MASTERING CHEMISTY NVCC ACCESS CODE
1st Edition
ISBN: 9780136444459
Author: Tro
Publisher: PEARSON
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Chapter E, Problem 5E
Explain the relationship between the reliability of a measurement and the instrument used to make the measurement.
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How many signals would you expect to see in the
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'C NMR spectrum for the following compound?
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Consider the "C NMR spectrum below.
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The spectrum belongs to which one of the following constitutional isomers of the compound C,H12? Select the single best answer.
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The structure of compound 1,3,5-trimethylbenzene (mesitylene) is given below.
How many signals would you expect to find in the 'H NMR spectrum of 1,3,5-trimethylbenzene (mesitylene)?
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Chapter E Solutions
MASTERING CHEMISTY NVCC ACCESS CODE
Ch. E - What are the standard SI base units of length,...Ch. E - What are the three common temperature scales? Does...Ch. E - What are prefix multipliers? List some examples.Ch. E - What is a derived unit? List an example.Ch. E - Explain the relationship between the reliability...Ch. E - What is the significance of the number of digits...Ch. E - Explain the difference between precision and...Ch. E - Prob. 8ECh. E - When multiplying or dividing measured quantities,...Ch. E - When adding or subtracting measured quantities,...
Ch. E - Explain the difference between density and mass.Ch. E - Explain the difference between intensive and...Ch. E - Prob. 13ECh. E - Prob. 14ECh. E - Prob. 15ECh. E - Prob. 16ECh. E - What is dimensional analysis?Ch. E - How should units be treated in calculations?Ch. E - Convert each temperature. a. 32 °F to °C...Ch. E - Convert each temperature. a. 212 °F to °C...Ch. E - The coldest temperature ever measured in the...Ch. E - Prob. 22ECh. E - Use the prefix multipliers to express each...Ch. E - Use prefix multipliers to express each measurement...Ch. E - Use scientific notation to express each quantity...Ch. E - Use scientific notation to express each quantity...Ch. E - Complete the table.Ch. E - Complete the table.Ch. E - Express the quantity 254,998 m in each unit. a. km...Ch. E - Express the quantity 556.2 × 10-12 s in each unit....Ch. E - How many 1-cm squares does it take to construct a...Ch. E - How many 1-cm cubes does it take to construct a...Ch. E - Convert 15.0 L to each unit. a.mL b. cm3 c. gal d....Ch. E - Convert 4.58 x 103 cm3 to each unit. a. L b. mL c....Ch. E - A ruler used to measure a penny has markings every...Ch. E - A scale used to weigh produce at a market has...Ch. E - Read each measurement to the correct number of...Ch. E - Read each measurement to the correct number of...Ch. E - For each number, underline the zeroes that are...Ch. E - For each number, underline the zeroes that are...Ch. E - How many significant figures are in each number?...Ch. E - How many significant figures are in each number?...Ch. E - Which numbers are exact (and therefore have an...Ch. E - Indicate the number of significant figures in each...Ch. E - Round each number to four significant figures. a....Ch. E - Round each number to three significant figures. a....Ch. E - Calculate to the correct number of significant...Ch. E - Calculate to the correct number of significant...Ch. E - Calculate to the correct number of significant...Ch. E - Calculate to the correct number of significant...Ch. E - Calculate to the correct number of significant...Ch. E - Calculate to the correct number of significant...Ch. E - A new penny has a mass of 2.49 g and a volume of...Ch. E - A titanium bicycle frame displaces 0.314 L of...Ch. E - Glycerol is a syrupy liquid used in cosmetics and...Ch. E - An allegedly gold nugget is tested to determine...Ch. E - Ethylene glycol (antifreeze) has a density of 1.11...Ch. E - Prob. 58ECh. E - A small airplane takes on 245 L of fuel, If the...Ch. E - Human fat has a density of 0.918 g/cm3. How much...Ch. E - Perform each unit conversion. a. 27.8 L to cm3 b....Ch. E - Prob. 62ECh. E - Prob. 63ECh. E - Prob. 64ECh. E - A runner wants to run 10.0 km. She knows that her...Ch. E - Prob. 66ECh. E - A European automobile has a gas mileage of 17...Ch. E - A gas can holds 5.0 gallons of gasoline. Express...Ch. E - A house has an area of 195 m2. What is its area...Ch. E - Prob. 70ECh. E - The average U.S. farm occupies 435 acres. (1 acre...Ch. E - Total U.S. farmland occupies 954 million acres....Ch. E - An acetaminophen suspension for infants contains...Ch. E - An ibuprofen suspension for infants contains 100...Ch. E - Convert between energy units. a. 534 kWh to J b....Ch. E - Prob. 76ECh. E - Suppose that a person eats 2387 Calories per day....Ch. E - A particular frost-free refrigerator uses about...Ch. E - Prob. 79ECh. E - Prob. 80ECh. E - A solid gold cylinder sits on a weight-sensitive...Ch. E - The proton has a radius of approximately 1.0 ×...Ch. E - The density of titanium is 4.51 g/cm3. What is the...Ch. E - The density of iron is 7.86 g/cm3. What is its...Ch. E - A steel cylinder has a length of 2.16 in, a radius...Ch. E - A solid aluminum sphere has a mass of 85 g. Use...Ch. E - Prob. 87ECh. E - Prob. 88ECh. E - The Toyota Prius, a hybrid electric vehicle, has a...Ch. E - The Honda