EBK ORGANIC CHEMISTRY
12th Edition
ISBN: 9781119233664
Author: Snyder
Publisher: VST
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Chapter A, Problem 3PP
Practice Problem A.3
How many signals (not counting the solvent) would you expect in the
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dow many signals 'H NMR be expected in the following molecules? (choose 4 only)
1) 5-methyl-3-hexanone
2) acetone
3) 4-methylacetophenone 4)1-propanol 5) cinammic acid
Morld)
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Chapter A Solutions
EBK ORGANIC CHEMISTRY
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- Please correct answer and don't use hand ratingarrow_forward+ Choose the molecule that is most likely to produce a spectrum with these IR frequencies: v = 3370, 3292, 2959, 2927, 2873, 1613 (small and broad), 1127 cm¹¹ A) pentanamide B) 1-pentanamine C) pentanal D) 2-pentanone E) 2-pentenearrow_forwardProblem A.4 Propose a molecular formula for cedrol, an alcohol found in cedar oil. Cedrol has three degrees of unsaturation and a molecular ion in its mass spectrum at m/z = 222.arrow_forward
- Answer E and Farrow_forwardWhat is the m/z of the signal produced when the molecule below undergoes a McLafferty rearrangement in a mass spectrum? Answer:arrow_forwardCan you assist me in identifying what I am doing wrong in this picture? Original Question: How many signals would be observed in proton-decoupled 13C-NMR spectrum of each of the isomeric C6H10 hydrocarbons below?arrow_forward
- Solve plsarrow_forwardH NMR question: For propene and for cis-2-butene, find # signals, chemical shift ranges, integration, splittingarrow_forwardWhich of the following will produce an even M and (M+2) peaks of equal intensity and a base peak of M-18? ⒸC4H7BrO2 © C5H12CIN ⒸC5H11CIO ⒸC5H11BrO C4H7CIO2 ⒸC5H12BrNarrow_forward
- Which base peak is expected in the mass spectrum of 2,2,3-trimethylbutane? Question 14 options: M-15 peak M-57 peak M-29 peak M-43 peak M-18 peakarrow_forwardProblem A.8 The mass spectrum of 2,3-dimethylpentane also shows peaks at m/z = 57 and 43. Propose possible structures for the ions that give rise to these peaks.arrow_forwardQuestion 1 Correct Answer-Label the spectra and compound OH 3 1HNMR (ppm): 4.77 (1H, br s); 3.50 (1H, quintet); 1.55 (2H, quintet); 1.40 (1H, m); 1.11 (3H, d); 0.99 (3H, t); 0.88 (3H, d) Explanation for Excellent - Draw compounds that match the other spectra. They all have the same molecular formula as above 2 IHNMR (ppm): 4.7 (1H, br s); 3.62 (2H, t); 1.58 (2H, quintet); 1.43 (2H, quintet); 1.37 (2H, quintet); 1.35 (2H, sextet); 0.88 (3H, t) IHNMR (ppm): 3.46 (2H, q); 3.35 (2H, t); 1.50 (2H, quintet); 1.46 (2H, sextet); 1.05 (3H, 1); 0.96 (3H, t) PPM 1HNMR (ppm): 3.65 (2H, m); 1.13 (12H, d)arrow_forward
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