CHEMISTRY+CHEM...HYBRID ED.(LL)>CUSTOM<
9th Edition
ISBN: 9781305020788
Author: John C.Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher: CENGAGE C
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Textbook Question
Chapter L.5, Problem 2Q
What mass and what volume of fuel should have been loaded? (1 lb = 453.6 g)
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Part V. Label ad match the carbons in compounds Jane and Diane
w/ the corresponding peak no.
in the
Spectra (Note: use the given peak no. To label the carbons, other peak
no are intentionally
omitted)
7 4 2
-0.13
-0.12
-0.11
-0.10
-0.08
8
CI
Jane
1
-0.09
5
210
200
190
180
170
160
150
140
130
120
110
100
-8
90
f1 (ppm)
11
8
172.4
172.0
f1 (ppr
HO
CI
NH
Diane
7
3
11
80
80
-80
-R
70
60
60
2
5
-8
50
40
8.
170
160
150
140
130
120
110
100
90
-0
80
70
20
f1 (ppm)
15
30
-20
20
-60
60
-0.07
-0.06
-0.05
-0.04
-0.03
-0.02
-0.01
-0.00
-0.01
10
-0.17
16
15
56
16
-0.16
-0.15
-0.14
-0.13
-0.12
-0.11
-0.10
-0.09
-0.08
-0.07
-0.06
-0.05
-0.04
17.8 17.6 17.4 17.2 17.0
f1 (ppm)
-0.03
-0.02
550
106
40
30
20
20
-0.01
-0.00
F-0.01
10
0
Chapter L Solutions
CHEMISTRY+CHEM...HYBRID ED.(LL)>CUSTOM<
Ch. L.1 - The distance between two carbon atoms in diamond...Ch. L.1 - Prob. 1RCCh. L.1 - Prob. 2RCCh. L.1 - Prob. 3RCCh. L.1 - Prob. 4RCCh. L.1 - 5. A circulated U.S. quarter has a mass of 5.59 g....Ch. L.1 - Prob. 6RCCh. L.1 - Prob. 7RCCh. L.2 - Two students measured the freezing point of a...Ch. L.2 - Prob. 1RC
Ch. L.2 - Two students were assigned to determine the mass...Ch. L.3 - Prob. 1CYUCh. L.3 - Prob. 1RCCh. L.3 - Prob. 2RCCh. L.3 - 3. What is the sum of 10.26 g and 0.063 g?
10.323...Ch. L.3 - Prob. 4RCCh. L.4 - The density of gold is 19,320 kg/m3. What is this...Ch. L.4 - 1. A lake has an area of 2.33 × 107 m2. What is...Ch. L.5 - What is the fuel density in units of kg/L?Ch. L.5 - What mass and what volume of fuel should have been...Ch. L.6 - A particular paint has a density of 0.914 g/cm3....Ch. L.6 - Prob. 1RCCh. L - Many laboratories use 25C as a standard...Ch. L - The temperature on the surface of the Sun is 5.5 ...Ch. L - Prob. 3PSCh. L - Make the following temperature conversions:Ch. L - A marathon distance race covers distance of 42.195...Ch. L - The average lead pencil, new and unused, is 19 cm...Ch. L - A standard U.S. postage stamp is 2.5 cm long and...Ch. L - A compact disc has a diameter of 11.8 cm. What is...Ch. L - A typical laboratory beaker has a volume of 250....Ch. L - Some soft drinks are sold in bottles with a volume...Ch. L - A book has a mass of 2.52 kg. What is this mass in...Ch. L - A new U.S. dime has a mass of 2.265 g. What is its...Ch. L - Ethylene glycol, C2H6O2, is an ingredient of...Ch. L - A piece of silver metal has a mass of 2.365 g. If...Ch. L - Prob. 15PSCh. L - Which occupies a larger volume, 600 g of water...Ch. L - You are on a diet that calls for eating no more...Ch. L - A 2-in. piece of chocolate cake with frosting...Ch. L - Prob. 19PSCh. L - Prob. 20PSCh. L - You and your lab partner are asked to determine...Ch. L - The accepted value of the melting point of...Ch. L - Prob. 23PSCh. L - Prob. 24PSCh. L - Prob. 25PSCh. L - Prob. 26PSCh. L - To determine the average mass of a popcorn kernel,...Ch. L - Use the following graph to answer the following...Ch. L - Use the graph below to answer the following...Ch. L - Solve the following equation for the unknown...Ch. L - Solve the following equation for the unknown...Ch. L - Solve the following equation for the unknown...Ch. L - Prob. 34PSCh. L - Molecular distances are usually given in...Ch. L - The separation between carbon atoms in diamond is...Ch. L - A red blood cell has a diameter of 7.5 m...Ch. L - The platinum-containing cancer drug cisplatin...Ch. L - Prob. 39GQCh. L - You need a cube of aluminum with a mass of 7.6 g....Ch. L - You have a 250.0-mL graduated cylinder containing...Ch. L - Prob. 42GQCh. L - The smallest repeating