reaction, two π-bonds are converted to two new stronger σ-bonds.
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Record the amounts measured and
calculate the percent yield for Part 2
in the table below.
Dicyclopentadiene
measured in volume
Cyclopentadiene
measured in grams
0
Measured
Calculated
Mol
Yield
Mass (g) or Volume (mL)
Mass (g) or Volume (ml)
0.6
2.955
Part 2 Measurements and Results
Record the amounts measured and calculate the percent yield for Part 2 in the table below.
0.588
0.0044
2.868
0.0434
N/A
Table view List view
Measured
Calculated
Mol
$ Yield
Melting Point (C)
Mass (g) or Volume (ml)
Mass (g) or Volume (ml.)
Cyclopentadiene
0.1
0.08
0.001189
measured in volume
Maleic Anhydride
0.196
N/A
cis-norbornene-5,6-endo-
dicarboxylic anhydride
0.041
0.0002467
N/A
N/A
N/A
0.002
N/A
N/A
128
Draw the condensed structural formula and line-angle formula for each:
2,3-dimethylheptane
3-bromo-2-pentanol
3-isopropyl-2-hexene
4-chlorobutanoic acid
Record the IUPAC names for each of the structures shown below.
a)
b)
c)
OH
d)
OH
e)
Chapter SRP Solutions
ORGANIC CHEM. VOL.1+2-W/WILEYPLUS
Ch. SRP - 1. Arrange the compounds of each of the following...Ch. SRP - 2. Arrange the compounds of each of the following...Ch. SRP - Predict the final product from each of the...Ch. SRP - Prob. 4PCh. SRP - Write detailed mechanisms for each of the...Ch. SRP - Prob. 6PCh. SRP - Prob. 7PCh. SRP - Prob. 8PCh. SRP - Prob. 9PCh. SRP - Give stereochemical structures for compounds AD:
Ch. SRP - Prob. 11PCh. SRP - The remaining steps in the industrial synthesis of...Ch. SRP - Prob. 13PCh. SRP - Prob. 14PCh. SRP - Prob. 15PCh. SRP - Prob. 16PCh. SRP - 17. Show how you would modify the synthesis given...Ch. SRP - Prob. 18PCh. SRP - Give structures for compounds AD. Compound D gives...Ch. SRP - The tranquilizing drug meprobamate (Equanil or...Ch. SRP - Prob. 21PCh. SRP - 22. Outlined here is the synthesis of a central...Ch. SRP - 23. What are compounds A and B? Compound B has a...Ch. SRP - Prob. 24PCh. SRP - 25. The Dow process for synthesizing phenol, which...Ch. SRP - Prob. 26PCh. SRP - Prob. 27PCh. SRP - 28. Compound Y shows prominent IR absorption...Ch. SRP - Prob. 29PCh. SRP - Consider this reaction involving peracetic acid:...Ch. SRP - 31. A compound (N) with the molecular formula...Ch. SRP - 32. Compound X is insoluble in aqueous sodium...Ch. SRP - Write the structures of the three products...Ch. SRP - Compound C (C9H11NO) gives a positive Tollens test...Ch. SRP - A compound X (C10H14O) dissolves in aqueous sodium...Ch. SRP - Compound Z (C5H10O) decolorizes bromine. The IR...Ch. SRP - 37. Compound W was isolated from a marine annelid...Ch. SRP - 38. Phenols generally are not changed on treatment...
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