ACHIEVE/CHEMICAL PRINCIPLES ACCESS 1TERM
7th Edition
ISBN: 9781319399849
Author: ATKINS
Publisher: MAC HIGHER
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Chapter 9, Problem 9C.3AST
(a)
Interpretation Introduction
Interpretation:
The type of isomer represented by the pair [Cu(NH3)4] [Pt(Cl4)] and [Pt(NH3)4] [Cu(Cl4)] has to be given.
Concept Introduction:
Isomers:
The compounds with same molecular formula but differ in the arrangement of the atom are said to be isomers.
Coordination Isomers:
Coordination isomerism arises in compounds containing complex anionic and cationic parts. Hence, there are two complex compounds bound together, one with a negative charge and the other with a positive charge. In coordination isomers, the anion and cation complexes of a coordination compound exchange one or more ligands.
(b)
Interpretation Introduction
Interpretation:
The type of isomer represented by the pair [Cr(NH3)4(OH)2]Br & [Cr Br(NH3)4(OH)](OH) has to be given
Concept Introduction:
Ionization Isomers:
Ionization isomers occur when a ligand is bound to the metal center exchanges places with an anion or neutral molecule that was previously outside the coordination complex.
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What parameters are included in the specific rotation calculation of a pure substance
based on measurement from a polarimeter?
Select one or more:
Density of the sample
Pathlength of the sample container
Enantiomeric excess of the sample
Measured rotation of light
V
Determine whether the following molecule is a hemiacetal, acetal, or neither and select the appropriate box below.
Also, highlight the hemiacetal or acetal carbon if there is one.
Explanation
O
CH O
Ohemiacetal Oacetal Oneither
Check
A
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000
Ar
1. Using Online resources and chemical structures hand draw four different
organic compounds (not those already shown in your handout) that are
chiral, optically active (a pair of enantiomers will count as one). Pay attention
to correct stereochemistry
2. Write or type a short paragraph to Discuss the stereochemical relationship
between the four compounds.
Chapter 9 Solutions
ACHIEVE/CHEMICAL PRINCIPLES ACCESS 1TERM
Ch. 9 - Prob. 9A.1ASTCh. 9 - Prob. 9A.1BSTCh. 9 - Prob. 9A.1ECh. 9 - Prob. 9A.2ECh. 9 - Prob. 9A.3ECh. 9 - Prob. 9A.4ECh. 9 - Prob. 9A.5ECh. 9 - Prob. 9A.6ECh. 9 - Prob. 9A.7ECh. 9 - Prob. 9A.8E
Ch. 9 - Prob. 9A.9ECh. 9 - Prob. 9A.10ECh. 9 - Prob. 9A.11ECh. 9 - Prob. 9A.12ECh. 9 - Prob. 9A.13ECh. 9 - Prob. 9A.14ECh. 9 - Prob. 9B.1ASTCh. 9 - Prob. 9B.1BSTCh. 9 - Prob. 9B.2ASTCh. 9 - Prob. 9B.2BSTCh. 9 - Prob. 9B.1ECh. 9 - Prob. 9B.2ECh. 9 - Prob. 9B.3ECh. 9 - Prob. 9B.4ECh. 9 - Prob. 9B.5ECh. 9 - Prob. 9B.6ECh. 9 - Prob. 9B.7ECh. 9 - Prob. 9B.8ECh. 9 - Prob. 9B.9ECh. 9 - Prob. 9B.10ECh. 9 - Prob. 9B.11ECh. 9 - Prob. 9B.12ECh. 9 - Prob. 9B.13ECh. 9 - Prob. 9B.14ECh. 9 - Prob. 9B.15ECh. 9 - Prob. 9B.16ECh. 9 - Prob. 9C.1ASTCh. 9 - Prob. 9C.1BSTCh. 9 - Prob. 9C.2ASTCh. 9 - Prob. 9C.2BSTCh. 9 - Prob. 9C.3ASTCh. 9 - Prob. 9C.3BSTCh. 9 - Prob. 9C.4ASTCh. 9 - Prob. 9C.4BSTCh. 9 - Prob. 9C.1ECh. 9 - Prob. 9C.2ECh. 9 - Prob. 9C.3ECh. 9 - Prob. 9C.4ECh. 9 - Prob. 9C.5ECh. 9 - Prob. 9C.6ECh. 9 - Prob. 9C.7ECh. 9 - Prob. 9C.8ECh. 9 - Prob. 9C.9ECh. 9 - Prob. 9C.10ECh. 9 - Prob. 9C.11ECh. 9 - Prob. 9C.12ECh. 9 - Prob. 9C.13ECh. 9 - Prob. 9C.14ECh. 9 - Prob. 9C.15ECh. 9 - Prob. 9C.16ECh. 9 - Prob. 9C.17ECh. 9 - Prob. 9C.18ECh. 9 - Prob. 9C.19ECh. 9 - Prob. 9C.20ECh. 9 - Prob. 9D.1ASTCh. 9 - Prob. 9D.1BSTCh. 9 - Prob. 9D.2ASTCh. 9 - Prob. 9D.2BSTCh. 9 - Prob. 9D.3ASTCh. 9 - Prob. 9D.3BSTCh. 9 - Prob. 9D.4ASTCh. 9 - Prob. 9D.4BSTCh. 9 - Prob. 9D.1ECh. 9 - Prob. 9D.2ECh. 9 - Prob. 9D.3ECh. 9 - Prob. 9D.4ECh. 9 - Prob. 9D.5ECh. 9 - Prob. 9D.6ECh. 9 - Prob. 9D.7ECh. 9 - Prob. 9D.8ECh. 9 - Prob. 9D.9ECh. 9 - Prob. 9D.10ECh. 9 - Prob. 9D.11ECh. 9 - Prob. 9D.12ECh. 9 - Prob. 9D.13ECh. 9 - Prob. 9D.14ECh. 9 - Prob. 9D.15ECh. 9 - Prob. 9D.16ECh. 9 - Prob. 9D.17ECh. 9 - Prob. 9D.18ECh. 9 - Prob. 9D.19ECh. 9 - Prob. 9D.20ECh. 9 - Prob. 9D.21ECh. 9 - Prob. 9D.22ECh. 9 - Prob. 9D.23ECh. 9 - Prob. 9D.24ECh. 9 - Prob. 9D.25ECh. 9 - Prob. 9D.26ECh. 9 - Prob. 9D.27ECh. 9 - Prob. 9D.28ECh. 9 - Prob. 9D.29ECh. 9 - Prob. 9D.30ECh. 9 - Prob. 9D.31ECh. 9 - Prob. 9D.32ECh. 9 - Prob. 9D.33ECh. 9 - Prob. 9D.34ECh. 9 - Prob. 9.1ECh. 9 - Prob. 9.2ECh. 9 - Prob. 9.3ECh. 9 - Prob. 9.4ECh. 9 - Prob. 9.5ECh. 9 - Prob. 9.6ECh. 9 - Prob. 9.7ECh. 9 - Prob. 9.8ECh. 9 - Prob. 9.9ECh. 9 - Prob. 9.10ECh. 9 - Prob. 9.11ECh. 9 - Prob. 9.12ECh. 9 - Prob. 9.13ECh. 9 - Prob. 9.14ECh. 9 - Prob. 9.15ECh. 9 - Prob. 9.16ECh. 9 - Prob. 9.17ECh. 9 - Prob. 9.18ECh. 9 - Prob. 9.19ECh. 9 - Prob. 9.20ECh. 9 - Prob. 9.21ECh. 9 - Prob. 9.23ECh. 9 - Prob. 9.25E
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