Mastering Chemistry with Pearson eText -- Standalone Access Card -- for Chemistry: Structure and Properties (2nd Edition)
2nd Edition
ISBN: 9780134566290
Author: Nivaldo J. Tro
Publisher: PEARSON
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Question
Chapter E, Problem 101E
Interpretation Introduction
To determine:
The percentage of carbon’s occupied volume
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Students have asked these similar questions
On the next page is an LC separation of the parabens found in baby wash. Parabens are
suspected in a link to breast cancer therefore an accurate way to quantitate them is desired.
a. In the chromatogram, estimate k' for ethyl paraben. Clearly indicate what values you used for
all the terms in your calculation.
b. Is this a "good" value for a capacity factor? Explain.
c. What is the resolution between n-Propyl paraben and n-Butyl paraben? Again, indicate clearly
what values you used in your calculation.
MAU
| Methyl paraben
40
20
0
-2
Ethyl paraben n-Propyl paraben
n-Butyl paraben
App ID 22925
6
8
min
d. In Figure 4, each stationary phase shows some negative correlation between plate count
and retention factor. In other words, as k' increases, N decreases. Explain this relationship
between k' and N.
Plate Count (N)
4000
3500
2500
2000
1500
1000
Figure 4. Column efficiency (N) vs retention factor (k') for 22
nonionizable solutes on FMS (red), PGC (black), and COZ (green). 3000
Eluent compositions (acetonitrile/water, A/W) were adjusted to obtain
k' less than 15, which was achieved for most solutes as follows: FMS
(30/70 A/W), PGC (60/40), COZ (80/20). Slightly different
compositions were used for the most highly retained solutes. All
columns were 50 mm × 4.6 mm id and packed with 5 um particles,
except for COZ, which was packed with 3 um particles. All other
chromatographic conditions were constant: column length 5 cm,
column j.§. 4.6 mm, flow rate 2 mL/min, column temperature 40 °C,
and injection volume 0.5 μL
Log(k'x/K'ethylbenzene)
FMS
1.5
1.0
0.5
0.0
ཐྭ ཋ ཤྩ བྷྲ ;
500
0
5
10…
f. Predict how the van Deemter curve in Figure 7
would change if the temperature were raised
from 40 °C to 55 °C.
Figure 7. van Desmter curves in reduced coordinates for four
nitroalkane homologues (nitropropane, black; nitrobutane, red;
nitropentane, blue; and nitrohexane, green) separated on the FMS
phase. Chromatographic conditions: column dimensions 50 mm × 4.6
mm id, eluent 30/70 ACN/water, flow rates 0.2-5.0 mL/min, injection
volume 0.5 and column temperature 40 °C. No corrections to the
plate heights have been made to account for extracolumn dispersion.
Reduced Plate Height (h)
°
20
40
60
Reduced Velocity (v)
8. (2) A water sample is analyzed for traces of benzene using headspace analysis. The sample and
standard are spiked with a fixed amount of toluene as an internal standard. The following data are
obtained:
Ppb benzene
Peak area benzene
Peak area toluene
10.0
252
376
Sample
533
368
What is the concentration of benzene in the sample?
Chapter E Solutions
Mastering Chemistry with Pearson eText -- Standalone Access Card -- for Chemistry: Structure and Properties (2nd Edition)
Ch. E - What are the standard SI base units of length,...Ch. E - What are the three common temperature scales? Does...Ch. E - What are prefix multipliers? List some examples.Ch. E - What is a derived unit? List an example.Ch. E - Explain the relationship between the reliability...Ch. E - What is the significance of the number of digits...Ch. E - Explain the difference between precision and...Ch. E - Prob. 8ECh. E - When multiplying or dividing measured quantities,...Ch. E - When adding or subtracting measured quantities,...
