ORGANIC CHEMISTRY-ETEXT REG ACCESS
12th Edition
ISBN: 9781119308362
Author: Solomons
Publisher: WILEY
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Chapter D, Problem 6PP
Interpretation Introduction
Interpretation:
The products of the given electrocyclic reactions are to be determined.
Concept introduction:
▸ Electrocyclic reactions are initiated by heat or light and are stereospecific in nature.
▸ The thermal electrocyclic reaction having
▸ The photochemical electrocyclic reaction having
▸ The photochemical electrocyclic reaction having
▸ The thermal electrocyclic reaction having
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Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an
organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the
compound. Find the structure. Show complete solutions.
Predicted 1H NMR Spectrum
4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1
f1 (ppm)
Predicted 13C NMR Spectrum
100
f1 (ppm)
30
220 210 200 190 180
170
160 150 140 130 120
110
90
80
70
-26
60
50
40
46
30
20
115
10
1.0 0.9 0.8
0
-10
Q: Arrange BCC and Fec
metals, in sequence from the
Fable (Dr. R's slides) and
Calculate Volume and Density.
Aa
BCC
V
52 5
SFCC
None
Chapter D Solutions
ORGANIC CHEMISTRY-ETEXT REG ACCESS
Ch. D - Prob. 1PPCh. D - Practice Problem D.2 (a) Show the orbitals...Ch. D - Prob. 3PPCh. D - Prob. 4PPCh. D - Prob. 5PPCh. D - Prob. 6PPCh. D - Practice Problem D.7 Can you suggest a...Ch. D - Practice Problem D.8 When compound A is heated,...Ch. D - Prob. 9PPCh. D - Practice Problem D.10 What reactant could lead to...
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