ORGANIC CHEMISTRY
ORGANIC CHEMISTRY
9th Edition
ISBN: 9780134645704
Author: WADE AND SIMEK
Publisher: PEARSON
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Chapter 9.10B, Problem 9.25P

(a)

Interpretation Introduction

To determine: The synthesis of 3methylnon4yn3ol, using acetylene and compounds containing no more than four carbon atoms as starting material.

Interpretation: The synthesis of 3methylnon4yn3ol, using acetylene and compounds containing no more than four carbon atoms as starting material is to be developed.

Concept introduction: The synthesis of compound relies upon the type of reactants and reagents that are used during the reactions. The mechanism in alkenes and alkynes proceed through the breaking of double or triple bonds because pi bonds are less stable as compared to sigma bonds.

The Stability of a product is the major factor that is responsible for the high yield of the product. The reagents perform numerous functions in reactions like proton abstraction, oxidation, reduction, catalysis, and dehydrogenation.

(b)

Interpretation Introduction

To determine: The synthesis of cis1ethyl2methylcyclopropane, using acetylene and compounds containing no more than four carbon atoms as starting material.

Interpretation: The synthesis of cis1ethyl2methylcyclopropane, using acetylene and compounds containing no more than four carbon atoms as starting material is to be developed.

Concept introduction: The synthesis of compound relies upon the type of reactants and reagents that are used during the reactions. The mechanism in alkene and alkynes proceed through the breaking of double or triple bonds because pi bonds are less stable.

The Stability of a product is the major factor that is responsible for the high yield of the product. The reagents perform numerous functions in reactions like proton abstraction, oxidation, reduction, catalysis, and dehydrogenation.

(c)

Interpretation Introduction

To determine: The synthesis of given compound, using acetylene and compounds containing no more than four carbon atoms as starting material.

Interpretation: The synthesis of given compound, using acetylene and compounds containing no more than four carbon atoms as starting material is to be developed.

Concept introduction: The synthesis of compound relies upon the type of reactants and reagents that are used during the reactions. The mechanism in alkene and alkynes proceed through the breaking of double or triple bonds because pi bonds are less stable.

The Stability of a product is the major factor that is responsible for the high yield of the product. The reagents perform numerous functions in reactions like proton abstraction, oxidation, reduction, catalysis, and dehydrogenation.

(d)

Interpretation Introduction

To determine: The synthesis of mesohexane3,4diol, using acetylene and compounds containing no more than four carbon atoms as starting material.

Interpretation: The synthesis of mesohexane3,4diol, using acetylene and compounds containing no more than four carbon atoms as starting material is to be developed.

Concept introduction: The synthesis of compound relies upon the type of reactants and reagents that are used during the reactions. The mechanism in alkene and alkynes proceed through the breaking of double or triple bonds because pi bonds are less stable.

The Stability of a product is the major factor that is responsible for the high yield of the product. The reagents perform numerous functions in reactions like proton abstraction, oxidation, reduction, catalysis, and dehydrogenation.

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5. Propose a Synthesis for the molecule below. You may use any starting materials containing 6 carbons or less (reagents that aren't incorporated into the final molecule such as PhзP do not count towards this total, and the starting material can have whatever non-carbon functional groups you want), and any of the reactions you have learned so far in organic chemistry I, II, and III. Your final answer should show each step separately, with intermediates and conditions clearly drawn. H3C CH3
State the name and condensed formula of isooxazole obtained by reacting acetylacetone and hydroxylamine.
State the name and condensed formula of the isothiazole obtained by reacting acetylacetone and thiosemicarbazide.

Chapter 9 Solutions

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