Ch. E - Explain the difference between density and mass.Ch. E - Explain the difference between intensive and...Ch. E - Prob. 13ECh. E - Prob. 14ECh. E - Prob. 15ECh. E - Prob. 16ECh. E - What is dimensional analysis?Ch. E - How should units be treated in calculations?Ch. E - Convert each temperature. a. 32 °F to °C...Ch. E - Convert each temperature. a. 212 °F to °C...Ch. E - The coldest temperature ever measured in the...Ch. E - Prob. 22ECh. E - Use the prefix multipliers to express each...Ch. E - Use prefix multipliers to express each measurement...Ch. E - Use scientific notation to express each quantity...Ch. E - Use scientific notation to express each quantity...Ch. E - Complete the table.Ch. E - Complete the table.Ch. E - Express the quantity 254,998 m in each unit. a. km...Ch. E - Express the quantity 556.2 × 10-12 s in each unit....Ch. E - How many 1-cm squares does it take to construct a...Ch. E - How many 1-cm cubes does it take to construct a...Ch. E - Convert 15.0 L to each unit. a.mL b. cm3 c. gal d....Ch. E - Convert 4.58 x 103 cm3 to each unit. a. L b. mL c....Ch. E - A ruler used to measure a penny has markings every...Ch. E - A scale used to weigh produce at a market has...Ch. E - Read each measurement to the correct number of...Ch. E - Read each measurement to the correct number of...Ch. E - For each number, underline the zeroes that are...Ch. E - For each number, underline the zeroes that are...Ch. E - How many significant figures are in each number?...Ch. E - How many significant figures are in each number?...Ch. E - Which numbers are exact (and therefore have an...Ch. E - Indicate the number of significant figures in each...Ch. E - Round each number to four significant figures. a....Ch. E - Round each number to three significant figures. a....Ch. E - Calculate to the correct number of significant...Ch. E - Calculate to the correct number of significant...Ch. E - Calculate to the correct number of significant...Ch. E - Calculate to the correct number of significant...Ch. E - Calculate to the correct number of significant...Ch. E - Calculate to the correct number of significant...Ch. E - A new penny has a mass of 2.49 g and a volume of...Ch. E - A titanium bicycle frame displaces 0.314 L of...Ch. E - Glycerol is a syrupy liquid used in cosmetics and...Ch. E - An allegedly gold nugget is tested to determine...Ch. E - Ethylene glycol (antifreeze) has a density of 1.11...Ch. E - Prob. 58ECh. E - A small airplane takes on 245 L of fuel, If the...Ch. E - Human fat has a density of 0.918 g/cm3. How much...Ch. E - Perform each unit conversion. a. 27.8 L to cm3 b....Ch. E - Prob. 62ECh. E - Prob. 63ECh. E - Prob. 64ECh. E - A runner wants to run 10.0 km. She knows that her...Ch. E - Prob. 66ECh. E - A European automobile has a gas mileage of 17...Ch. E - A gas can holds 5.0 gallons of gasoline. Express...Ch. E - A house has an area of 195 m2. What is its area...Ch. E - Prob. 70ECh. E - The average U.S. farm occupies 435 acres. (1 acre...Ch. E - Total U.S. farmland occupies 954 million acres....Ch. E - An acetaminophen suspension for infants contains...Ch. E - An ibuprofen suspension for infants contains 100...Ch. E - Convert between energy units. a. 534 kWh to J b....Ch. E - Prob. 76ECh. E - Suppose that a person eats 2387 Calories per day....Ch. E - A particular frost-free refrigerator uses about...Ch. E - Prob. 79ECh. E - Prob. 80ECh. E - A solid gold cylinder sits on a weight-sensitive...Ch. E - The proton has a radius of approximately 1.0 ×...Ch. E - The density of titanium is 4.51 g/cm3. What is the...Ch. E - The density of iron is 7.86 g/cm3. What is its...Ch. E - A steel cylinder has a length of 2.16 in, a radius...Ch. E - A solid aluminum sphere has a mass of 85 g. Use...Ch. E - Prob. 87ECh. E - Prob. 88ECh. E - The Toyota Prius, a hybrid electric vehicle, has a...Ch. E - The Honda Insight, a hybrid electric vehicle, has...Ch. E - The single proton that forms the nucleus of the...Ch. E - A sample of gaseous neon atoms at atmospheric...Ch. E - Prob. 93ECh. E - The world’s record in the 100-m dash is 9.58 s,...Ch. E - Table salt contains 39.33 g of sodium per 100 g of...Ch. E - Prob. 96ECh. E - A length of #8 copper wire (radius = 1.63 mm) has...Ch. E - Rolls of aluminum foil are 304 mm wide and 0.016...Ch. E - Liquid nitrogen has a density of 0.808 g/L and...Ch. E - Mercury is often used in thermometers. The mercury...Ch. E - Prob. 101ECh. E - In 1999, scientists discovered a new class of...Ch. E - Prob. 103ECh. E - Nanotechnology, the field of building ultrasmall...Ch. E - Prob. 105ECh. E - A box contains a mixture of small copper spheres...Ch. E - A cube has an edge length of 7 cm. If it is...Ch. E - Prob. 108ECh. E - For each box, examine the blocks attached to the...Ch. E - Look up the measurement of the approximate...Ch. E - Prob. 111ECh. E - One inch is equal to 2.54 cm. Draw a line that is...Ch. E - Convert the height of each member in your group...Ch. E - Prob. 114ECh. E - Convert 85.0 °F to k. 358 k 181.1 k 302.6 k 29.4 kCh. E - Express the quantity 33.2 × 10-4 m in mm. 0.332 mm...Ch. E - How many significant figures are there in the...Ch. E - Perform the calculation to the correct number of...Ch. E - Perform the calculation to the correct number of...Ch. E - What is the mass of a 1 .75-L sample of a liquid...Ch. E - Convert 1,285 cm2to m2. 12.85 m2 0.1285 m2 1.285 ×...Ch. E - Prob. 8SAQCh. E - A solid metal sphere has a radius of 3.53 cm and a...Ch. E - A German automobile’s gas mileage is 22km/L....Ch. E - A wooden block has a volume of 18.5 in3. Express...
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