unit of a crystal of common...Ch. L - Diamond has a density of 3.513 g/cm3. The mass of...Ch. L - Prob. 45GQCh. L - The density of pure water at various temperatures...Ch. L - Prob. 47GQCh. L - The aluminum in a package containing 75 ft2 of...Ch. L - Fluoridation of city water supplies has been...Ch. L - About two centuries ago, Benjamin Franklin showed...Ch. L - Prob. 51GQCh. L - A 26-meter-tall statue of Buddha in Tibet is...Ch. L - At 25 C, the density of water is 0.997 g/cm3,...Ch. L - Suppose your bedroom is 18 ft long and 15 ft wide,...Ch. L - A spherical steel ball has a mass of 3.475 g and a...Ch. L - You are asked to identify an unknown liquid that...Ch. L - You have an irregularly shaped piece of an unknown...Ch. L - There are five hydrocarbon compounds (compounds of...Ch. L - Suppose you have a cylindrical glass tube with a...Ch. L - Copper: Copper has a density of 8.96 g/cm3 An...Ch. L - Copper: (a) Suppose you have a cube of copper...Ch. L - A sample of unknown metal is placed in a graduated...Ch. L - Iron pyrite is often called fool's gold because it...Ch. L - You can analyze for a copper compound in water...Ch. L - Prob. 67IL
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- n Feb 3 A T + 4. (2 pts) Draw the structure of the major component of the Limonene isolated. Explain how you confirmed the structure. 5. (2 pts) Draw the fragment corresponding to the base peak in the Mass spectrum of Limonene. 6. (1 pts) Predict the 1H NMR spectral data of R-Limonene. Proton NMR: 5.3 pon multiplet (H Ringarrow_forwardPart VI. Ca H 10 O is the molecular formula of compound Tom and gives the in the table below. Give a possible structure for compound Tom. 13C Signals summarized C1 C2 C3 C4 C5 C6 C7 13C shift (ppm) 23.5 27.0 33.0 35.8 127 162 205 DEPT-90 + DEPT-135 + +arrow_forward2. Using the following data to calculate the value of AvapH o of water at 298K. AvapH o of water at 373K is 40.7 kJ/mol; molar heat capacity of liquid water at constant pressure is 75.2J mol-1 K-1 and molar heat capacity of water vapor at constant pressure is 33.6 J mol-1 K-1.arrow_forward
- Part VII. Below are the 'HNMR 13 3 C-NMR, COSY 2D- NMR, and HSQC 20-NMR (Similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H13 O. Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum ли 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 1.0 0.9 0.8 f1 (ppm)arrow_forward3. Draw the expanded structural formula, the condensed structural formula, and the skeletal structural formula for 2-pentene. expanded structure: Condensed structure: Skeletal formula: 4. Draw the expanded structural formula, the condensed structural formula, and the skeletal structural formula for 2-methyl-3-heptene. expanded structure: Condensed structure: Skeletal formula: following structurearrow_forwardPart IV. Propose a plausible Structure w/ the following descriptions: a) A 5-carbon hydrocarbon w/ a single peak in its proton decoupled the DEPT-135 Spectrum shows a negative peak C-NMR spectrum where b) what cyclohexane dione isomer gives the largest no. Of 13C NMR signals? c) C5H120 (5-carbon alcohol) w/ most deshielded carbon absent in any of its DEPT Spectivaarrow_forward
- 13C NMR is good for: a) determining the molecular weight of the compound b) identifying certain functional groups. c) determining the carbon skeleton, for example methyl vs ethyl vs propyl groups d) determining how many different kinds of carbon are in the moleculearrow_forward6 D 2. (1 pt) Limonene can be isolated by performing steam distillation of orange peel. Could you have performed this experiment using hexane instead of water? Explain. 3. (2 pts) Using GCMS results, analyze and discuss the purity of the Limonene obtained from the steam distillation of orange peel.arrow_forwardPart III. Arrange the following carbons (in blue) in order of increasing chemical shift. HO B NH 2 A CIarrow_forward
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