KLEIN'S ORGANIC CHEMISTRY
KLEIN'S ORGANIC CHEMISTRY
3rd Edition
ISBN: 9781119423126
Author: Klein
Publisher: WILEY
Question
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Chapter 9.5, Problem 11CC

 (a)

Interpretation Introduction

Interpretation:

The reagents used to accomplish the given transformation should be draw and identified.

Concept Introduction:

Platinum reduction reaction: The alkenes can be reduced to alkanes with H2 in the presence of metal catalyst (Pt). The two new C-H σ bonds are formed simultaneously from H atoms absorbed into the metal surface. Further this type of reaction stereospecific giving only the cis (syn) addition product.

Linder’s catalyst (Pt/H2): The alkyne reduced to alkenes to give the cis (Z) alkene.

Metal and ammonia reaction: The conjugated alkynes and benzenes in the presence of sodium metal in liquid ammonia and alkyne produced a non-conjugated diene system. The alkyne involves sodium (Na)/NH3 . This end up reducing to alkyne to give the trans (E) alkene.

(b)

Interpretation Introduction

Interpretation:

The reagents used to accomplish the given transformation should be draw and identified.

Concept Introduction:

Platinum reduction reaction: The alkenes can be reduced to alkanes with H2 in the presence of metal catalyst (Pt). The two new C-H σ bonds are formed simultaneously from H atoms absorbed into the metal surface. Further this type of reaction stereospecific giving only the cis (syn) addition product.

Linder’s catalyst (Pt/H2): The alkyne reduced to alkenes to give the cis (Z) alkene.

Metal and ammonia reaction: The conjugated alkynes and benzenes in the presence of sodium metal in liquid ammonia and alkyne produced a non-conjugated diene system. The alkyne involves sodium (Na)/NH3 . This end up reducing to alkyne to give the trans (E) alkene.

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KLEIN'S ORGANIC CHEMISTRY

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