Insight, a hybrid electric vehicle, has...Ch. E - The single proton that forms the nucleus of the...Ch. E - A sample of gaseous neon atoms at atmospheric...Ch. E - Prob. 93ECh. E - The world’s record in the 100-m dash is 9.58 s,...Ch. E - Table salt contains 39.33 g of sodium per 100 g of...Ch. E - Prob. 96ECh. E - A length of #8 copper wire (radius = 1.63 mm) has...Ch. E - Rolls of aluminum foil are 304 mm wide and 0.016...Ch. E - Liquid nitrogen has a density of 0.808 g/L and...Ch. E - Mercury is often used in thermometers. The mercury...Ch. E - Prob. 101ECh. E - In 1999, scientists discovered a new class of...Ch. E - Prob. 103ECh. E - Nanotechnology, the field of building ultrasmall...Ch. E - Prob. 105ECh. E - A box contains a mixture of small copper spheres...Ch. E - A cube has an edge length of 7 cm. If it is...Ch. E - Prob. 108ECh. E - For each box, examine the blocks attached to the...Ch. E - Look up the measurement of the approximate...Ch. E - Prob. 111ECh. E - One inch is equal to 2.54 cm. Draw a line that is...Ch. E - Convert the height of each member in your group...Ch. E - Prob. 114ECh. E - Convert 85.0 °F to k. 358 k 181.1 k 302.6 k 29.4 kCh. E - Express the quantity 33.2 × 10-4 m in mm. 0.332 mm...Ch. E - How many significant figures are there in the...Ch. E - Perform the calculation to the correct number of...Ch. E - Perform the calculation to the correct number of...Ch. E - What is the mass of a 1 .75-L sample of a liquid...Ch. E - Convert 1,285 cm2to m2. 12.85 m2 0.1285 m2 1.285 ×...Ch. E - Prob. 8SAQCh. E - A solid metal sphere has a radius of 3.53 cm and a...Ch. E - A German automobile’s gas mileage is 22km/L....Ch. E - A wooden block has a volume of 18.5 in3. Express...
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- 1 How many signals do you expect in the 'H NMR spectrum for this molecule? CI CI Cl Write the answer in the table below. Also, in each of the drawing areas below is a copy of the molecule, with H atoms shown. In each copy, one of the H atoms is highlighted red. Highlight in red all other H atoms that would contribute to the same signal as the H already highlighted red. Note for advanced students: Remember, a multiplet is considered one signal in the 'H NMR spectrum. 1 Number of signals in the 'H NMR spectrum. ☐ For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to the same signal as the H atom already highlighted red. If no other H atoms will contribute, check the box at right. No additional H atoms to highlight in top molecule For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute to the same signal as the H atom already highlighted red. If no other H atoms will contribute, check the box at…arrow_forwardwrtie the balanced equation and find the E° when the following half- reactions are combined Zn2+(aq) + 2e---> Zn(s) E°= -0.763V Ag+(aq) + e---> Ag (s) E°=+0.799Varrow_forwardConsider this molecule: How many H atoms are in this molecule? How many different signals could be found in its 'H NMR spectrum? Note: A multiplet is considered one signal. ☐arrow_forward
- Study this 'H NMR spectrum, and then answer the questions about it in the table below. Check 1.0- 0.5- 0.0 10.0 9.0 8.0 7.0 6.0 5.0 4.0 3.0 2.0 1.0 0.0 What unit symbol should be written on the horizontal axis? What is the chemical shift & of the doublet? If there is no doublet, just check the box instead. Give your answer to 2 significant digits. What is the chemical shift of the signal immediately upfield of the doublet? If there is no doublet, or no signal upfield of it, check the box instead. What is the chemical shift & of the least deshielded proton? If you can't tell without more information, check the box instead. 血 8 = ☐ There is no doublet. 8 = ☐ No such signal. 8 = 0 Need more information.arrow_forwardhow many moles of H2O2 are required to react with 11g of N2H4 according to the following reaction? (atomic weights: N=14.01, H=1.008, O= 16.00) 7H2O2 + N2H4 -> 2HNO3 + 8H20arrow_forwardcalculate the number of moles of H2 produced from 0.78 moles of Ga and 1.92 moles HCL? 2Ga+6HCL->2GaCl3+3H2arrow_forward
- an adult human breathes 0.50L of air at 1 atm with each breath. If a 50L air tank at 200 atm is available, how man y breaths will the tank providearrow_forwardWhat are the advantages and/or disadvantages of using the MOHR titration method & AOEC method?arrow_forwardAre there any alternative methods better than the MOHR titration to quantitatively determine salt in a sample?arrow_forward
- hybridization of nitrogen of complex moleculesarrow_forwardUsing reaction free energy to predict equilibrium composition Consider the following equilibrium: 2NO2 (g) = N2O4(g) AGº = -5.4 kJ Now suppose a reaction vessel is filled with 4.53 atm of dinitrogen tetroxide (N2O4) at 279. °C. Answer the following questions about this system: Under these conditions, will the pressure of N2O4 tend to rise or fall? Is it possible to reverse this tendency by adding NO2? In other words, if you said the pressure of N2O4 will tend to rise, can that be changed to a tendency to fall by adding NO2? Similarly, if you said the pressure of N2O4 will tend to fall, can that be changed to a tendency to '2' rise by adding NO2? If you said the tendency can be reversed in the second question, calculate the minimum pressure of NO 2 needed to reverse it. Round your answer to 2 significant digits. 00 rise ☐ x10 fall yes no ☐ atm G Ar 1arrow_forwardWhy do we analyse salt?arrow_forward
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