Chemistry-Stud. Solution Guide
9th Edition
ISBN: 9781285697185
Author: ZUMDHAL
Publisher: CENGAGE L
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Textbook Question
Chapter 9, Problem 99CP
Carbon monoxide (CO) forms bonds to a variety of metals and metal ions. liS ability to bond to iron in hemoglobin is the reason that CO is so toxic. The bond carbon monoxide forms to metals is through the carbon atom:
a. On the basis of electronegativities, would you expect the carbon atom or the oxgen atom to form bonds to metals?
b. Assign formal charges to the atoms in CO. Which atom would you expect to bond to a metal on this basis?
c. In the MO model, bonding MOs place more electron density near the more electronegative atom. (See the HF molecule in Figs. 4-54 and 4-55.) Antibonding MOs place more electron density near the less electronegative atom in the diatomic molecule. Use the MO model to predict which atom of carbon monoxide should form bonds to metals.
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(a) The following synthesis of the molecule shown in the circle has a major problem. What is this problem? (2
pts)
1) HBr
(no peroxides)
2) H-
NaNH2
Br
3) NaNH,
4) CH3Br
5) H2, Pd
(b) Starting with the molecule shown below and any other materials with two carbons or less, write out an
alternate synthesis of the circled molecule. More than one step is needed. Indicate the reagent(s) and the major
product in all the steps in your synthesis. (5 pts)
2024 Fall Term (1) Organic Chemistry 1 (Lec)
CHEM 22204 02[6386] (Hunter College)
(c) Using the same starting material as in part (b) and any other materials win two carpons or less, write out
syntheses of the circled molecules shown below. More than one step is needed in each case. Indicate the
reagent(s) and the major product in all the steps in your synthesis. You may use reactions and products from
your synthesis in part (b). (5 pts)
alt
ons for
Free Response Questions
FRQ 1:
0/5
To spectrophotometrically determine the mass percent of cobalt in an ore containing cobalt and
some inert materials, solutions with known [Co?) are prepared and absorbance of each of the
solutions is measured at the wavelength of optimum absorbance. The data are used to create a
calibration plot, shown below.
0.90-
0.80-
0.70
0.60
0.50
0.40-
0.30
0.20-
0.10-
0.00-
0.005
0.010
Concentration (M)
0.015
A 0.630 g sample of the ore is completely dissolved in concentrated HNO3(aq). The mixture is diluted
with water to a final volume of 50.00 ml. Assume that all the cobalt in the ore sample is converted to
Co2+(aq).
a. What is the [Co2] in the solution if the absorbance of a sample of the solution is 0.74?
13
✗
b. Calculate the number of moles of Co2+(aq) in the 50.00 mL solution.
0.008 mols Co
Please correct answer and don't used hand raiting
Chapter 9 Solutions
Chemistry-Stud. Solution Guide
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