CHEM: STRUC & PROP (LL) >CUST PKG<
2nd Edition
ISBN: 9780137390977
Author: Tro
Publisher: PEARSON C
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Chapter E, Problem 81E
A solid gold cylinder sits on a weight-sensitive alarm. A thief uses a can of sand to replace the solid gold cylinder. The can of sand and the gold cylinder have exactly the same dimensions (length = 22 cm and radius = 3.8 cm).
a. Calculate the mass of the gold cylinder and can of sand (ignore the mass of the can itself). (density of gold = 19.3 g/cm3, density of sand = 3.00 g/cm3)
b. Did the thief set off the alarm? Explain.
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81. a. Propose a mechanism for the following reaction:
OH
CH2=CHCHC=N
b. What is the product of the following reaction?
HO
H₂O
N=CCH2CH2CH
OH
HO
CH3CCH=CH2
H₂O
C=N
82. Unlike a phosphonium ylide that reacts with an aldehyde or a ketone to form an alkene a sulfonium ulia
For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check
the appropriate box.
Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below.
Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions
- just focus on the first stable product you expect to form in solution.
?
NH2
MgBr
Will the first product that forms in this reaction
create a new CC bond?
○ Yes
○ No
MgBr
?
Will the first product that forms in this reaction
create a new CC bond?
O Yes
O No
Click and drag to start drawing a
structure.
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Predicting
As the lead product manager at OrganometALEKS Industries, you are trying to decide if the following reaction will make a molecule
with a new C - C bond as its major product:
H₂N
O
H
1.
?
2. H3O+
If this reaction will work, draw the major organic product or products you would expect in the drawing area below. If there's more
than one major product, you can draw them in any arrangement you like. Be sure you use wedge and dash bonds if necessary, for
example to distinguish between major products with different stereochemistry.
0
If the major products of this reaction won't have a new CC bond, just check the box under the drawing area and leave it blank.
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Explanation
Check
Click and drag to start drawing a
structure.
Chapter E Solutions
CHEM: STRUC & PROP (LL) >CUST PKG<
Ch. E - What are the standard SI base units of length,...Ch. E - What are the three common temperature scales? Does...Ch. E - What are prefix multipliers? List some examples.Ch. E - What is a derived unit? List an example.Ch. E - Explain the relationship between the reliability...Ch. E - What is the significance of the number of digits...Ch. E - Explain the difference between precision and...Ch. E - Prob. 8ECh. E - When multiplying or dividing measured quantities,...Ch. E - When adding or subtracting measured quantities,...
Ch. E - Explain the difference between density and mass.Ch. E - Explain the difference between intensive and...Ch. E - Prob. 13ECh. E - Prob. 14ECh. E - Prob. 15ECh. E - Prob. 16ECh. E - What is dimensional analysis?Ch. E - How should units be treated in calculations?Ch. E - Convert each temperature. a. 32 °F to °C...Ch. E - Convert each temperature. a. 212 °F to °C...Ch. E - The coldest temperature ever measured in the...Ch. E - Prob. 22ECh. E - Use the prefix multipliers to express each...Ch. E - Use prefix multipliers to express each measurement...Ch. E - Use scientific notation to express each quantity...Ch. E - Use scientific notation to express each quantity...Ch. E - Complete the table.Ch. E - Complete the table.Ch. E - Express the quantity 254,998 m in each unit. a. km...Ch. E - Express the quantity 556.2 × 10-12 s in each unit....Ch. E - How many 1-cm squares does it take to construct a...Ch. E - How many 1-cm cubes does it take to construct a...Ch. 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E - The average U.S. farm occupies 435 acres. (1 acre...Ch. E - Total U.S. farmland occupies 954 million acres....Ch. E - An acetaminophen suspension for infants contains...Ch. E - An ibuprofen suspension for infants contains 100...Ch. E - Convert between energy units. a. 534 kWh to J b....Ch. E - Prob. 76ECh. E - Suppose that a person eats 2387 Calories per day....Ch. E - A particular frost-free refrigerator uses about...Ch. E - Prob. 79ECh. E - Prob. 80ECh. E - A solid gold cylinder sits on a weight-sensitive...Ch. E - The proton has a radius of approximately 1.0 ×...Ch. E - The density of titanium is 4.51 g/cm3. What is the...Ch. E - The density of iron is 7.86 g/cm3. What is its...Ch. E - A steel cylinder has a length of 2.16 in, a radius...Ch. E - A solid aluminum sphere has a mass of 85 g. Use...Ch. E - Prob. 87ECh. E - Prob. 88ECh. E - The Toyota Prius, a hybrid electric vehicle, has a...Ch. E - The Honda Insight, a hybrid electric vehicle, has...Ch. E - The single proton that forms the nucleus of the...Ch. E - A sample of gaseous neon atoms at atmospheric...Ch. E - Prob. 93ECh. E - The world’s record in the 100-m dash is 9.58 s,...Ch. E - Table salt contains 39.33 g of sodium per 100 g of...Ch. E - Prob. 96ECh. E - A length of #8 copper wire (radius = 1.63 mm) has...Ch. E - Rolls of aluminum foil are 304 mm wide and 0.016...Ch. E - Liquid nitrogen has a density of 0.808 g/L and...Ch. E - Mercury is often used in thermometers. The mercury...Ch. E - Prob. 101ECh. E - In 1999, scientists discovered a new class of...Ch. E - Prob. 103ECh. E - Nanotechnology, the field of building ultrasmall...Ch. E - Prob. 105ECh. E - A box contains a mixture of small copper spheres...Ch. E - A cube has an edge length of 7 cm. If it is...Ch. E - Prob. 108ECh. E - For each box, examine the blocks attached to the...Ch. E - Look up the measurement of the approximate...Ch. E - Prob. 111ECh. E - One inch is equal to 2.54 cm. Draw a line that is...Ch. 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